单体烃类包裹体在油气地球化学中的应用——以塔河油田为例

潘安阳; 秦建中; 姚素平; 腾格尔; 申宝剑

doi:10.11781/sysydz201705675

单体烃类包裹体在油气地球化学中的应用——以塔河油田为例

doi: 10.11781/sysydz201705675

1.
南京大学地球科学与工程学院, 南京 210093
2. 中国石化石油勘探开发研究院无锡石油地质研究所, 江苏无锡 214126

基金项目: 联合基金重点支持项目“古生界页岩含气性原生有机质控制作用研究”（U1663202）和中国石化科技部项目“海相页岩超显微特征及与页岩气富集的关系”（P15097）资助。

详细信息

作者简介:
潘安阳(1986—),男,博士后,从事烃源岩有机地球化学研究.E-mail:panay.syky@sinopec.com.

中图分类号: TE122.114
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出版历程
- 收稿日期: 2017-04-17
- 修回日期: 2017-08-03
- 刊出日期: 2017-09-28

Application of single hydrocarbon inclusions in petroleum geochemistry: A case study of the Tahe oilfield

1.
School of Earth Science and Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
2. Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi, Jiangsu 214126, China

摘要

摘要: 利用近年来发展的烃类包裹体研究新方法，综合分析了塔河油田油气成藏期次与油气来源特征。结果表明，塔河油田具有多期油气充注特征，其中海西中期和喜马拉雅晚期占优势，单体烃类包裹体激光剥蚀在线成分分析表明，早期原油（黄色荧光包裹体）具有饱和烃色谱呈双峰型、芳烃含量较高的特征，属于成熟度相对较低的中质原油；而晚期原油（蓝色荧光包裹体）具有饱和烃呈单主峰型、芳烃含量较低的特征，属成熟中晚期轻质原油。结合研究区原油的来源或烃源岩沉积环境、成烃生物、成熟度、运移距离和成藏过程及时间，推测早期原油主要来源于下寒武统—下奥陶统优质烃源岩，晚期原油主要来自上奥陶统碳酸盐岩烃源岩。
- 烃类包裹体 /
- 成藏期次 /
- 生物标志化合物 /
- 油气来源 /
- 塔河油田
Abstract: The hydrocarbon accumulation period and petroleum source characteristics in the Tahe oilfield were discussed using the newly developed methods for hydrocarbon inclusion analyses. The results confirmed that there were many stages of hydrocarbon accumulation in the Tahe oilfield, especially predominated by the Middle Hercynian and the Late Himalayan. The online laser ablation compositional analyses of single hydrocarbon inclusion showed that the early oil (yellow fluorescing inclusion) was characterized by bimodal n-alkane distribution and higher aromatic component content, belonging to medium crude oil with relatively lower maturity. In contrast, the late oil (blue fluorescing inclusion) was featured by unimodal n-alkane distribution and lower aromatic component content, belonging to late light crude oil at the middle-late mature stage. Based on the petroleum source or sedimentary environment of source rocks, hydrocarbon-forming organisms, maturity, migration distance, accumulation process and period, the early oil was suggested mainly from -C₁-O₁excellent source rocks and the late oil was mainly from O₃ carbonate source rocks.
- hydrocarbon inclusion /
- hydrocarbon accumulation period /
- biomarker /
- petroleum source /
- Tahe oilfield

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参考文献(42)

[1]	Burruss R C.Hydrocarbon fluid inclusions in studies of sedimentary diagenesis[M]//Hollister L S,Crawford M L.Fluid inclusions:App-lications to petrology.Canada:Mineralogical Association of Canada,1981:138-156.
[2]	Roedder E.Fluid inclusions[J].Reviews in Mineralogy,1984,12:251-290.
[3]	Mclimans R K.The application of fluid inclusions to migration of oil and diagenesis in petroleum reservoirs[J].Applied Geoche-mistry,1987,2(5/6):585-603.
[4]	Bodnar R J.Petroleum migration in the Miocene Monterey Formation,California,USA:Constraints from fluid-inclusion studies[J].Minera-logical Magazine,1990,54(375):295-304.
[5]	Guilhaumou N,Szydlowskii N,Pradier B.Characterization of hydrocarbon fluid inclusions by infra-red and fluorescence microspectro-metry[J].Mineralogical Magazine,1990,54(375):311-324.
[6]	Moser M R,Rankin A H,Milledge H J.Hydrocarbon-bearing fluid inclusions in fluorite associated with the Windy Knoll bitumen deposit,UK[J].Geochimica et Cosmochimica Acta,1992,56(1):155-168.
[7]	刘德汉,卢焕章,肖贤明.油气包裹体及其在石油勘探和开发中的应用[M].广州:广东科技出版社,2007. Liu Dehan,Lu Huanzhang,Xiao Xianming.Application of hydrocarbon inclusions in petroleum exploration and development[M].Guangzhou:Guangdong Science & Technology Press,2007.
[8]	刘德汉,肖贤明,田辉,等.含油气盆地中流体包裹体类型及其地质意义[J].石油与天然气地质,2008,29(4):491-501. Liu Dehan,Xiao Xianming,Tian Hui,et al.Fluid inclusion types and their geological significance in petroliferous basins[J].Oil & Gas Geology,2008,29(4):491-501.
[9]	George S C,Lisk M,Eadington P J,et al.Comparison of palaeo oil charges with currently reservoired hydrocarbons using the geochemistry of oil-bearing fluid inclusions[C]//SPE Asia Pacific Oil and Gas Conference.Adelaide,Australia:Society of Petroleum Engineers,1996:159-171.
[10]	George S C,Lisk M,Eadington P J,et al.Fluid inclusion record of early oil preserved at Jabiru Field,Vulcan Sub-basin[J].Exploration Geophysics,1997,28(2):66-71.
[11]	George S C,Volk H,Ahmed M.Geochemical analysis techniques and geological applications of oil-bearing fluid inclusions,with some Australian case studies[J].Journal of Petroleum Science and Engineering,2007,57(1/2):119-138.
[12]	王爱国,衣丽萍,石磊,等.单个油包裹体组分研究进展[J].石油实验地质,2015,37(2):226-230. Wang Aiguo,Yi Liping,Shi Lei,et al.Research progress on composition of individual oil inclusion[J].Petroleum Geology & Experiment,2015,37(2):226-230.
[13]	王波,杨海风,王孝辕,等.黄河口凹陷陡坡带B27构造古近系油气成藏期:基于流体包裹体的证据[J].断块油气田,2016,23(6):693-696. Wang Bo,Yang Haifeng,Wang Xiaoyuan,et al.Paleogene accumulation period in B27 Structure of northern steep slope belt,Huanghekou Sag: based on evidence from fluid inclusions[J].Fault-Block Oil and Gas Field, 2016,23(6):693-696.
[14]	马安来,金之钧,王毅.塔里木盆地台盆区海相油源对比存在的问题及进一步工作方向[J].石油与天然气地质,2006,27(3):356-362. Ma Anlai,Jin Zhijun,Wang Yi.Problems of oil-source correlation for marine reservoirs in Paleozoic craton area in Tarim Basin and future direction of research[J].Oil & Gas Geology,2006,27(3):356-362.
[15]	周永昌,杨国龙.塔里木盆地阿克库勒地区油气地质特征及勘探前景[J].石油学报,2001,22(3):1-5. Zhou Yongchang,Yang Guolong.The character and prospect of the petroleum geology of the area of Akekule in Tarim basin[J].Acta Petrolei Sinica,2001,22(3):1-5.
[16]	张水昌,王飞宇,张保民,等.塔里木盆地中上奥陶统油源层地球化学研究[J].石油学报,2000,21(6):23-28. Zhang Shuichang,Wang Feiyu,Zhang Baomin,et al.Middle-Upper Ordovician source rock geochemistry of the Tarim Basin[J].Acta Petrolei Sinica,2000,21(6):23-28.
[17]	张水昌,赵文智,王飞宇,等.塔里木盆地东部地区古生界原油裂解气成藏历史分析:以英南2气藏为例[J].天然气地球科学,2004,15(5):441-451. Zhang Shuichang,Zhao Wenzhi,Wang Feiyu,et al.Paleozoic oil cracking gas accumulation history from eastern part of the Tarim Basin:A case study of the YN2 gas reservoir[J].Natural Gas Geoscience,2004,15(5):441-451.
[18]	顾忆,丁勇,陈跃,等.新疆塔里木盆地塔河油区成藏历史与成藏机制研究[R].无锡:中国石化石油勘探开发研究院无锡实验地质研究所,2000. Gu Yi,Ding Yong,Chen Yue,et al.The study of the reservoir-formed history and mechanism of Tahe Oilfield in Tarim Basin,Xinjiang[R].Wuxi:Wuxi Research Institute of Petroleum Geology,SINOPEC Petroleum Exploration & Production Research Institute,2000.
[19]	王铁冠,何发歧,王春江.塔河油田奥陶系油气藏成藏地球化学研究[R].北京:中国石油大学(北京),2003. Wang Tieguan,He Faqi,Wang Chunjiang.Geochemistry of Tahe Ordovician reservoir[R].Beijing:China University of Petroleum (Beijing),2003.
[20]	顾忆.塔里木盆地北部塔河油田油气藏成藏机制[J].石油实验地质,2000,22(4):307-312. Gu Yi.Forming mechanism of hydrocarbon pools in Tahe oilfield of the northern Tarim Basin[J].Experimental Petroleum Geo-logy,2000,22(4):307-312.
[21]	钱一雄.塔河油田下奥陶统储层中流体包裹体成份[J].地质科学,2002,37(S):22-28. Qian Yixiong.Chemical composition of fluid inclusions from the lower Ordovician reservoirs in the Tahe oil field[J].Chinese Journal of Geology,2002,37(S):22-28.
[22]	王铁冠,王春江,何发岐,等.塔河油田奥陶系油藏两期成藏原油充注比率测算方法[J].石油实验地质,2004,26(1):74-79. Wang Tieguan,Wang Chunjiang,He Faqi,et al.Determination of double filling ratio of mixed crude oils in the Ordovician oil reservoir,Tahe oilfield[J].Petroleum Geology & Experiment,2004,26(1):74-79.
[23]	李纯泉,陈红汉,张希明,等.塔河油田奥陶系储层流体包裹体研究[J].石油学报,2005,26(1):42-46. Li Chunquan,Chen Honghan,Zhang Ximing,et al.Fluid inclusions analysis of the Ordovician reservoir in Tahe oilfield[J].Acta Petrolei Sinica,2005,26(1):42-46.
[24]	殷和平,钱一雄,陈强路,等.流体包裹体主要成分及谱学特征研究:以塔河油区下奥陶统储层为例[J].石油实验地质,2009,31(3):282-286. Yin Heping,Qian Yixiong,Chen Qianglu,et al.Approaching to chemical composition and application of Raman spectrum of fluid inclusion:Taking the Lower Ordovician reservoirs in Tahe as an example[J].Petroleum Geology & Experiment,2009,31(3):282-286.
[25]	范昱,何新明,汪彦,等.塔河油田主体区奥陶系流体包裹体特征及油气成藏研究[J].新疆地质,2013,31(S):116-121. Fan Yu,He Xinming,Wang Yan,et al.The characteristics of fluid inclusion and oil and gas accumulation of Ordovician in main area,Tahe Oilfield[J].Xinjiang Geology,2013,31(S):116-121.
[26]	杨爱玲.单个油气包裹体检测技术及应用[D].青岛:中国海洋大学,2010. Yang Ailing.A testing technique for single hydrocarbon inclusions and its applications[D].Qingdao:Ocean University of China,2010.
[27]	Zhang Zhirong,Greenwood P,Zhang Qu,et al.Laser ablation GC-MS analysis of oil-bearing fluid inclusions in petroleum reservoir rocks[J].Organic Geochemistry,2012,43:20-25.
[28]	施伟军,席斌斌,秦建中,等.单体油气包裹体激光剥蚀在线成分分析技术:以塔河油田奥陶系储层为例[J].石油学报,2016,37(2):196-206. Shi Weijun,Xi Binbin,Qin Jianzhong,et al.Online laser ablation compositional analysis technique for single hydrocarbon inclusion:A case study of the Ordovician reservoirs in Tahe oilfield,Tarim Basin,NW China[J].Acta Petrolei Sinica,2016,37(2):196-206.
[29]	饶丹,秦建中,许锦,等.塔河油田奥陶系油藏成藏期次研究[J].石油实验地质,2014,36(1):83-88. Rao Dan,Qin Jianzhong,Xu Jin,et al.Accumulation periods of Ordovician reservoirs in Tahe Oil Field[J].Petroleum Geology & Experiment,2014,36(1):83-88.
[30]	国家能源局.沉积盆地流体包裹体显微测温方法:SY/T 6010-2011[S].北京:石油工业出版社,2011. National Energy Board.Test method for fluid inclusion in sedimentary basins by microthermometry:SY/T 6010-2011[S].Beijing:Petroleum Industry Press,2011.
[31]	Greenwood P F,George S C,Hall K.Applications of laser micropyrolysis-gas chromatography-mass spectrometry[J].Organic Geochemistry,1998,29(5/7):1075-1089.
[32]	Volk H,Fuentes D,Fuerbach A,et al.First on-line analysis of petroleum from single inclusion using ultrafast laser ablation[J].Organic Geochemistry,2010,41(2):74-77.
[33]	Siljeström S,Volk H,George S C,et al.Analysis of single oil-bearing fluid inclusions in mid-Proterozoic sandstones (Roper Group,Australia)[J].Geochimica et Cosmochimica Acta,2013,122:448-463.
[34]	George S C,Ruble T E,Dutkiewicz A,et al.Assessing the maturity of oil trapped in fluid inclusions using molecular geochemistry data and visually-determined fluorescence colors[J].Applied Geoche-mistry,2001,16(4):451-473.
[35]	Stasiuk L D,Snowdon L R.Fluorescence micro-spectrometry of synthetic and natural hydrocarbon fluid inclusions:Crude oil chemistry,density and application to petroleum migration[J].Applied Geochemistry,1997,12(3):229-241.
[36]	Peters K E,Fraser T H,Amris W,et al.Geochemistry of crude oils from Eastern Indonesia[J].AAPG Bulletin,1999,83(12):1927-1942.
[37]	Hanson A D,Zhang S C,Moldowan J M,et al.Molecular organic geochemistry of the Tarim Basin,Northwest China[J].AAPG Bulletin,2000,84(8):1109-1128.
[38]	刘斌,沈昆.流体包裹体热力学[M].北京:地质出版社,1999. Liu Bin,Shen Kun.Thermodynamics of fluid inclusions[M].Beijing:Geological Publishing House,1999.
[39]	卢焕章,范宏瑞,倪培,等.流体包裹体[M].北京:科学出版社,2004. Lu Huanzhang,Fan Hongrui,Ni Pei,et al.Fluid inclusion[M].Beijing:Science Press,2004.
[40]	饶丹. 油气包裹体成分分析技术方法的完善与应用[R].无锡：中石化石油勘探开发研究院无锡石油地质研究所，2011. Rao Dan. Improvement and application of hydrocarbon inclusions component analysis technique[R]. Wuxi: Wuxi Institute of Petroleum Geology, Petroleum Exploration & Production Research Institute, SINOPEC, 2011.
[41]	李慧莉,邱南生,金之钧,等.塔里木盆地的热史[J].石油与天然气地质,2005,26(5):613-617. Li Huili,Qiu Nansheng,Jin Zhijun,et al.Geothermal history of Tarim Basin[J].Oil & Gas Geology,2005,26(5):613-617.
[42]	王劲骥,潘长春,姜兰兰,等.塔中4油田石炭系储层不同赋存态烃类分子和碳同位素对比研究[J].地球化学,2010,39(5):479-490. Wang Jinji,Pan Changchun,Jiang Lanlan,et al.Molecular and carbon isotope correlation of free,adsorbed and inclusion oils from the Carboniferous sandstone in the Tazhong-4 oilfield[J].Geochimica,2010,39(5):479-490.