RESEARCHES ON THE CHARACTERISTICS OF THE NEUTRAL NITROGEN COMPOUNDS AND THE OIL MIGRATION IN ORDOVICIAN CRUDE OIL FROM TAHE OIL FIELD, TARIM BASIN
-
摘要: 塔河油区具多期成藏的特点,重质油与轻质油并存。重质油中,无论是中性含氮化合物的绝对浓度或是其比值指标都降低,严重影响了原油运移途径的判别。轻质油中,中性含氮化合物指示原油具有自南向北、自东向西的运移特点,其咔唑(CA)绝对浓度由高变低,甲基咔唑系列(MCA)与二甲基咔唑系列(DMCA)比值逐渐增大,苯并咔唑系列的[a]/([a]+[c])比值则随运移距离增加而降低。在塔河3区断裂带附近,咔唑(CA)绝对浓度较高,甲基咔唑系列(MCA)与二甲基咔唑系列(DMCA)比值较低,苯并咔唑系列的[a]/([a]+[c])比值较大,显示断裂沟通了源岩及主力油气输导层,油气运移距离短,晚期油气活跃,油质总体优于塔河4、6区。Abstract: In Tahe oil field,the oil accumulation formed in several stages.The heavy oil and the light oil are together in presence in the Ordovician reservoirs.In heavy oil,not only the absolute concentrations but also the ratio indicators of neutral nitrogen compounds are too low to distinguish the oil migration path.The distribution of the neutral nitrogen compounds in the light oil shows that the oil migrates from the south to the north and from the east to the west.In these two orientations,the absolute concentration of carbazole(CA) decreases,the ratio of methycarbazoles(MCA) and the dmethycarbazoles(DMCA) increases,and the ratio of benzo carbazole,[a]/([a]+[c]),decreases.At the fault belt in the No.3 Block in Tahe oil field,the absolute concentration of carbazole is high,the ratio of MCA to DMCA is low,and the value of [a]/([a]+[c]) is relative high.These features show that it is through the fault that the hydrocarbon migrates from the source rock to the reservoirs.In this way,the oil migration paths are short,and the hydrocarbon can accumulate in the late stages.Therefore,the crude oil is lighter in No.3 Block than in the blocks of No.4 and No.6 in Tahe oil field.
-
Key words:
- neutral nitrogen compound /
- petroleum migration /
- Ordovician /
- heavy oil /
- light oil /
- the Tahe oil field /
- Tarim Basin
-
[1] 顾忆.塔里木盆地北部塔河油田油气藏成藏机制[J].石油实验地质,2000,22(4):307~312. [2] 范小林,邱蕴玉,鲍新毅.塔里木盆地轮南-阿克库勒地区地质及油气成藏与勘探目标关系[J].石油实验地质,1999,21(2):132~136. [3] 刘洛夫,徐新德,毛东风等.咔唑类化合物在油气运移研究中的应用初探[J].科学通报,1997,42(4):420~423. [4] 李素梅,王铁冠,张爱云.原油中吡咯类化合物的分布特征及其地球化学意义[J].沉积学报,1999,17(2):312~317. [5] 李素梅,王铁冠,郭绍辉等.原油中含氮化合物——烷基酚类[J].石油学报,2000,21(1):44~48. [6] 张春明,赵红静,梅博文等.微生物降解对原油中咔唑类化合物的影响[J].石油与天然气地质,1999,20(4):341~343,348. [7] 南红丽,李永林,赵德力等.焉耆盆地含氮化合物分布与油气运移特征[J].石油实验地质,2004,26(5):488~491. [8] 李贤庆,侯读杰,肖贤明等.应用含氮化合物探讨油气运移和注入方向[J].石油实验地质,2004,26(2):200~205. [9] Dorbon M,Schmitter J M,Garrigues P,et al.Distribution of carbazole derivatives in petroleum [J].Organic Geochemistry,1984,7:111~120. [10] Yamamoto M.Fractionation of azarenes during oil migration[J].Organic Geochemistry,1992,19:389~402. [11] 黄继文.塔里木盆地塔河油区原油生物标志化合物在运移方面的应用探讨[J].石油实验地质,2003,25(增刊):573~577
计量
- 文章访问数: 643
- HTML全文浏览量: 66
- PDF下载量: 411
- 被引次数: 0