SEQUENTIAL ANALYSIS OF BLACKSHALES AND ITS APPLICATION TO BIOMINERALIZATION RESEARCH
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摘要: 用三氯甲烷、醋酸-醋酸钠缓冲溶液、盐酸-磷酸混合液、盐酸-氢氨酸混合液和重液分离法,依次处理暗色泥质岩,分别得到氯仿沥青A、碳酸盐组分、铁锰氧化物组分、硅酸盐组分,最后得到生油母质干酪根。各组分的标准加入回收率为38%~104.3%。除用于油页岩中主要组分的赋存状态研究外,该分析方法亦适用于生物成矿作用研究。Abstract: After leaching blackshales with CHCL3,HaAc-NaAc buffer,HCl-H3PO4 mixture,HCl-HP mix-ture and heavy liquid sequentially,chloroform extracted bitumen-A,carbonate,ferromanganese oxide,silicate components and kerogen are obtained respectively-The recovery of standard addition for different components ranges 86%-104.3%.The sequential analysis is applicable to,besides the study of main components in oil shales,biomineralization research.
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[1] 高瑞棋,孔庆云,辛国强,黄福堂.石油地质实验手册,哈尔滨:黑龙江科技出版社,1992 [2] 叶连俊等著.生物成矿作用研究.北京:海洋出版社,1993 [3] 王璞君,王东坡,常平,李红.油页岩中生物及有机质对金属元素富集作用机理研究.地质科学,1995 [4] 王子玉,曹继安.相指标分析中黄铁矿铁的直接测定.石油地质实验室,1990,(12)1:71-15 [5] 余至清.氛仿沥青A连续抽提法的研究.石油实验地质,1989,11(3):264, [6] 周明宜.二元溶剂抽提岩石中可溶有机质的试验.石油地质实验室,1983,5(1):75-76 [7] Canfield D E.Raiswell R,Westrich J T,Reaves C M and Bern-er R A.The use of chromium reduction in the analysis of re-duced inorganic sulfur in sediments and shales.Chem.Geol.1986,54:149-155. [8] Coveney Jr R M et al.Gold and platinum in shales with evidence against extra-terrestrial sources of metals.Chemical Geology,1992.99;101-104 [9] Ripley E M,Shaffer N R and Gilstrap M S.Distribution and geochemical characteristics of metal enrichment in the New Al-bony shale (Devonian-Mississippian),Indiana.Economic Ge-ol.1990,85:1790-1807 [10] Tessler A,Campbell P G C and Bisson M.Sequential extrac-tion procedure for the speciation of particulate trace metals.Analytical Chem,1979.51(7):844-851
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