留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

鄂尔多斯盆地三叠系油砂中芴酮系列化合物成因

赵欣 史基安 王金鹏 王琪 卢龙飞 王雷 王有孝

赵欣, 史基安, 王金鹏, 王琪, 卢龙飞, 王雷, 王有孝. 鄂尔多斯盆地三叠系油砂中芴酮系列化合物成因[J]. 石油实验地质, 2006, 28(1): 49-53. doi: 10.11781/sysydz200601049
引用本文: 赵欣, 史基安, 王金鹏, 王琪, 卢龙飞, 王雷, 王有孝. 鄂尔多斯盆地三叠系油砂中芴酮系列化合物成因[J]. 石油实验地质, 2006, 28(1): 49-53. doi: 10.11781/sysydz200601049
Zhao Xin, Shi Jian, Wang Jinpeng, Wang Qi, Lu Longfei, Wang Lei, Wang Youxiao. DETECTION OF ALKYLATED FLUORENONES AND THEIR ORIGIN IN OIL SANDS OF TRIASSIC, THE ORDOS BASIN[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2006, 28(1): 49-53. doi: 10.11781/sysydz200601049
Citation: Zhao Xin, Shi Jian, Wang Jinpeng, Wang Qi, Lu Longfei, Wang Lei, Wang Youxiao. DETECTION OF ALKYLATED FLUORENONES AND THEIR ORIGIN IN OIL SANDS OF TRIASSIC, THE ORDOS BASIN[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2006, 28(1): 49-53. doi: 10.11781/sysydz200601049

鄂尔多斯盆地三叠系油砂中芴酮系列化合物成因

doi: 10.11781/sysydz200601049
基金项目: 国家自然科学基金项目(40272065);中国科学院知识创新重要方向项目(KZCX3-SW-128)
详细信息
    作者简介:

    赵欣(1968- ),男(汉族),陕西凤翔人,博士生、讲师,主要从事油气储层沉积学与储层地球化学研究工作.

  • 中图分类号: TE135

DETECTION OF ALKYLATED FLUORENONES AND THEIR ORIGIN IN OIL SANDS OF TRIASSIC, THE ORDOS BASIN

  • 摘要: 从鄂尔多斯盆地三叠系延长组6个油砂样品的抽提物中,通过色谱-质谱(GC-MS)分析,首次检测出一系列C0-5芴-9-酮化合物和苯并芴-9-酮化合物,它们是芴和苯并芴在储集层中发生氧化-还原反应的产物。这个过程是由于在晚成岩A期,陆表暴露时期,伴随着含氧和细菌的大气淡水的渗入,在延长组储集层中的铝硅酸盐矿物参与下,油砂中的烷基芴和苯并芴在碱性成岩环境下氧化的结果。

     

  • [1] Venkatesan M I,Kaplan I R.Distribution and transport of hydrocarbons in surface sediments of the Alaskan Outer Continental Shelf[J].Geochimet Cosmochim Acta,1982,46:2 135~2 149.
    [2] Hallett D J,Onuska F I,Comba M E.Aliphatic and polyaromatic compounds of weathered and unweathered southern Louisiana crude oil[J].Marine Environ Res,1983,8:73~85.
    [3] Stoicovici E,Muresan I.Studies on some bituminous rocks around Tibles Mountains (Romania)[J].Geol-Geogr,1982,27:3~12.
    [4] Simoneit bR T,Brenner S,Peters K E,et al.Thermal alteration of Cretaceous black shale by dibase intrusions in the eastern Atlantic.Ⅱ.effects on bitumen and kerogen[J].Geochimet Cosmochim Acta,1981,45:1 581~1 602.
    [5] Rovere C E,Crisp P T,Ellis J,et al.Chemical characterization of shale oil from Condor,Australia[J].Fuel,1983,62:1 274~1 282.
    [6] Poirier M A,Das B S.Characterization of polynuclear aromatic hydrocarbons in bitumen,heavy oil fractions boiling above 350℃ by GC-MS[J].Fuel,1984,63:361~367.
    [7] Van Graas G,de Leeuw J W,Schenck P A,et al.Kerogen of Toarcian shales of the Paris Basin,A study of its maturation by flash pyrolysis techniques[J].Geochimet Cosmochim Acta,1981,45:2 465~2 474.
    [8] Martin F,Gonzalez-Vila F J.Pyrolysis of soil humic acid and of their hydrolyzed and methylated products[J].Z Pflanzenernaehr Bodenk,1983,146:653~659.
    [9] Mojelsky T W,Strausz O P.Detection of alkylated fluorenes in Athabasca oil sand hitumens[J].Org Geochem,1986,9 (1):39~45.
    [10] Mojelsky T W,Strausz O P.Detection of methyl fluorenones in Athabasca oil sand bitumens[J].Org Geochem,1986,9 (1):31~37.
    [11] Heinz Wilkes,Heather Clegg.Fluoren-9-ones and carbazoles in the Posidonia Shale,Hils Syncline,northwest Germany[J].Fuel,1998,77(7):657~668.
    [12] Bcnnett B,Larter S R.The isolation,occurrence and origin of fluorenones in crude oil and rock extracts[J].Org Geochem,2000,31:117~126.
    [13] 杨俊杰,斐锡古.中国天然气地质学(卷四)[M].北京:石油工业出版社,1996.1~291.
    [14] 张福礼.多旋回与鄂尔多斯盆地石油天然气[J].石油实验地质,2004,26(2):138~142.
    [15] 长庆油田石油地质志编写组.中国石油地质志(卷十二)长庆油田[M].北京:石油工业出版社,1992.1~399.
    [16] Maowen Li,Larter S R,Daniel Stoddart.Liquid chromatographic separation schemes for pyrrole and pridine nitrogen aromatic heterocycle fractions from crude oils suitable for rapid characterization of geochemical[J].Anal Chem,1992,64:1 337~1 344.
    [17] 史基安,赵欣,王金鹏等.油藏储层中不同赋存状态烃类地球化学特征:Ⅰ链烷烃[J].沉积学报,2005,23(1):162~169.
    [18] 黄思静,武文慧,刘洁等.大气水在碎屑岩次生孔隙形成中的作用—以鄂尔多斯盆地三叠系延长组为例[J].地球科学—中国地质大学学报,2003,28(4):419~424.
    [19] 段毅,王智平,张辉等.柴达木盆地原油烃类地球化学特征[J].石油实验地质,2004,26(4):359~364
  • 加载中
计量
  • 文章访问数:  737
  • HTML全文浏览量:  56
  • PDF下载量:  284
  • 被引次数: 0
出版历程
  • 收稿日期:  2005-06-27
  • 修回日期:  2005-11-25
  • 刊出日期:  2006-01-28

目录

    /

    返回文章
    返回