基于电子背散射衍射技术的纤维状方解石脉体晶体分析

赵兰全; 李志鹏; 邹开真; 马晓楠; 刘振阳; 尹鹤; 雷利庆; 禹宝军; 马存飞

doi:10.11781/sysydz202202357

基于电子背散射衍射技术的纤维状方解石脉体晶体分析

doi: 10.11781/sysydz202202357

1.
中国石化胜利油田勘探开发研究院, 山东东营 257100
2.
中国石油青海油田勘探开发研究院, 甘肃敦煌 736200
3.
中国石油大港油田采油五厂, 天津 300000
4.
中国石油新疆油田勘探开发研究院, 新疆克拉玛依 834000
5.
布鲁克(北京)科技有限公司, 上海 201100
6.
中国石油大学（华东）地球科学与技术学院, 山东青岛 266580

基金项目:

国家自然科学基金 41802172

国家自然科学基金 42172153

中央高校基本科研业务费专项 20CX02109A

详细信息

作者简介:
赵兰全(1981—)，男，高级工程师，从事石油地质综合研究工作。E-mail: zhaolanquan.slyt@sinopec.com

通讯作者:
马存飞(1987—)，男，博士，副教授，从事非常规油气储层和油气藏开发地质学的教学与科研工作。E-mail: mcf-625@163.com

中图分类号: TE122.23
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- 被引次数: 0
出版历程
- 收稿日期: 2021-03-29
- 修回日期: 2022-02-22
- 刊出日期: 2022-03-28

Crystal characteristics of fibrous calcite veins based on Electron Back Scattered Diffraction (EBSD)

1.
Exploration and Development Research Institute of Shengli Oil Field, SINOPEC, Dongying, Shandong 257100, China
2.
Exploration and Development Research Institute of Qinghai Oil Field, CNPC, Dunhuang, Gansu 736200, China
3.
No.5 Oil Production Plant of Dagang Oil Field, CNPC, Tianjin 300000, China
4.
Research Institute of Exploration and Development, Xinjiang Oilfield Company, PetroChina, Karamay, Xinjiang 834000, China
5.
Bruker (Beijing) Scientific Technology Co., Ltd., Shanghai 201100, China
6.
School of Geosciences, China University of Petroleum (East China), Qingdao, Shandong 266580, China

摘要

摘要: 方解石脉体广泛发育在富有机质页岩中，其岩石学特征和成因机制是研究的热点。电子背散射衍射技术能够原位表征矿物晶体的微观结构和晶体取向信息，而被广泛应用于材料科学领域，并在地质学领域得到了迅速发展。为了明确四川盆地龙马溪组富有机质页岩中纤维状方解石脉体的晶体特征，电子背散射衍射技术被用于表征方解石脉体的矿物学特征和结晶学特征。研究结果表明，方解石脉体的矿物组成为方解石和石英，其中方解石是主体，其晶粒的平均大小为372 μm；而石英主要分布在方解石纹层界面处。方解石脉体中的方解石晶体属于三方晶系或菱方晶系，相应的晶胞类型为三方晶胞或菱方晶胞，其晶格常数为a₀=b₀=4.99 Å，c₀=17.061 Å，α=β=90°，γ=120°。方解石脉体在纵剖面上具有一定的择优取向，原因是方解石晶粒内部发育聚片双晶，其中相邻的双晶条纹具有不同的晶体取向，晶体取向差为75°；而相间的双晶条纹具有相同的晶体取向，且同一双晶条纹的晶体取向相同。方解石晶粒内部发育完全解理，常成组出现且与双晶条纹呈锐夹角斜交，两者均是在方解石结晶过程中受到构造压扭作用产生的，其中最大主应力方向与双晶条纹平行。
- 电子背散射衍射技术 /
- 结晶学特征 /
- 矿物学特征 /
- 方解石脉体 /
- 页岩 /
- 四川盆地
Abstract: Calcite veins are widely developed in organic-rich shale, and their petrological characteristics and genetic mechanism are the focus of research. The Electron Back Scatter Diffraction (EBSD) can characterize the micro-structure and orientation of mineral crystals in situ, which has been widely used in the field of material science and has been rapidly developed in the field of geology. In order to clarify the crystal characte-ristics of fibrous calcite veins in organic-rich shale of the Longmaxi Formation in the Sichuan Basin, EBSD was used to characterize the mineralogical and crystallographic characteristics of calcite veins. The calcite veins are mainly composed of calcite and quartz. Calcite is the main body, with an average grain size of 372 μm, while quartz is mainly distributed at the interface of calcite lamina. The calcite crystals in calcite veins belong to trigonal[JP] or rhombohedral system, and the corresponding unit cell is trigonal or rhombohedral. The lattice parameters are a₀=b₀=4.99 Å, c₀=17.061 Å, α=β=90°, γ=120°, respectively. Calcite veins have a certain preferred orientation on longitudinal section, which is due to the development of polysynthetic twin crystals in calcite grains. The adjacent twin crystal stripes have different crystal orientations, and the crystal misorientation is 75° while the alternate twin stripes have the same crystal orientation, and the crystal orientation of the same twin stripe is the same. In calcite grains, perfect cleavage occurs in groups with sharp angle with twin crystal stripes. Both cleavage and twin crystal stripes are formed by tectonic compression and shearing during the crystallization of calcite, and the maximum principal stress direction is parallel to the twin crystal stripes.
- Electron Back Scattered Diffraction (EBSD) /
- crystallographic characteristics /
- mineralogical characteristics /
- calcite vein /
- shale /
- Sichuan Basin

HTML全文

图 1 方解石脉体的多尺度特征

Figure 1. Multi-scale characteristics of calcite veins

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图 2 电子背散射衍射测试示意

Figure 2. Schematic diagram of EBSD

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图 3 电子背散射衍射数据自动采集过程

Figure 3. Automatic acquisition process of EBSD

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图 4 方解石脉体花样质量图及反极图

Figure 4. Pattern quality figure and inverse pole figure of calcite veins

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图 5 方解石脉体的物相鉴定

Figure 5. Phase identification of calcite veins

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图 6 方解石脉体的晶粒大小统计

Figure 6. Grain size statistics of calcite veins

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图 7 方解石脉体纵剖面上的晶体取向差分布

Figure 7. Distribution of crystal misorientation on longitudinal section of calcite veins

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图 8 方解石脉体纵剖面上的晶体极图

Figure 8. Crystal pole figure on longitudinal section of calcite veins

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图 9 方解石晶粒内部电子背散射衍射花样标定及晶胞提取

Figure 9. Calibration of EBSD pattern and extraction of crystal cell within calcite grains

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图 10 方解石晶粒内部双晶及其晶体取向

Figure 10. Twin crystals and crystal orientation within calcite grains

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图 11 方解石晶粒内部解理微观特征及其力学成因示意

Figure 11. Micro characteristics of cleavage within calcite grains and its mechanical origin

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