页岩岩心样品烃类散失特征与地质意义

钱门辉; 黎茂稳; 蒋启贵; 李志明; 陶国亮; 鲍云杰

doi:10.11781/sysydz202203497

页岩岩心样品烃类散失特征与地质意义

doi: 10.11781/sysydz202203497

钱门辉^{1, 2, 3, 4,},
黎茂稳^{1, 2, 3, 4},
蒋启贵^{1, 2, 3, 4},
李志明^{1, 2, 3, 4},
陶国亮^{1, 2, 3, 4},
鲍云杰^{1, 2, 3, 4}

1.
中国石化石油勘探开发研究院无锡石油地质研究所, 江苏无锡 214126
2.
页岩油气富集机理与有效开发国家重点实验室, 江苏无锡 214126
3.
国家能源页岩油研发中心, 江苏无锡 214126
4.
中国石化油气成藏重点实验室, 江苏无锡 214126

基金项目:

国家自然科学基金项目"陆相富有机质页岩成烃动态演化与烃类赋存机理" 42090022

详细信息

作者简介:
钱门辉(1985-), 男, 硕士, 副研究员, 从事页岩油气地球化学、石油地质实验研究。E-mail: qianmh.syky@sinopec.com

中图分类号: TE122.1
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- 被引次数: 0
出版历程
- 收稿日期: 2022-01-06
- 修回日期: 2022-04-18
- 刊出日期: 2022-05-28

Evaluation of evaporative loss of hydrocarbon in shale samples and its geological implications

QIAN Menhui^{1, 2, 3, 4
,},
LI Maowen^{1, 2, 3, 4},
JIANG Qigui^{1, 2, 3, 4},
LI Zhiming^{1, 2, 3, 4},
TAO Guoliang^{1, 2, 3, 4},
BAO Yunjie^{1, 2, 3, 4}

1.
Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi, Jiangsu 214126, China
2.
State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Wuxi, Jiangsu 214126, China
3.
State Energy Center for Shale Oil Research and Development, Wuxi, Jiangsu 214126, China
4.
SINOPEC Key Laboratory of Petroleum Accumulation Mechanisms, Wuxi, Jiangsu 214126, China

摘要

摘要: 游离烃含量是页岩油资源评价中最关键参数之一，但由于烃类散失的影响，实验测得的游离烃含量往往与真实含量差异较大，从而导致含油性评价结果“失真”。为研究含油泥页岩烃类散失过程，获取烃类散失量及校正系数，本文利用成熟度相近、不同岩相的新鲜含油岩心样品，对不同放置时间后样品的烃类残留量及残留组分开展实验并进行综合分析。研究认为，页岩样品烃类散失分早期快速散失和后期缓慢散失2个过程，挥发组分主要为C₁₃—C₁₅以前的低碳数烃类，中质—重质组分受影响较小；储集物性条件及原始含油量共同控制了烃类散失量及散失过程。原始含油量越高、储集物性越好的泥页岩样品烃类散失量越大，因此，在评价储集物性好的高含油的页岩油“甜点”段时，更需要注意原始烃含量的恢复。
- 烃类散失 /
- 轻烃恢复 /
- 游离烃含量 /
- 含油性评价 /
- 页岩油
Abstract: Free hydrocarbon content is one of the key parameters for resource assessment of shale oil.However, due to the evaporative loss of hydrocarbon, the measured results from lab analysis differ greatly from real value, which leads to the "distortion" of shale oil resource assessment.To investigate the process of the evaporative loss and obtain the hydrocarbon loss amount and correction coefficient, a time-series of analysis has been carried out on fresh oil-bearing shale samples with similar maturity and different lithofacies for both the amount and the composition of the hydrocarbons retained in shale.Results suggest that there are two processes of early rapid and later slow evaporative loss. The volatile components are mainly light hydrocarbons with carbon numbers smaller than C₁₃-C₁₅, while the medium to heavy components are less affected. Both the amount and processes of hydrocarbon evaporative loss are controlled by the physical properties and original oil content of shale samples.The oil-bearing shale samples with higher original oil content and better physical properties appear to have more evaporative loss of hydrocarbons.Results also indicate that more attention should be exercised on original hydrocarbon content when conducting the shale oil resource assessment of "sweet spot" section with high oil content and good physical properties.
- hydrocarbon evaporative loss /
- recovery of light hydrocarbons /
- free hydrocarbon content /
- evaluation of oil-bearing capacity /
- shale oil

HTML全文

图 1 热解S₁测量值与样品放置时间的关系

Figure 1. Relationships between Rock-Eval S₁ value and sample storing time

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图 2 不同含油程度的样品放置后S₁测量值变化

Figure 2. Rock-Eval S₁ value changes of samples with different oil contents after storing

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图 3 页岩岩心样品不同放置周期后散失烃类组分变化特征

Figure 3. Characteristics of hydrocarbon component changes of shale core samples with different storing time

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图 4 不同放置周期后样品游离烃含量与原始游离烃含量的关系

Figure 4. Free hydrocarbon contents before and after different storing time

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图 5 样品早期散失量与孔隙度、渗透率及原始含油量的关系

Figure 5. Early loss vs. porosity, permeability and original oil content of samples

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图 6 常用轻烃校正恢复系数

据参考文献[16, 25]整理。

Figure 6. Correction coefficient of light hydrocarbons commonly used

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图 7 泥页岩样品长时间放置后烃类损失比例与原始含油量关系

Figure 7. Hydrocarbon loss ratio vs. original oil content of shale samples after long-time storing

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图 8 不同泥页岩样品原始含油量与长时间放置后含油量对比

Figure 8. Original S₁ value vs. S₁ value of different shale samples after storing for five months

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表 1 实验样品基础数据

Table 1. Basic information of experimental samples

井号	样品号	岩性	深度/m	S₁/(mg·g^-1)	S₂/(mg·g^-1)	ω(TOC)/%	T_max/℃	主要矿物含量/%							孔隙度/%
井号	样品号	岩性	深度/m	S₁/(mg·g^-1)	S₂/(mg·g^-1)	ω(TOC)/%	T_max/℃	黏土	石英	长石	方解石	白云石	石膏	钙芒硝	孔隙度/%
BYY1	45	灰色纹层状白云质泥岩	3 124.07	4.45	2.96	2.07	408	29.6	14.5	7.4	5.8	28.8	1.1	8.0	1.1
	55	灰色纹层状泥质白云岩	3 124.39	5.72	3.91	2.17	414	19.2	9.2	8.1	16.5	40.2	1.4	2.3	8.4
	61	灰黑色纹层状白云质泥岩	3 124.70	3.23	2.86	1.46	416	18.7	9.2	8.3	19.6	34.9	2.1	1.2	1.0
	67	灰黑色纹层状白云质泥岩	3 124.88	3.66	2.26	1.28	414	38.6	17.8	7.9	18.6	5.0	1.2	2.4	3.1
	143	灰色泥质白云岩	3 127.33	5.54	3.36	1.75	407	18.5	10.2	6.5	12.1	47.6	0.9	0.6	7.5
	161	灰色纹层状泥质白云岩	3 127.76	7.79	1.55	1.16	402	13.9	9.4	7.8	16.9	43.1	0.8	4.3	2.5
	192	灰黄色含穿层钙芒硝白云岩	3 129.07	5.34	1.22	0.80	398	17.1	9.0	6.5	6.7	25.4	1.8	27.9	2.8
	205	灰黄色纹层状白云岩	3 129.56	12.60	1.21	1.40	393	8.0	7.5	8.1	4.0	54.1	1.0	13.3	1.6
	220	浅灰色白云岩	3 130.12	3.93	0.69	0.60	403	7.6	12.6	11.4	3.6	56.7	1.2	1.2	13.4
	224	灰色细纹层状白云岩	3 130.27	7.60	4.22	1.68	408	34.1	20.3	5.0	5.3	3.7	1.5	24.1	3.8
	197	灰色含钙芒硝白云质泥岩	3 129.29	4.43	1.68	1.04	397	31.3	22.2	10.3	11.3	7.0	1.6	5.1	3.8
	253	灰白色块状钙芒硝岩	3 131.40	2.92	0.77	0.66	391	27.6	15.3	4.0	3.6	1.9	1.8	37.4	0.7
	264	灰黄色块状白云岩	3 131.73	4.75	1.18	0.85	405	13.3	8.7	4.4	2.7	58.1	0.6	1.2	8.2
BYY2	1111	灰黑色纹层状白云质泥岩	3 400.29	10.88	5.22	4.13	428	15.5	8.6	13.7	21.3	29.0	5.1	0.3	1.3
BYY2	1076	灰黑色纹层状白云质泥岩	3 399.37	2.43	0.69	2.27	400	12.4	6.1	18.5	8.7	35.3	16.7	0.7	6.0
注：S₁、S₂、TOC及T_max数据为原始新鲜样品分析结果。

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表 2 泥页岩样品不同常温放置时间后S₁测试值

Table 2. Rock-Eval S₁ value of shale samples after a time-series of storing in normal conditions

放置时间/h	S₁/(mg·g^-1)
放置时间/h	样品1111	样品1076
2	10.88	2.43
8	10.54	1.64
32	9.70	1.45
56	9.41	1.27
794	8.20	1.08
1 394	8.16	0.98

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表 3 不同样品的S₁恢复系数计算结果

Table 3. Calculation results of corrective coefficients of Rock-Eval S₁ for different samples

样品号	原始S₁含量/(mg·g^-1)	缓慢散失阶段S₁含量/(mg·g^-1)	S₁损失比例/%	S₁恢复系数
205	12.6
55	5.72
224	7.60	2.63	65.39	2.89
161	7.79	4.11	47.24	1.90
264	4.75	2.83	40.42	1.68
67	3.66	2.75	24.86	1.33
143	5.54	3.84	30.69	1.44
192	5.34	3.55	33.52	1.50
61	3.23	2.43	24.77	1.33
220	3.93	2.73	30.53	1.44
注：样品205和55由于尚未进入缓慢散失阶段，故本文未计算其恢复系数。

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页岩岩心样品烃类散失特征与地质意义

doi: 10.11781/sysydz202203497

作者简介:
钱门辉(1985-), 男, 硕士, 副研究员, 从事页岩油气地球化学、石油地质实验研究。E-mail: qianmh.syky@sinopec.com

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Evaluation of evaporative loss of hydrocarbon in shale samples and its geological implications

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页岩岩心样品烃类散失特征与地质意义

doi: 10.11781/sysydz202203497

作者简介: 钱门辉(1985-), 男, 硕士, 副研究员, 从事页岩油气地球化学、石油地质实验研究。E-mail: qianmh.syky@sinopec.com

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Evaluation of evaporative loss of hydrocarbon in shale samples and its geological implications

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作者简介:
钱门辉(1985-), 男, 硕士, 副研究员, 从事页岩油气地球化学、石油地质实验研究。E-mail: qianmh.syky@sinopec.com