四川盆地五峰组—龙马溪组页岩气成因与碳同位素倒转机制——来自热模拟实验的认识

马中良; 申宝剑; 潘安阳; 腾格尔; 宁传祥; 郑伦举

doi:10.11781/sysydz202003428

四川盆地五峰组—龙马溪组页岩气成因与碳同位素倒转机制——来自热模拟实验的认识

doi: 10.11781/sysydz202003428

马中良^{1, 2, 3,},
申宝剑^{1, 2, 3},
潘安阳^{1, 2, 3},
腾格尔⁴,
宁传祥^{1, 2, 3},
郑伦举^{1, 2, 3}

1.
页岩油气富集机理与有效开发国家重点实验室, 江苏无锡 214126
2.
中国石油化工集团公司油气成藏重点实验室, 江苏无锡 214126
3.
中国石化石油勘探开发研究院无锡石油地质研究所, 江苏无锡 214126
4.
中国地质调查局油气资源调查中心, 北京 100083

基金项目:

国家科技重大专项 2017ZX05036-002-004

国家科技重大专项 2017ZX05005-001-003

国家自然科学基金 U1663202

国家自然科学基金 41690133

详细信息

作者简介:
马中良(1984-), 男, 高级工程师, 从事油气地球化学和非常规油气地质研究。E-mail: mazl.syky@sinopec.com

中图分类号: TE135
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- 被引次数: 0
出版历程
- 收稿日期: 2020-01-24
- 修回日期: 2020-04-17
- 刊出日期: 2020-05-28

Origin and carbon isotope reversal of shale gas in Wufeng-Longmaxi formations, Sichuan Basin: implication from pyrolysis experiments

MA Zhongliang^{1, 2, 3
,},
SHEN Baojian^{1, 2, 3},
PAN Anyang^{1, 2, 3},
BORJIGIN Tenger⁴,
NING Chuanxiang^{1, 2, 3},
ZHENG Lunju^{1, 2, 3}

1.
State Key Laboratory of Shale Oil and Gas Enrichment and Effective Development, Wuxi, Jiangsu 214126, China
2.
SINOPEC Key Laboratory of Petroleum Accumulation Mechanisms, Wuxi, Jiangsu 214126, China
3.
Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi, Jiangsu 214126, China
4.
Oil and Gas Survey, China Geological Survey, Beijing 100083, China

摘要

摘要: 四川盆地上奥陶统五峰组-下志留统龙马溪组是国内目前唯一实现页岩气商业性开发的层系，但目前对页岩气成因仍有一定分歧，主要原因是缺乏直接的实验证据。通过对国内外上奥陶统-下志留统低、中成熟度页岩和笔石开展黄金管生烃热模拟实验研究发现：（1）五峰组-龙马溪组页岩气主体以浮游藻类等富氢、富脂质有机质生成的油进一步滞留裂解为主，笔石生油能力较差，高-过成熟演化阶段有一定的生气能力，最高可达浮游藻类等富氢、富脂质有机质生气能力的20%左右；（2）五峰组-龙马溪组页岩下部层位由于富集浮游藻类、疑源类等富氢、富脂质有机质等生烃能力更强的有机质，从生气量上就优于上部以笔石为主的层位，这是下部为商业性页岩气层的一个重要原因；（3）单纯的热演化分馏、原油裂解气和干酪根裂解气的混合未造成烃气碳同位素倒转，地层抬升作用、地层水、矿物、金属等对页岩气中烃类的后期改造可能是造成页岩气同位素倒转的重要原因，碳同位素倒转可能更多体现了页岩气后期保存过程的影响。
- 页岩气成因 /
- 同位素倒转 /
- 五峰组—龙马溪组 /
- 热模拟实验 /
- 四川盆地
Abstract: The Wufeng-Longmaxi shale in the Sichuan Basin is the only stratum in China to realize commercial development of shale gas. There are some differences in shale gas generation and a lack of direct experimental evidence of the reasons for these differences. Hydrocarbon generation experiments using pyrolysis in a gold tube with low and medium maturity shale and graptolite of O₃-S₁ were carried out. Gas from remaining oil produced by hydrogen-rich and lipid-rich organic matter such as planktonic algae is the main contributor of shale gas in the Wufeng-Longmaxi formations. The oil generation ability of graptolite is poor, and it can produce gas during the high-maturity and over-mature stages, up to about 20% of the hydrogen-rich and lipid-rich organic matter such as algae. The lower layer of the Wufeng-Longmaxi shale in the Sichuan Basin is superior to the upper layer, which is mainly composed of graptolite, because of abundant hydrogen-rich and lipid-rich organic matter such as phytoplankton. Pure thermal evolution fractionation and the mixture of primary (from kerogen) and secondary (from oil) gas do not cause hydrocarbon gas isotopes to "reverse". Formation uplift, formation water, minerals, metals and other late transformation of hydrocarbons in shale gas may be an important cause of shale gas isotopic "inversion". Carbon isotope "inversion" may be more of a reflection of the later shale gas preservation process.
- shale gas genesis /
- isotope reversal /
- Wufeng-Longmaxi formations /
- pyrolysis experiment /
- Sichuan Basin

HTML全文

图 1 样品热模拟实验油产率

Figure 1. Oil yield of pyrolysis experiments

下载: 全尺寸图片幻灯片

图 2 样品热模拟实验烃气产率

Figure 2. Hydrocarbon gas yield of pyrolysis experiments

下载: 全尺寸图片幻灯片

图 3 四川盆地下志留统龙马溪组页岩TOC值和有机显微组分比例纵向分布

据参考文献[5]修改。

Figure 3. TOC and organic macerals distribution of Lower Silurian Longmaxi shale, Sichuan Basin

下载: 全尺寸图片幻灯片

图 4 热模拟实验烃气与四川盆地五峰组—龙马溪组页岩气碳同位素对比

Figure 4. Comparison of carbon isotopes between hydrocarbon gas of pyrolysis experiments and shale gas of Wufeng-Longmaxi formations in Sichuan Basin

下载: 全尺寸图片幻灯片

表 1 样品基础地球化学参数

Table 1. Geochemical parameters of samples

样品编号	样品性质	地质年代	w(TOC)/%	S₁+S₂/(mg·g^-1)	T_max/℃	I_H/(mg·g^-1)	R_b/%
MB-3	笔石	S₁l	71.34	75.54	456	86	1.10
O-1	笔石	O₃	71.47	134.64	437	165	0.84
G-3	黑色页岩	S₁	7.14	36.92	437	467	0.56

下载: 导出CSV

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