准噶尔盆地腹部地区原油金刚烷化合物特征及应用

李二庭; 陈俊; 迪丽达尔&#183;肉孜; 高秀伟; 米巨磊; 马万云

doi:10.11781/sysydz201904569

准噶尔盆地腹部地区原油金刚烷化合物特征及应用

doi: 10.11781/sysydz201904569

1. 中国石油新疆油田分公司实验检测研究院, 新疆克拉玛依 834000;
2. 新疆砾岩油藏实验室, 新疆克拉玛依 834000

详细信息

作者简介:
李二庭(1988-),男,高级工程师,地球化学专业。E-mail:lierting@petrochina.com.cn。

中图分类号: TE122.1
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出版历程
- 收稿日期: 2018-09-29
- 修回日期: 2019-05-14
- 刊出日期: 2019-07-28

Characteristics of diamondoids in crude oil and its application in hinterland of Junggar Basin

LI Erting^1,2,
CHEN Jun^1,2,
ROUZI Dilidaer^1,2,
GAO Xiuwei^1,2,
MI Julei^1,2,
MA Wanyun^1,2

1. Research Institute of Experiment and Testing, Xinjiang Oilfield Company, PetroChina, Karamay, Xinjiang 834000, China;
2. Xinjiang Laboratory of Petroleum Reserve in Conglomerate, Karamay, Xinjiang 834000, China

摘要

摘要: 利用色谱/质谱/质谱方法分析了准噶尔盆地腹部地区原油中金刚烷化合物的含量，探讨了金刚烷参数指标在腹部地区原油类型划分和成熟度判识中的适用性。腹部地区原油中金刚烷类化合物含量较低，主要分布在（200~500）×10^-6。利用金刚烷类化合物浓度指标能够有效划分原油的类型，金刚烷异构化指标能够有效判识原油的成熟度。腹部地区原油主要分为两大类：Ⅰ类原油为早期相对低熟原油，金刚烷类化合物含量低，单金刚烷含量相对较高，浓度指标A/1-MA比值分布在0.50~0.71，成熟度指标MAI值较小，在0.41~0.50之间，主要分布在远离生烃凹陷区域；Ⅱ类原油为晚期相对高熟油，金刚烷类化合物含量较高，1-甲基单金刚烷含量较高，A/1-MA比值分布在0.30~0.37，MAI值在0.52~0.69之间，主要分布在生烃凹陷内，其分布格局与油气运移方向一致，即晚期充注的原油驱动早期充注的原油向远离生烃凹陷处运移，证实了腹部原油运移方向为盆1井西凹陷向北运移。
- 金刚烷 /
- 成熟度 /
- 原油类型 /
- 准噶尔盆地
Abstract: The content of diamondoids in crude oil from the hinterland of Junggar Basin was analyzed by GC, MS and GC-MS methods. The applicability of diamondoid indices to identify and evaluate oil maturity was discussed. The diamondoid content in crude oil is (200-500)×10^-6. The concentration index of diamondoids can classify oil types effectively, and the adamantane isomerization index can be used to evaluate oil maturity. The oil in the hinterland of Junggar Basin can be divided into two types. Type I oils were generated early with relatively lower maturity and lower content of diamondoids. The content of adamantane is relatively higher. The concentration index A/1-MA ratio is distributed in the range of 0.50-0.71, and the maturity index MAI value is smaller, between 0.41 and 0.50, which is far away from the hydrocarbon source depression. Type Ⅱ oils were generated late with relatively higher maturity and higher content of diamondoids. The content of 1-methyladamantane is higher. The ratio of A/1-MA is in the range of 0.30-0.37, and the MAI value is between 0.52 and 0.69, which fall within the hydrocarbon source depression. The distribution pattern is consistent with the direction of oil migration. That is, the late filling oil displaced the early filling oil away from the hydrocarbon generation depression, which proves that the oil in the hinterland area migrated from the area of the well Pen 1 sag to the north.
- diamondoid /
- maturity /
- oil type /
- Junggar Basin

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参考文献(24)

[1]	VON R SCHLEYER P.My thirty years in hydrocarbon cages:from adamantane to dodecahedrane[M]//OLAH G A.Cage Hydrocarbons.New York:Wiley-Interscience,1990:1-38.
[2]	WILLIAMS J A,BJORØY M,DOLCATER D L,et al.Biodegradation in South Texas Eocene oils:effects on aromatics and biomarkers[J].Organic Geochemistry,1986,10(1/3):451-461.
[3]	梁前勇,熊永强,房忱琛,等.两种测定原油中金刚烷类化合物方法的对比研究[J].地球化学,2012,41(5):433-441. LIANG Qianyong,XIONG Yongqiang,FANG Chenchen,et al.Comparison of two methods for the determination of diamondoids in crude oils[J].Geochimica,2012,41(5):433-441.
[4]	王汇彤,张水昌,翁娜,等.凝析油全二维气相色谱分析[J].石油勘探与开发,2012,39(1):123-128. WANG Huitong,ZHANG Shuichang,WENG Na,et al.Analysis of condensate oil by comprehensive two-dimensional gas chromatography[J].Petroleum Exploration and Development,2012,39(1):123-128.
[5]	曾凡刚,程克明.利用双金刚烷指标研究下古生界海相碳酸盐岩的热成熟度[J].地质地球化学,1998,26(3):16-20. ZENG Fangang,CHENG Keming.Thermal maturity of Lower Palaeozoic marine carbonate rocks:a double adamantane index study[J].Geology-Geochemistry,1998,26(3):16-20.
[6]	STOUT S A,DOUGLAS G S.Diamondoid hydrocarbons:application in the chemical fingerprinting of natural gas condensate and gasoline[J].Environmental Forensics,2004,5(4):225-235.
[7]	DAHL J E,MOLDOWAN J M,PETERS K E,et al.Diamondoid hydrocarbons as indicators of natural oil cracking[J].Nature,1999,399(6731):54-57.
[8]	GRICE K,ALEXANDER R,KAGI R I.Diamondoid hydrocarbon ratios as indicators of biodegradation in Australian crude oils[J].Organic Geochemistry,2000,31(1):67-73.
[9]	SCHULZ L K,WILHELMS A,REIN E,et al.Application of diamondoids to distinguish source rock facies[J].Organic Geoche-mistry,2001,32(3):365-375.
[10]	任康绪,黄光辉,肖中尧,等.大宛齐原油金刚烷类化合物及其在油气运移中的应用[J].中国石油勘探,2012,17(2):27-31. REN Kangxu,HUANG Guanghui,XIAO Zhongyao,et al.Application of diamondoids to hydrocarbon migration in Dawanqi Oilfield,Tarim Basin[J].China Petroleum Exploration,2012,17(2):27-31.
[11]	陈建平,王绪龙,邓春萍,等.准噶尔盆地烃源岩与原油地球化学特征[J].地质学报,2016,90(1):37-67. CHEN Jianping,WANG Xulong,DENG Chunping,et al.Geoche-mical features of source rocks and crude oil in the Junggar Basin,northwest China[J].Acta Geologica Sinica,2016,90(1):37-67.
[12]	杨帆,侯连华,卫延召,等.准噶尔盆地腹部石南21油藏、石南31油藏新认识[J].中国矿业大学学报,2015,44(4):696-703. YANG Fan,HOU Lianhua,WEI Yanzhao,et al.New perspective on Shinan 21 and Shinan 31 reservoirs in the central Junggar Basin[J].Journal of China University of Mining & Technology,2015,44(4):696-703.
[13]	石好果.准噶尔盆地腹部阜康深凹带侏罗系成藏规律[J].石油实验地质,2017,39(2):238-246. SHI Haoguo.Jurassic reservoir development in Fukang Deep Sag, Central Junggar Basin[J]. Petroleum Geology & Experiment, 2017, 39(2):238-246.
[14]	陶国亮,胡文瑄,曹剑,等.准噶尔盆地腹部二叠系混源油油源组成与聚集特征研究[J].南京大学学报(自然科学版),2008,44(1):42-49. TAO Guoliang,HU Wenxuan,CAO Jian,et al.Source composition and accumulation characteristics of Permian mixed oils in central Junggar Basin,NW China[J].Journal of Nanjing University (Natural Sciences),2008,44(1):42-49.
[15]	张学军,徐兴友,彭平安.车排子凸起轻质油成熟度分析与烃源层再认识[J].地球化学,2013,42(2):180-187. ZHANG Xuejun,XU Xingyou,PENG Pingan.Maturity assessment of light oils in Chepaizi Uplift and re-understanding of its source rock[J].Geochimica,2013,42(2):180-187.
[16]	JIANG Wenmin,LI Yun,XIONG Yongqiang.Source and thermal maturity of crude oils in the Junggar Basin in northwest China determined from the concentration and distribution of diamondoids[J].Organic Geochemistry,2019,128:148-160.
[17]	赵文,郭小文,何生.生物标志化合物成熟度参数有效性:以伊通盆地烃源岩为例[J].西安石油大学学报(自然科学版),2016,31(6):23-31. ZHAO Wen,GUO Xiaowen,HE Sheng.Analysis on validity of maturity parameters of biomarkers:a case study from source rocks in Yitong Basin[J].Journal of Xi'an Shiyou University (Natural Science Edition),2016,31(6):23-31.
[18]	陈菊林,张敏.烃源岩热模拟实验中重排藿烷类化合物变化特征及其意义[J]. 石油实验地质, 2016,38(5):672-678. CHEN Julin,ZHANG Min. Features and significance of rearranged hopanes in pyrolyzates of hydrocarbon source rocks[J]. Petroleum Geology & Experiment,2016,38(5):672-678.
[19]	SEIFERT W K,MOLDOWAN J M.Use of biological markers in petroleum exploration[M]//JOHNS R B.Methods in Geoche-mistry and Geophysics.Amsterdam:Elsevier,1986:261-290.
[20]	RADKE M,WELTE D H,WILLSCH H.Geochemical study on a well in the Western Canada Basin:relation of the aromatic distribution pattern to maturity of organic matter[J].Geochimica et Cosmochimica Acta,1982,46(1):1-10.
[21]	孔婷,张敏.C₄-C₈轻烃在原油地球化学研究中的应用:以塔里木盆地大宛齐油田凝析油为例[J].石油实验地质,2017,39(4):535-543. KONG Ting,ZHANG Min.Application of C₄-C₈ light hydrocarbons in geochemical studies:a case of condensates in Dawanqi Oil Field,Tarim Basin[J].Petroleum Geology & Experiment,2017,39(4):535-543.
[22]	LIANG Qianyong,XIONG Yongqiang,FANG Chenchen,et al.Quantitative analysis of diamondoids in crude oils using Gas Chromatography-Triple Quadrupole Mass Spectrometry[J].Organic Geochemistry,2012,43:83-91.
[23]	邹华耀,郝芳,张柏桥,等.准噶尔盆地腹部油气充注与再次运移研究[J].地质科学,2005,40(4):499-509. ZOU Huayao,HAO Fang,ZHANG Boqiao,et al.History of hydrocarbon-filling and remigrating in hinterland of the Junggar Basin[J].Chinese Journal of Geology,2005,40(4):499-509.
[24]	石好果,林会喜.准中4区块侏罗系储层成岩及油气充注特征研究[J]. 特种油气藏,2017,24(6):18-22. SHI Haoguo, LIN Huixi.Study on the characteristics of Jurassic reservoir diagenesis and hydrocarbon filling in middle 4 block of Jungar Basin[J]. Special Oil & Gas Reservoirs,2017,24(6):18-22.