GEOCHEMICAL CHARACTERISTICS AND SIGNIFICANCE OF HEAVY OILS FROM THE WEST AREA OF BIYANG SAG, NANXIANG BASIN
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摘要: 精细刻画稠油地球化学特征,对其油源对比、成因乃至开发都具有一定指导作用。南襄盆地泌阳凹陷西部地区原油均遭受了中等以上级别的生物降解,规则甾烷和藿烷受到不同程度破坏,使得一些反映原油成因、成熟度的常用指标严重失效。通过对该区12个稠油样品地球化学特征的精细分析和研究,发现饱和烃中的伽马蜡烷、Ts、Tm以及长链三环萜烷的抗降解能力高于规则甾烷和藿烷,能较好地反映该区稠油地球化学特征。油源对比表明,该区核三下段原油均来源于核三下段烃源岩,而核三上段原油除来源于核三上段烃源岩外,不同小层段都有核三下段源岩不同程度的贡献。结合芳烃组成特征和参数,可以清楚地将研究区稠油划分成两类,并显示他们可能具有不同的生物降解机制。Abstract: It is essential to take a detailed study on the geochemical characteristics of heavy oil,which will be useful to conduct the oil-source correlation,the genesis and the development of heavy oil.The oils,which are from the west of Biyang Sag,have been experienced above middle degree of biodegradation.Furthermore,the regular steranes and hopanes have been suffered biodegradation to some extent,which made the common parameters reflected the genesis and maturity of oil ineffective.However,some parameters,which can resist strong biodegradation,such as gammacerane,Ts/Tm and some tricyclic terpane,still can identify the source of these biodegraded oils based on the GC-MS characteristics of 12 oil samples.It indicates that the crude oils in the lower of the Eh3 formation are derived from the source rock of the lower of the Eh3 formation,while the source of crude oils in the top of the Eh3 formation is the mixture of the top and lower of the Eh3 formation.In addition,some aromatic parameters,which are the component of aromatic hydrocarbon and the relation of triaromatic sterane(C20+C21) /∑(C20-C28) and triaromatic sterane C20/(C20+C28R),can divide biodegraded oils into two types.And this conclusion is also proved by the relation of triaromatic sterane(C20+C21)/∑(C20-C28) and C24 tetracyclic terpane/C26 tricyclic terpane.Moreover,it suggests that there might have different biodegraded mechanisms for the biodegraded oils in the west area,for the same degraded degree of oils have a different distribution of saturated compounds.
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Key words:
- biomarker /
- triaromatic steroid /
- heavy oil /
- Biyang Sag /
- Nanxiang Basin
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[1] 牛嘉玉,刘尚奇,门存贵,等.稠油资源地质与开发利用[M].北京:科学出版社,2002. [2] 蔡佳,罗家群,甘华军,等.南襄盆地泌阳凹陷隐蔽油气藏模式与富集规律[J].石油实验地质,2009,31(3):244-248. [3] 刘桂兰.稠油资源地质与开发利用[D].北京:中国地质大学,2008. [4] 蒋启贵,王强,马媛媛,等.全二维色谱飞行时间质谱在石油地质样品分析中的应用[J].石油实验地质,2009,31(6):627-632. [5] 李素梅,庞雄奇,高先志,等.辽河西部凹陷稠油成因机制[J].中国科学D辑,2008,38(增刊Ⅰ):138-149. [6] 包建平,朱翠山.生物降解作用对辽河盆地原油甾萜烷成熟度参数的影响[J].中国科学D辑,2008,38(增刊Ⅱ):38-46. [7] 罗家群,甘华军,蔡佳,等.泌阳凹陷下第三系核三上、下亚段油源差异及地球化学特征[J].石油天然气学报(江汉石油学院学报),2008,30(2):20-24. [8] 孟仟祥,张松林,催明中,等.不同沉积环境湖相低熟原油的芳烃分布特征[J].沉积学报,1998,17(1):121-126. [9] 倪春华,包建平,顾忆.生物降解作用对芳烃生物标志物参数的影响研究[J].石油实验地质,2008,30(4):386-389. [10] 李林强,林壬子.利用芳烃化合物研究东濮凹陷西斜坡地区原油成熟度[J].沉积学报,2005,23(2):361-365. [11] 李水福,何生.原油芳烃中三芴系列化合物的环境指示作用[J].地球化学,2008,37(1):45-50. [12] 李振广,冯子辉,宋桂侠,等.松辽盆地原油芳烃分布、组成特征与原油类型划分[J].石油与天然气地质,2005,26(4):494-500. [13] 朱扬明,张洪波,傅家谟,等.塔里木不同成因原油芳烃组成和分布特征[J].石油学报,1998,19(3):33-37. [14] BEACH F,PEAKMAN T M,ABBOTT G D,et al.Laboratory thermal alteration of triaromatic steroid hydrocarbons[J].Organic Geochemistry,1989,14(1):109-111. [15] 梁狄刚,陈建平.中国南方高过成熟区海相油源对比研究[J].石油勘探与开发,2005,32(2):8-14. [16] HUANG H P,BOWLER B F J,OLDENBURGA T B P,et al.The effect of biodegradation on polycyclic aromatic hydrocarbons in reservoired oils from the Liaohe Basin,NE China[J].Organic Geochemistry,2004,35(11-12):1619-1634.
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