全二维色谱飞行时间质谱在石油地质样品分析中的应用

蒋启贵; 王强; 马媛媛; 宋晓莹; 张志荣; 张美珍

doi:10.11781/sysydz200906627

全二维色谱飞行时间质谱在石油地质样品分析中的应用

doi: 10.11781/sysydz200906627

中国石油化工股份有限公司, 石油勘探开发研究院, 无锡石油地质研究所, 江苏, 无锡, 214151

基金项目: 国家重点基础研究发展计划(973计划)项目(2005CB422102);中国石化科技开发项目(P07018)

详细信息

作者简介:
蒋启贵(1964- ),男,高级工程师,主要从事油气地球化学研究.E-mail:qiguij2004@126.com.

中图分类号: TE135
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出版历程
- 收稿日期: 2009-05-26
- 修回日期: 2009-10-27
- 刊出日期: 2009-12-28

ANALYSIS APPLICATION OF COMPREHENSIVE TWO-DIMENSIONALl GAS CHROMATOGRAPHY TIME-OF-FLIGHT MASS SPECTROMENTRY IN PETROLEUM GEOLOGY

Wuxi Institute of Petroleum Geology, SINOPEC, Wuxi, Jiangsu 214151, China

摘要

摘要: 利用全二维气相色谱—飞行时间质谱技术对石油地质样品进行了分析研究。原油直接进样分析显示原油组分中链烷烃、环烷烃、单环芳烃、双环芳烃和三环芳烃非常有规律地分布在特征区域。化合物鉴别定性准确可靠,能获取原油烃组成的详细特征。和传统色谱分析相比,轻烃分析可实现C₆-C₁₀轻烃组分中的单体烃的分离和识别,能提供更为丰富的轻烃指纹信息。生物标志物多环萜烷的分析可实现高碳数低含量三环萜烷与五环萜烷的分离和识别,伽马蜡烷也得到很好的分离。研究表明全二维气相色谱—飞行时间质谱技术在石油地质勘探研究中有广阔的应用前景。
- 全二维气相色谱 /
- 飞行时间质谱 /
- 烃组成 /
- 轻烃 /
- 生物标志物
Abstract: Analysis study to the petro-geology samples was carried out by the technology of comprehensive 2-D GC TOF MS.According to the analysis of original oil,the regulation of the characteristic regions of several groups,namely paraffin,cyclane,monoaromatics,dinuclear and trinuclear aromatics were revealed.With this facility,it is possible to obtain accurate compound identifying and detailed feature of oil sample's hydrocarbon composition.To give more information of the fingerprint of light hydrocarbons,based on the comparison with traditional GC,higher performance on separating and easier re-cognizing of the light hydrocarbon,which are in the frame of C₆-C₁₀,can be achieved by GC×GC.To the biomarkers analysis,it achieved the great separating and easy identifying of tricyclic and pentacyclic terpane,and similarly to the gammacerane.With the high efficiency and performance of the facility,perspective application in the field of petroleum exploration will be done by the GC×GC.
- GC×GC /
- TOF MASS /
- hydrocarbon composition /
- light hydrocarbon /
- biomarker

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参考文献(19)

[1]	Phillips J B,Liu Z.Comprehensive 2 dimensionalgas chromatography using an on column thermal modulatorinterface[J].Journal of Chromatographic Science,1991,29:227-231
[2]	Philips J B,Beens J.Comprehensive two dimensional gas chromtography:a hyphenated method with strongcoupling between the two dimensions[J].Journal of Chromatography A,1999,856:331-347
[3]	Colombe Vendeuvre,Fabrice Bertoncini,Laurent Duval,et al.Comparison of conventional gas chromatography for the detailed analysis of petrochemical samples[J].Journal of Chromatography A,2004,1056:155-162
[4]	花瑞香,阮春海,王京华等.全二维气相色谱法用于不同石油馏分的族组成分布研究[J].化学学报,2002,60(12):2185-2191
[5]	路鑫,武建芳,吴建华等.全二维气相色谱/飞行时间质谱用于柴油组成的研究[J].色谱,2004,22(1):5-11
[6]	苟爱仙,张艳丽,史群策等.高效液相色谱测定润滑油烃族组成[J].黑龙江石油化工,1999,10(4):40-42
[7]	苟捷,谢小渝.轻质原油(含凝析油)的烃族组成分析[J].石油实验地质,2000,22(1):94-96
[8]	郭志军,张庭良,刘秀清等.用TLC/FID棒薄层色谱测定重质油的族组成方法的研究[J].福建分析测试,2008,17(2):22-24
[9]	田亮.多维气相色谱法测定油品的族组成[J].石化技术与应用,2004,18(2):119-121
[10]	丁洪生,孙兆林,张晓彤.毛细管气相色谱法分析轻烃族组成[J].石油化工高等学校学报,2004,17(4):9-11
[11]	张美珍,承秋泉,蒋启贵等.原油轻烃反吹色谱分析[J].石油实验地质,2007,29(2):212-216
[12]	蒋启贵,张彩明,张美珍等.岩石C₆-C₁₅轻烃定量分析方法研究[J].石油实验地质,2007,29(5):512-515,521
[13]	Thompson K F M.Light hydrocarbons in subsurface sediments[J].Geochimica et Cosmochimica Acta,1979,43,657-672
[14]	程克明,金伟明,向忠华等.陆相原油及凝析油的轻烃单体烃组成特征及地质意义[J].石油勘探与开发,1987,(1):33-34
[15]	Mango F D.The light hydrocarbons in petroleum:a critical review[J].Organic Geochemistry,1997,26(7/8):417-440
[16]	王培荣,朱俊章,方孝林等.一种新的原油轻烃分类法:塔里木盆地原油分类及其地化特征[J].石油学报,1998,19(1):24-29
[17]	张敏,张俊.塔中地区不同Mango轻烃参数原油的地球化学特征[J].地质勘探,2000,7(1):14-17
[18]	Chakhmakhchev A,Suzuki M,Takayama K,et al.Distribution of alkylated dibenzothiophenes in petroleum as a tool for maturity assessments[J] ．Organic Geochemistry,1997,26(7-8):483-490
[19]	王铁冠,何发岐,李美俊等.烷基二苯并噻吩类:示踪油藏充注途径的分子标志物[J].科学通报,2005,50(2):176-182