APPLICATION OF THE SUPERCRITICAL FLUID EXTRACTION TECHNIQUE IN GEOCHEMICAL PROSPECTING FOR OIL AND GAS
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摘要: 超临界流体的密度是气体的100~1 000倍,粘度比液体低10~100倍,扩散系数比液体高10~100倍,易于穿透介质,可以选择性分离,特别是基本消除了有机溶剂对人体和环境的危害。一般超临界萃取过程仅需10~60 min。选择某油田已知含油气区进行试验研究,结果表明,萃取出的烃类物质保真性好,可以与化探样品分析的其它指标进行对比,为油气化探提供可靠资料。Abstract: The densities of supercritical fluids are 100 to 1 000 times as much as the densities of gases.Their viscosities are 10 to 100 times less than that of liquids.And their coefficients of diffusion are 10 to 100 larger than that of liquids.A supercritical fluid is easy to penetrate the media and can achieve selective separation on hydrocarbons.Moreover,supercritical fluid extraction can basically remove the harm of organic solvents to human and environment.Generally,the process of supercritical fluid extraction only take 10 to 60 minutes.An existing oil and gas area in a oil field was selected where research on supercritical fluid extraction was made.The result shows that fidelity of the extracted hydrocarbons is high.The comparison between supercritical fluid extraction and the other indicators in petroleum geochemical exploration is possible.Supercritical fluid extraction can supply oil and gas geochemical exploration with reliable information.
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[1] 杨育斌,张金来,吴学明等.油气地球化学勘查[M].武汉:中国地质大学出版社,1995.1~60 [2] 赵克斌,孙长青.油气化探在天然气勘探中的应用[J].石油实验地质,2004,26(6):574~579,584 [3] 邱楠生,金奎励.不同显微组分芳烃结构与荧光机理探讨[J].石油实验地质,1994,16(4):380~383 [4] 王汇彤,游建昌,王培荣等.饱和烃和芳烃的高压液相色谱法精细分离[J].石油实验地质,2003,25(2):221~224 [5] 金晓辉,朱丹,林壬子等.原油气相色谱指纹可配比性实验研究[J].石油实验地质,2003,25(1):53~57,92 [6] 曹寅,钱志浩.油气地质实验分析技术发展趋势与发展望[J].石油实验地质,2003,25(S1):621~624 [7] 王少芬,魏建漠.超临界流体萃取技术在核废料处理方面的应用[J].应用化学,2003,20(5):409~414 [8] 蒋崇文,杨亦文,任其龙等.超临界流体色谱法分离生育酚同系物[J].分析化学,2003,31(11):1 337~1 340 [9] 崔兆杰,张春阳.环境模拟样品中多环芳烃超临界流体萃取对回收率影响的研究[J].分析仪器,1996(1):55~58 [10] 沈忠民,周光甲.超临界流体对生油岩烃类抽提研究[J].南京大学学报(自然科学),1995,3(4):635~640
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