原油中烷基萘的形成机理及其成熟度参数应用

李美俊; 王铁冠

doi:10.11781/sysydz200506606

原油中烷基萘的形成机理及其成熟度参数应用

doi: 10.11781/sysydz200506606

李美俊^1,2,
王铁冠^1,2

1.
中国石油大学石油天然气成藏机理教育部重点实验室北京102249
2. 中国石油大学资源与信息学院地化室北京102249

基金项目: 国家自然科学基金项目(40172056)

详细信息

作者简介:
李美俊(1972- ),男(汉族),重庆人,博士,讲师,主要从事有机地球化学和石油地质研究和教学工作.

中图分类号: TE132.4
计量
- 文章访问数: 823
- HTML全文浏览量: 106
- PDF下载量: 719
- 被引次数: 0
出版历程
- 收稿日期: 2005-01-29
- 修回日期: 2005-09-10
- 刊出日期: 2005-11-25

THE GENERATING MECHANISM OF METHYLATED NAPHTHALENE SERIES IN CRUDE OILS AND THE APPLICATION OF THEIR MATURITY PARAMETERS

Li Meijun^1,2,
Wang Tieguan^1,2

1.
Key Laboratory for Hydrocarbon Accumulation Mechanism, Ministry of Education, China University of Petroleum, Beijing 102249, China
2. Geochemical Laboratory of Resources and Information School, China University of Petroleum, Beijing 102249, China

摘要

摘要: 原油和沉积有机质中烷基萘系列主要通过异构化反应和歧化反应生成,并可用芳香烃的亲电取代反应历程进行解释,所生成各种异构体的相对含量受“电子效应”和“空间效应”的控制。多甲基萘系列地球化学参数,对于原油及沉积有机质的成熟度、生物降解作用和生源组成具有表征意义。渤海湾盆地大民屯凹陷原油样品中的多甲基取代萘系列分析结果表明,在常规的甾萜类异构化作用达到平衡终点的情况下,多甲基萘取代系列地球化学参数仍能反映出大民屯凹陷高蜡油成熟度比正常油偏低,并与该区的石油地质背景和盆地模拟结果相吻合,表明多甲基萘系列相关的地球化学参数是一类非常有用的地球化学指标。
- 多甲基萘 /
- 地球化学指标 /
- 成熟度参数 /
- 高蜡油 /
- 大民屯凹陷 /
- 渤海湾盆地
Abstract: Naphthalene and methylated naphthalene series in crude oils and sedimentary organic matters are formed through isomerization and disproportionation,which can be interpreted by aromatic electrophilic substitution process.The relative concentrations of various isomers are controlled by "electronic effect" and "steric effect".Geochemical parameters related to methylated naphthalenes can be used to indicate the differences of maturity,biodegradation,and source input between oil and sedimentary organic matters.Oil samples selected from Damintun Depression in Bohai Bay Basin have been analyzed for methylated naphthalene series.The results show that the high waxy oils are more thermally mature than normal oils,even though some saturated hydrocarbon composition such as steranes and terpanes isomeric ratios get to equilibrium end.This conclusion is consistent with the geological background and the basin modeling results in the study area.It is proved that these methylated naphthalene parameters are very useful geochemical indicators.
- methylated naphthalene /
- maturity parameter /
- high waxy oil /
- Damintun depression /

HTML全文

参考文献(25)

[1]	Tissot B P,Welte D H.Petroleum formation and occurrence [M].New York:Springer-Verlag,1984
[2]	Puttmann W,Villar H.Occurrence and geochemical significance of 1,2,5,6-tetramethylnaphthalene[J].Geochimica et Cosmochimica Acta,1982,46:1～10
[3]	Strachan M G,Alexander R,Kagi R I.Trimethylnaphthalenes in crude oils and sediments:effects of source and maturity [J].Geochimica et Cosmochimica Acta,1988,52:1 255～1 264
[4]	陈致林,李素娟,王忠.低-中成熟演化阶段芳烃成熟度指标的研究[J].沉积学报,1997,15(2):193～197
[5]	黄海平,杨杰,Larter S R.生物降解作用对储层抽提物中多甲基萘分布的影响[J].地球科学,2003,28(3):281～288
[6]	王振平,曲佳燕,卢双舫.原油中萘菲化合物的分布与油藏聚集途径[J].大庆石油学院学报,2002,26(3):5～8
[7]	Radke M,Willsch H,Welte D H.Methylated dicyclic and tricyclic aromatic hydrocarbons in crude oils from the Handil field,Indonesia [J].Organic Geochemistry,1990,15:17～34
[8]	Radke M,Rullkotter J,Vriend S P.Distribution of naphthalenes in crude oils from the Java Sea:source and maturation effects[J].Geochimica et Cosmochimica Acta,1994,52:1 255～1 264
[9]	van Aaressen B G K,Hessels J K C,Abbink O A,et al.The occurrence of polycyclic sesqui-,tri-and oligoterpenoids derived from a resinouse polymeric cadinene in crude oils form South East Asia[J].Geochimica et Cosmochimica Acta,1992,56:1 231～1 246
[10]	Ellis L,Singh R K,Akecabser,et al.Formation of isohexyl alkyaromatic hydrocarbons form aromatization-rearrangement of terpenoids in the sedimentary environment:a new class of biomarker [J].Geochimica et Cosmochimica Acta,1996,60:4 747～4 763
[11]	Killops S D.Novel aromatic hydrocarbons of probable bacteria origin in a Jurassic lacustrine sequence [J].Organic geochemistry,1991,17:25～36
[12]	Alexander R,Bastow T P,Fisher S J,et al.Tetramethylnaphthalenes in crude oils[J].Journal of Polycyclic Aromatic Compounds,1993,3:629～634
[13]	Bastow T P,Alexander R,Sosrowidjojo I B,et al.Pentamethylnaphalenes and ralted compounds in sedimentary organic matter[J].Organic geochemistry,1998,28:585～596
[14]	Radke M,Welte D H,Willsch H.Geochimical study on a well in the Western Canada Basin:relation of the aromatic ditribution pattern to maturity of organic matter [J].Geochimica et Cosmochimica Acta,1982,46:1～10
[15]	Alexander R,Kagi R I,Rowland S J,et al.The effects of thermal maturity on distribution of dimethylnaphthalenes and trimethylnaphthalenes in some Ancient sediments and petroleums [J].Geochimica et Cosmochimica Acta,1985,49:385～395
[16]	van Aarssen B G K,Bastow T P,Alexander R,et al.Distributions of methylated naphthalenes in crude oils:indicators of maturity,biodegradation and mixing[J].Organic Geochemistry,1999,30:1 213～1 227
[17]	Bastow T P,Alexander R,Fisher S J,et al.Geosynthesis of organic compounds.PartⅤ-mehylation of alkylnaphthalenes[J].Organic Geochemistry,2000,31:523～534
[18]	黄志桂,吴兆荧,吴增元等.有机化学[M].重庆:西南师范大学出版社,1990
[19]	Huang Y S,Geng A S,Fu J M,et al.The investigation of characteristics of biomarker assemblages and their precursors in Damintun ultra-high wax oils and related source rocks[J].Organic Geochemistry,1992,19:29～39
[20]	郑容植,王贵珍.大民屯凹陷高凝油低凝油特征及其油气分布规律[J].石油实验地质,1988,10(3):256～267
[21]	黄海平,李虹,马刊创等.大民屯凹陷高蜡油的形成条件[J].石油与天然气地质,2001,22(1):64～71
[22]	黄海平.大民屯凹陷烃源岩中高分子量烃的形成与分布特征[J].石油实验地质,2000,22(4):297～301,318
[23]	谢文彦,张占文,姜建群等.辽河盆地大民屯凹陷油气性质及成因机制研究[J].石油实验地质,2004,26(3):292～297
[24]	李美俊.大民屯凹陷层序地层地球化学及油气成藏特征:[学位论文].北京:中国地质大学,2003
[25]	Huang H,Later S R,Love G D.Analysis of wax hydrocarbons in petroleum source rocks from the Damintun Depression,eastern China,using high temperature gas chromatography [J].Organic Geochemistry,2003,34(12):1 673～1 687