留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

原油中难以分辨的复杂混合物研究进展

胡守志 李水福 张冬梅 马军

胡守志, 李水福, 张冬梅, 马军. 原油中难以分辨的复杂混合物研究进展[J]. 石油实验地质, 2011, 33(3): 292-296. doi: 10.11781/sysydz201103292
引用本文: 胡守志, 李水福, 张冬梅, 马军. 原油中难以分辨的复杂混合物研究进展[J]. 石油实验地质, 2011, 33(3): 292-296. doi: 10.11781/sysydz201103292
Hu Shouzhi, Li Shuifu, Zhang Dongmei, Ma Jun. Study of unresolved complex mixtures in crude oil[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(3): 292-296. doi: 10.11781/sysydz201103292
Citation: Hu Shouzhi, Li Shuifu, Zhang Dongmei, Ma Jun. Study of unresolved complex mixtures in crude oil[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(3): 292-296. doi: 10.11781/sysydz201103292

原油中难以分辨的复杂混合物研究进展

doi: 10.11781/sysydz201103292
基金项目: 国家青年自然科学基金(40902037);中央高校基本科研业务费专项资金(CUGL090219);构造与油气资源教育部重点实验室基金(TPR-2010-11)联合资助
详细信息
    作者简介:

    胡守志(1976- ),女,博士,副教授,从事油气地球化学研究.E-mail:hushzh@cug.edu.cn.

  • 中图分类号: TE135

Study of unresolved complex mixtures in crude oil

  • 摘要: 普通一维气相色谱中难以分辨的复杂混合物(UCM)是指普遍存在于原油(尤其是生物降解油)中的烃类化合物,其包含化合物数目可多达250000个,对其有效分辨可为原油(特别是生物降解油)成因、开采、炼制和残油环境污染评价及治理等研究提供大量以前未被发掘的地球化学信息。文章在阐述UCM定义的基础上,对UCM研究的实验技术进展、UCM化合物特征及其在石油勘探、开发和环境保护等领域的应用进行全面综述,并指出当前UCM研究存在的问题和进一步研究的方向。

     

  • [1] Peters K E,Walters C C,Moldowan J M.The biomarker guide:Biomarkers and Isotopes in Petroleum Systems and Earth History[M]. Cambridge: Cambridge University Press,2005.
    [2] 胡守志,张冬梅,唐静,等.稠油成因研究综述[J].地质科技情报,2009,28(2):94-97.
    [3] 胡守志,李水福,何生,等.南襄盆地泌阳凹陷西部稠油地化特征及意义[J].石油实验地质,2010,32(4):387-392.
    [4] 路俊刚,陈世加,王绪龙,等.严重生物降解稠油成熟度判识:以准噶尔盆地三台一北三台地区为例[J].石油实验地质,2010,32(4):373-376.
    [5] 卢鸿,彭平安,徐兴友,等.济阳坳陷特殊生物降解油的初步研究[J].沉积学报,2004,22(4):694-699.
    [6] 宋孚庆,任冬芩,张文龙,等.严重生物降解原油GC-MS特征及油源对比[J].分析测试学报,2004,23(S1):304-306.
    [7] 牛嘉玉,刘尚奇,门存贵,等.稠油资源地质与开发利用[M].北京:科学出版社,2002.
    [8] Sutton P A,Lewis C A,Rowland S J.Isolated of individual hydrocarbons from the unresolved complex hydrocarbon mixture of a biodegraded crude oil using preparative capillary gas chromatography[J].Organic Geochemistry,2005,36(6):963-970.
    [9] Gough M A,Rowland S J.Characterization of unresolved complex mixtures of hydrocarbons from lubricating oil feedstocks[J].Energy and Fuels,1991,5(6):869-874.
    [10] Gough M A,Rowland S J.Characterization of unresolved complex mixtures of hydrocarbons in petroleum[J].Nature,1990,334(6267):648-650.
    [11] Gough M A,Rhead M M,Rowland S J.Biodegradation studies of unresolved complex mixtures of hydrocarbons:model UCM hydrocarbons and the aliphatic UCM[J].Organic Geochemistry,1992,18(1):17-22.
    [12] Ellis L,Alexander R,Kagi R I.Separation of petroleum hydrocarbons using dealuminated mordenite molecular sieve-Ⅱ.Alkylnaphthalenes and alkylphenanthrenes[J].Organic Geochemistry,1994,21(8-9):849-855.
    [13] Donkin P,Smith E L,Rowland S J.Toxic effects of unresolved complex mixtures of aromatic hydrocarbons accumulated by mussels,Mytilus edulis,from contaminated field sites[J].Environmental Science and Technology,2003,37(21):4825-4830.
    [14] Frysinger G S,Gaines R B,Xu L,et al.Resolving the unresolved complex mixture in petroleum-contained sediments[J].Environmental Science and Technology,2003,37(8):1653-1662.
    [15] Killops S D,Al-Juboori M A.Characterization of the unresolved complex mixture(UCM) in the gas chromatograms of biodegraded petroleums[J].Organic Geochemistry,1990,15(2):147-160.
    [16] Demir C,Hindmarch P,Brereton R G.Deconvolution of a three component co-eluring peak duster in gas chromatography-mass spectrometry[J].Analyst,2000,125(2):287-292.
    [17] Mao D,Weghe H V D,Diels L,et al.High-performance liquid chromatography fractionation using a silver-modified column followed by two-dimensional comprehensive gas chromatography for detailed group-type characterization of oils and oil pollutions[J].Journal of Chromatography A,2008,1179(1):33-40.
    [18] Mao D,Lookman R,Weghe H B D,et al.Combing HPLC-GC×GC,GC×GC/ToF-MS,and Selected Ecotoxicity Assays for Detailed Monitoring of Petroleum Hydrocarbon Degradation in Soil and Leaching Water[J].Environ Sci Technol,2009,43(20):7651-7657.
    [19] Thomas K V,Donkin P,Rowland S J.Toxicity enhancement of an aliphatic petrogenic unresolved complex mixture(UCM)by chemical oxidation[J].Wat Res,1995,29(1):379-382.
    [20] Warton B,Alexander R,Kagi R.Characterisation of the ruthenium tetroxide oxidation products from the aromatic unresolved complex mixture of a biodegraded crude oil[J].Organic Geochemistry,1999,30(10):1255-1272.
    [21] Mapolelo MM,Rodger R P,BlakneyG T,et al.Characterization of naphthenic acids in crude oils and naphthenates by electrospray ionization FT-ICR mass spectrometry[J].International Journal of Mass Spectrometry,2010,300(2-3):149-157.
    [22] Adahchour M,Beens J,Brinkman U A T.Recent developments in the application of comprehensive two-dimensional gas chromatography[J].Journal of Chromatography A,2008,1186(1-2):67-108.
    [23] Boros E,Gurvich V,Zverovich I.Comprehensive two djmensional gas chromatography review[J].Journal of Separation Science,2009,32(5):883-904.
    [24] 王汇彤,魏彩云,张水昌,等.全二维气相色谱/飞行时间质谱在石油地质实验中应用初探[J].现代科学仪器,2008(6):21-23.
    [25] 王汇彤,翁娜,张水昌,等.全二维气相色谱/飞行时间质谱对饱和烃分析的图谱识别及特征[J].质谱学报,2010,31(1):18-27.
    [26] 蒋启贵,王强,马媛媛,等.全二维色谱飞行时间质谱在石油地质样品分析中的应用[J].石油实验地质,2009,31(6):627-632.
    [27] 李水福,胡守志,何生,等.原油中常见化合物的全二维气相色谱-飞行时间质谱分析[J].地质科技情报,2010,29(5):46-50,55.
    [28] Ventura G T,Kenig F,Reddy C M,et al.Analysis of unresolved complex mixtures of hydrocarbons extracted from Late Archean sediments by comprehensive two-dimensional gas chromatography (GC×GC)[J].Organic Geochemistry,2008,39(7):846-867.
    [29] Booth A M,Sutton P A,Lewis C A,et al.Unresolved complex mixtures of aromatic hydrocarbons:thousands of overlooked persistent,bioaccumulative,and toxic contaminants in mussels[J].Environment Science and Technology,2007,41(2):457-464.
    [30] Booth A M,Scarlett A G,Lewis C A,et al.Unresolved complex mixtures (UCMs) of aromatic hydrocarbons:branched alkyl indanes and branched alkyl tetralins are present in UCMs and accumulated by and toxic to,the mussel Mytilus edulis[J].Environment Science and Technology,2008,42(21):8122-8126.
    [31] Melbye A G,Brakstad O G,Hokstad J N,et al.Chemical and toxicological characterization of an unresolved complex mixture-rich biodegraded crude oil[J].Environmental Toxicology and Chemistry,2009,28(9):1815-1824.
    [32] Frenzel M,Scarlett A,Rowland S J,et al.Complications with remediation strategies involving the biodegradation and detoxification of recalcitrant contaminant aromatic hydrocarbons[J].Science of the Total Environment,2010,408(19):4093-4101.
    [33] Quan Shi,Dujie Hou,Keng H Chung,et al.Characterization of heteroatom compounds in a crude oil and its saturates,aromatics,resins,and asphaltenes(SARA) and non-basic nitrogen fractions analyzed by negative-ion electrospray ionization fourier transform ion cyclotron resonance mass spectrometry[J]. Energy Fuels,2010,24(4):2545-2553.
    [34] Pomerantz A E,Ventura G T,McKenna A M,et al.Combining biomarker and bulk compositional gradient analysis to assess reservoir connectivity[J].Organic Geochemistry,2010,41(8):812-821.
    [35] Lewis C A,Rowland S J,Ellen N M,et al.How to get the hump[C]//24th International Meeting on Organic Geochemistry,Bremen,2009:367.
    [36] Rowland S J,Donkin P,Smith E J,et al.Aromatic hydrocarbon "humps" in themarine environment:Unrecognised toxins[J].Environment Science and Technology,2001,35(13):2640-2644.
    [37] Booth A M,Aitken C,Jones D M,et al.Resistance of toxic alkylcyclohexyltetralins to biodegradation byaerobie bacteria[J].Organic Geochemistry,2007,38(4):540-550.
    [38] Frenzel M.Persistence,bioremediation and fate of unresolved complex mixtures (UCMs) of hydrocarbons in the environment[D].Exeter,UK:University of Exeter,2008.
    [39] Smith E,Wraige E,Rowland S,et al.Hydrocarbon humps in the marine environment:synthesis,toxicity,and aqueous solubility of monoaromatic compounds[J].Environmental Toxicology and Chemistry, 2001,20 (11):2428-2432.
    [40] Scarlett A,Galloway T S,Rowland S J.Chronic toxicity of unresolved complex mixtures (UCM) of hydrocarbons in marine sediments[J].Journal of Soils and Sediments,2007,7(4):200-206.
    [41] Frenzel M,James P,Burton S K,et al.Towards bioremediation of toxic unresolved complex mixtures of hydrocarbons:identification of bacteria capable of rapid degradation of alkyltetralins[J].Journal of Soils and Sediments,2009,9(2):129-136.
    [42] Ventura G T,Simoneit B T,Nelson R K.Resolving the origin of unresolved complex mixtures in hydrothermal petroleum:novel methods for comprehensive two-dimensional gas chromatography[C]//24th International Meeting on Organic Geochemistry,Bremen,2009:316.
    [43] Reddy C M,Eglinton T I,Hounshell A,et al.The west Falmouth oil spill after thirty years:the persistence of petroleum hydrocarbons in marsh sediments[J]. Environment Science and Technology,2002,36(2):4754-4760.
  • 加载中
计量
  • 文章访问数:  3739
  • HTML全文浏览量:  83
  • PDF下载量:  1060
  • 被引次数: 0
出版历程
  • 收稿日期:  2010-08-18
  • 修回日期:  2011-04-04
  • 刊出日期:  2011-06-28

目录

    /

    返回文章
    返回