鄂尔多斯盆地南部张家滩油页岩生烃演化特征

高波; 武晓玲; 张英; 陈新军; 边瑞康; 李倩文

doi:10.11781/sysydz202201024

鄂尔多斯盆地南部张家滩油页岩生烃演化特征

doi: 10.11781/sysydz202201024

高波^{1, 2, 3,},
武晓玲³,
张英³,
陈新军³,
边瑞康^{1, 2, 3},
李倩文³

1.
页岩油气富集机理与有效开发国家重点实验室, 北京 100083
2.
中国石化页岩油气勘探开发重点实验室, 北京 100083
3.
中国石化石油勘探开发研究院, 北京 100083

基金项目:

国家科技重大专项 2017ZX05036-004-004

中国石化科技开发部项目 P20049-1

详细信息

作者简介:
高波(1969-), 男, 博士, 研究员, 从事非常规油气地质、地球化学研究。E-mail: gaobo.syky@sinopec.com

中图分类号: TE122.1
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出版历程
- 收稿日期: 2021-03-25
- 修回日期: 2021-11-30
- 刊出日期: 2022-01-28

Hydrocarbon generation and evolution characteristics of Triassic Zhangjiatan oil shale in southern Ordos Basin

GAO Bo^{1, 2, 3
,},
WU Xiaoling³,
ZHANG Ying³,
CHEN Xinjun³,
BIAN Ruikang^{1, 2, 3},
LI Qianwen³

1.
State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 100083, China
2.
Key Laboratory of Shale Oil/Gas Exploration & Production, SINOPEC, Beijing 100083, China
3.
SINOPEC Petroleum Exploration and Production Research Institute, Beijing 100083, China

摘要

摘要: 鄂尔多斯盆地南部上三叠统延长组张家滩油页岩不仅是重要的固体矿产资源，也是该盆地三叠系油气的主力烃源岩。对张家滩油页岩典型露头剖面、钻井岩心进行有机碳含量（TOC）、氯仿沥青“A”及族组分、含油率等相关测试分析表明，张家滩油页岩有机质丰度高，TOC介于5.11%~36.47%，平均16.15%，生烃潜量（S₀+S₁+S₂）介于16.58~230.98 mg/g，平均94.20 mg/g，氯仿沥青“A”介于0.42%~2.22%之间，平均1.25%，属于生烃条件极好的优质烃源岩；含油率高，介于3.52%~14.6%之间，平均8.16%，属于中高品质的油页岩；干酪根类型以Ⅰ—Ⅱ₁型为主，R_o介于0.43%~1.09%。综合利用野外露头剖面和钻井岩心样品，建立了盆地南部张家滩油页岩的热演化剖面，分析了氯仿抽提前、后油页岩的含油率变化及油页岩热演化过程中含油率、热解烃产物的变化特征，揭示鄂尔多斯盆地南部张家滩油页岩具有聚集油页岩、页岩油两类资源的潜力，提出了相应的勘探开发对策。
- 热演化 /
- 页岩油 /
- 张家滩油页岩 /
- 延长组 /
- 上三叠统 /
- 鄂尔多斯盆地南部
Abstract: The Zhangjiatan oil shale from the Upper Triassic Yanchang Formation in the southern Ordos Basin is an important solid mineral resource, it can also be considered as the main source rock of Triassic oil and gas in the basin. Results of analytical experiments such as TOC, bitumen extraction and group composition, oil content etc. of shale samples from key typical outcrop sections and drilling cores showed that the Zhangjiatan oil shale has a high organic matter abundance. The TOC content ranges 5.11% to 36.47%, with an average value of 16.15%. The S₀+S₁+S₂ value distributes between 16.58-230.98 mg/g, with an average value of 94.20 mg/g. The extracted bitumen abundance is between 0.42%-2.22%, with an average value of 1.25%. Based on these analytical results, Zhangjiatan oil shale can be assigned to be high-quality source rock with an excellent hydrocarbon generation potential. The oil content of oil shale is between 3.52% and 14.6%, with an average value of 8.16%, which belongs to medium- and high-quality oil shale. The kerogen type is mainly Ⅰ-Ⅱ₁, and the R_o value generally ranges from 0.43% to 1.09%. Based on field outcrop and drilling core samples, a thermal evolution profile of the Zhangjiatan oil shale in the southern Ordos Basin was established. Moreover, the oil contents of oil shale before and after solvent extraction were compared, and the variations of oil content and pyrolysis hydrocarbon products during the thermal evolution of oil shale were analyzed. There are two types of resources such as oil shale and shale oil in the Zhangjiatan oil shale with a great potential in the southern Ordos Basin. Moreover, some exploration and development countermeasures of oil shale and shale oil were put forward.
- thermal evolution /
- shale oil /
- Zhangjiatan oil shale /
- Yanchang Formation /
- Upper Triassic /
- southern Ordos Basin

HTML全文

图 1 鄂尔多斯盆地南部张家滩油页岩厚度分布

据文献[15]修改。

Figure 1. Thickness of Zhangjiatan oil shale in southern Ordos Basin

下载: 全尺寸图片幻灯片

图 2 鄂尔多斯盆地南部张家滩油页岩最高热解峰温(T_max)与氢指数(I_H)关系

青山口组、嫩江组和桦甸组油页岩数据据文献[19]。

Figure 2. I_H vs. T_max diagram indicating kerogen types and maturity range of Zhangjiatan oil shale in southern Ordos Basin

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图 3 鄂尔多斯盆地南部张家滩油页岩与陆相页岩储层矿物组分对比

图中张家滩油页岩来自何家坊地区，长7段页岩和山1段页岩数据据文献[22]。

Figure 3. Mineral composition of Zhangjiatan oil shale and continental shale reservoir in southern Ordos Basin

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图 4 鄂尔多斯盆地南部张家滩油页岩含油率和含硫量分布

Figure 4. Distribution of oil and sulfur contents of Zhangjiatan oil shale in southern Ordos Basin

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图 5 鄂尔多斯盆地南部张家滩油页岩抽提前、后含油率随R_o变化对比

Figure 5. Comparison of oil content with R_o before and after extraction of Zhangjiatan oil shale in southern Ordos Basin

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图 6 鄂尔多斯盆地南部张家滩油页岩含油率与相关参数关系

Figure 6. Relationship between oil content and related parameters of Zhangjiatan oil shale in southern Ordos Basin

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图 7 鄂尔多斯盆地张家滩油页岩自然剖面的热演化特征

Figure 7. Thermal evolution characteristics of natural profile of Zhangjiatan oil shale in Ordos Basin

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图 8 鄂尔多斯盆地南部张家滩油页岩与页岩油资源分布

Figure 8. Distribution of Zhangjiatan oil shale and shale oil resources in southern Ordos Basin

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表 1 鄂尔多斯盆地南部张家滩油页岩地球化学特征统计

Table 1. Geochemical characteristics of Zhangjiatan oil shale in southern Ordos Basin

地区	剖面/探井	ω(TOC)/%	ω(S)/%	(S₀+S₁+S₂)/(mg·g^-1)	氯仿沥青“A”/%	I_H/(mg·g^-1)	T_max/℃	R_o/%
旬宜	福地	$ \frac{{15.74\sim 27.74}}{{20.37(3)}}$	$ \frac{{0.45\sim 2.69}}{{1.31(3)}}$	$ \frac{{78.38\sim 105.57}}{{90.82(3)}}$	$ \frac{{0.93\sim 1.06}}{{1.01(3)}}$	$ \frac{{312\sim 576}}{{459(3)}}$	$ \frac{{432\sim 440}}{{437(3)}}$	$ \frac{{0.63\sim 0.68}}{{0.66(3)}}$
	霸王庄	$ \frac{{26.72\sim 36.47}}{{31.60(2)}}$	$ \frac{{2.81\sim 5.88}}{{4.35(2)}}$	$ \frac{{167.39\sim 230.98}}{{199.18(2)}}$	$ \frac{{1.52\sim 1.71}}{{1.62(2)}}$	$ \frac{{428\sim 815}}{{622(2)}}$	$ \frac{{433\sim 439}}{{436(2)}}$	$ \frac{{0.54\sim 0.59}}{{0.57(2)}}$
	何家坊	20.19	3.42	116.19	1.48	550	430	0.59
	前烈桥	27.08	0.61	122.29	0.72	436	430	0.51
	阎曲河	8.34	2.04	42.93	0.42	486	425	0.69
	贾曲河	9.35	1.19	35.42	0.51	363	428	0.43
	聂家河	$ \frac{{20.91\sim 33.71}}{{28.04(3)}}$	$ \frac{{0.82\sim 2.57}}{{1.53(3)}}$	$ \frac{{61.04\sim 150.87}}{{120.00(3)}}$	$ \frac{{0.46\sim 1.82}}{{1.27(3)}}$	$ \frac{{283\sim 485}}{{394(3)}}$	$ \frac{{426\sim 432}}{{430(3)}}$	$ \frac{{0.44\sim 0.47}}{{0.46(3)}}$
彬长	水北沟	$ \frac{{9.60\sim 9.95}}{{9.78(2)}}$	$ \frac{{0.75\sim 0.97}}{{0.86(2)}}$	$ \frac{{67.1\sim 159.99}}{{113.54(2)}}$	$ \frac{{0.83\sim 1.15}}{{0.99(2)}}$	$ \frac{{680\sim 1467}}{{1074(2)}}$	$ \frac{{432\sim 433}}{{433(2)}}$	$ \frac{{0.42\sim 0.43}}{{0.43(2)}}$
	JH4井	10.00	2.93	59.38	1.63	549	433	0.74
	JH6井	17.77	2.98	104.45	1.53	555	434	0.72
	JH60井	$ \frac{{7.40\sim 22.81}}{{13.13(3)}}$	$ \frac{{1.55\sim 2.32}}{{2.03(3)}}$	$ \frac{{57.60\sim 206.38}}{{113.67(3)}}$	$ \frac{{1.33\sim 1.66}}{{1.54(3)}}$	$ \frac{{757\sim 871}}{{799(3)}}$	$ \frac{{438\sim 439}}{{439(3)}}$	$ \frac{{0.6\sim 0.7}}{{>0.65(3)}}$3
镇泾	HH12井	13.75	2.17	114.17	1.22	780	443	0.61
	HH151井	6.24	0.55	46.30	1.24	730	448	0.67
	HH157井	5.44	0.44	42.00	1.05	733	446	0.7
	HH159井	6.41	1.58	39.01	1.07	574	438	0.74
富县	LH2井	6.81	2.39	16.58	1.54	202	449	0.84
富县	ZF25井	5.11	0.49	17.42	2.22	275	455	1.09
范围及平均值		$ \frac{{5.11\sim 36.47}}{{16.15(25)}}$	$ \frac{{0.44\sim 5.88}}{{1.83(25)}}$	$ \frac{{16.58\sim 230.98}}{{94.20(25)}}$	$ \frac{{0.42\sim 2.22}}{{1.25(25)}}$	$ \frac{{202\sim 1467}}{{583(25)}}$	$ \frac{{425\sim 455}}{{437(25)}}$	$ \frac{{0.42\sim 1.09}}{{0.63(25)}}$
注: 表中分式意义为$ \frac{{\left( {{\rm{最小值}}\sim {\rm{最大值}}} \right)}}{{\rm{平均值}}({\rm{样品数}})}$ 。

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表 2 鄂尔多斯盆地南部张家滩油页岩测试分析统计

Table 2. Testing data of Zhangjiatan oil shale in southern Ordos Basin

样品来源	样号	ω(TOC)/%	S₀/(mg·g^-1)	S₁/(mg·g^-1)	S₂/(mg·g^-1)	(S₀+S₁+S₂)/(mg·g^-1)	氯仿沥青“A”/%	饱和烃/%	芳烃/%	非烃/%	沥青质/%	含油率/%		R_o/%	T_max/℃
样品来源	样号	ω(TOC)/%	S₀/(mg·g^-1)	S₁/(mg·g^-1)	S₂/(mg·g^-1)	(S₀+S₁+S₂)/(mg·g^-1)	氯仿沥青“A”/%	饱和烃/%	芳烃/%	非烃/%	沥青质/%	抽提前	抽提后	R_o/%	T_max/℃
水北沟	SBG1	9.95	0.53	13.45	146.01	159.99	1.154	37.63	23.14	34.96	4.27	14.38	4.25	0.43	432
聂家河	NJH3	33.71	0.33	7.85	139.90	148.08	1.542	38.98	9.06	44.48	7.48	12.50	5.45	0.46	426
聂家河	NJH2	29.51	0.27	7.51	143.10	150.87	1.822	45.02	13.42	38.53	3.03	9.57	3.66	0.47	432
霸王庄	BWZ2	36.47	0.62	10.72	156.06	167.39	1.522	33.87	15.08	49.94	1.11	14.60	4.28	0.54	439
霸王庄	BWZ4	26.72	0.44	12.67	217.87	230.98	1.714	34.53	19.37	41.05	5.05	13.10	4.16	0.59	433
红河	HH12	13.75	0.45	6.51	107.22	114.17	1.222	32.96	33.79	25.43	7.82	11.35	3.05	0.61	443
泾河	JH60	22.81	0.91	6.89	198.58	206.38	1.663	33.15	20.66	38.08	8.11	12.35	2.42	0.63	439
福地	FD2	17.64	0.09	3.80	101.67	105.57	1.056	36.91	22.47	31.34	9.28	8.65	2.51	0.68	440
泾河	JH6	17.77	0.17	5.59	98.68	104.45	1.530	55.42	23.87	19.13	1.58	10.27	2.75	0.72	434
泾河	JH4	10.00	0.15	4.31	54.92	59.38	1.632	42.23	26.07	30.48	1.22	8.24	1.79	0.74	433
洛河	LH2	6.81	0.15	2.67	13.76	16.58	1.541	59.41	21.15	15.81	3.63	6.14	1.85	0.84	449
富县	ZF25	5.11	0.18	3.21	14.04	17.42	2.221	64.72	17.38	11.88	6.02	6.35	0.89	1.09	455

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