南襄盆地泌阳凹陷古近系核桃园组页岩含油性及烃类赋存特征

金芸芸; 李楚雄; 王勇; 严永新; 罗曦; 黄帅博; 李志明; 周圆圆; 孙中良; 刘雅慧; 贾梦瑶; 冷筠滢

doi:10.11781/sysydz202402354

南襄盆地泌阳凹陷古近系核桃园组页岩含油性及烃类赋存特征

doi: 10.11781/sysydz202402354

金芸芸^1,,
李楚雄^{2, 3, ,},
王勇⁴,
严永新⁴,
罗曦¹,
黄帅博¹,
李志明^{2, 3},
周圆圆^{2, 3},
孙中良^{2, 3},
刘雅慧^{2, 3},
贾梦瑶^{2, 3},
冷筠滢^{2, 3}

1.
中国石化河南油田分公司勘探开发研究院, 河南南阳 473132
2.
中国石化石油勘探开发研究院无锡石油地质研究所, 江苏无锡 214126
3.
页岩油气富集机理与高效开发全国重点实验室, 江苏无锡 214126
4.
中国石化河南油田分公司油气勘探管理部, 河南南阳 473132

基金项目:

国家自然科学基金项目 42090022

中国石化“十四五”资源评价方法与数据库建设项目 P23229

中国石化基础前瞻项目 P22211-4

详细信息

作者简介:
金芸芸(1983—)，女，硕士，高级工程师，从事油气勘探工作。E-mail: yjykt2jyy.hnyt@sinopec.com

通讯作者:
李楚雄(1992—)，男，硕士，助理研究员，从事非常规石油地质研究。E-mail: lichuxiong.syky@sinopec.com

中图分类号: TE122.2
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- 文章访问数: 380
- HTML全文浏览量: 161
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- 被引次数: 0
出版历程
- 收稿日期: 2023-03-16
- 修回日期: 2024-01-05
- 刊出日期: 2024-03-28

Oil-bearing potential and hydrocarbon occurrence characteristics of shale in Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

JIN Yunyun^1
,,
LI Chuxiong^{2, 3
, ,},
WANG Yong⁴,
YAN Yongxin⁴,
LUO Xi¹,
HUANG Shuaibo¹,
LI Zhiming^{2, 3},
ZHOU Yuanyuan^{2, 3},
SUN Zhongliang^{2, 3},
LIU Yahui^{2, 3},
JIA Mengyao^{2, 3},
LENG Junying^{2, 3}

1.
Research Institute of Exploration and Development, Henan Oilfield Company, SINOPEC, Nanyang, Henan 473132, China
2.
Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi, Jiangsu 214126, China
3.
State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Efficient Development, Wuxi, Jiangsu 214126, China
4.
Petroleum Exploration Management Department, Henan Oilfield Company, SINOPEC, Nanyang, Henan 473132, China

摘要

摘要: 南襄盆地泌阳凹陷古近系核桃园组发育优质湖相页岩层系，页岩油资源潜力巨大。前人针对该层系页岩含油性及烃类赋存状态的研究相对薄弱，可能是制约泌阳凹陷页岩油勘探突破的重要因素之一。以泌阳凹陷南部Y1井核三段Ⅲ亚段页岩为研究对象，通过岩石热解、多温阶热解、X射线衍射等地球化学分析技术，系统开展了页岩含油性、烃类赋存特征及影响因素研究。研究结果显示：核三段Ⅲ亚段页岩岩相组合主要包括长英质页岩相、云灰质页岩相和混合质页岩相，纹层结构发育。烃源岩类型整体处于好—优质范围，热演化程度处于生油阶段。有机显微组分以腐泥型为主，有机质类型为Ⅰ—Ⅱ₁型。页岩含油性随埋深增大呈递增趋势，烃类赋存特征由中上部以吸附烃为主，过渡至下部以游离烃为主。碎屑矿物及有机碳含量是控制游离烃和吸附烃含量的主要因素。总体认为，核桃园组下部页岩含油饱和度指数整体高于100 mg/g，游离烃含量平均高于3 mg/g，具备较好的页岩油勘探开发前景。
- 页岩油 /
- 含油性 /
- 烃类赋存状态 /
- 核桃园组 /
- 古近系 /
- 泌阳凹陷 /
- 南襄盆地
Abstract: High-quality lacustrine shale beds within the Paleogene Hetaoyuan Formation in the Biyang Sag, Nanxiang Basin, exhibit significant potential for shale oil resources. Previous studies on the oil-bearing potential and hydrocarbon occurrence of shales in the Biyang Sag were relatively limited, potentially hindering advancements for shale oil exploration. This study focuses on the shales found in the third sub-member of the third member within the Hetaoyuan Formation in well Y1, which locates in the southern area of the Biyang Sag. Through various geochemical analyses such as Rock-Eval pyrolysis, multi-temperature pyrolysis and X-ray diffraction, this research systematically investigates the shale oil contents, hydrocarbon occurrence characteristics, and influencing factors. These results indicate that the lithofacies assemblages of the shale primarily consist of felsic shale facies, dolomitic shale facies and mixed shale facies, with a well-developed laminar structure. The source rock quality is classified as good to excellent, and the thermal maturity stage of oil window. The predominant organic maceral is sapropelic, with organic matter types ranging from Ⅰ to Ⅱ₁. Oil content increases with burial depth, ranged from adsorbed hydrocarbons in the upper section to free hydrocarbons in the lower section. Detrital mineral content and total organic carbon (TOC) content are identified as the main factors influencing free and adsorbed hydrocarbon content, respectively. Overall, the oil saturation index (OSI) of the shale in the lower section of the Hetaoyuan Formation exceeds 100 mg/g, with an average free hydrocarbon content over 3 mg/g, indicating promising prospects for shale oil exploration and development.
- shale oil /
- oil-bearing potential /
- hydrocarbon occurrence state /
- Hetaoyuan Formation /
- Paleogene /
- Biyang Sag /
- Nanxiang Basin
注释:

利益冲突声明/Conflict of Interests

所有作者声明不存在利益冲突。

All authors disclose no relevant conflict of interests.

作者贡献/Authors’Contributions

李楚雄、李志明参与实验设计；周圆圆、刘雅慧、贾梦瑶、冷筠滢、孙中良完成实验操作；金芸芸、李楚雄、李志明、王勇、严永新、罗曦、黄帅博参与论文写作和修改。所有作者均阅读并同意最终稿件的提交。

The study was designed by LI Chuxiong and LI Zhiming. The experimental operation was completed by ZHOU Yuanyuan, LIU Yahui, JIA Mengyao, LENG Junying and SUN Zhongliang. The manuscript was drafted and revised by JIN Yunyun, LI Chuxiong, LI Zhiming, WANG Yong, YAN Yongxin, LUO Xi and HUANG Shuaibo. All the authors have read the last version of paper and consented for submission.

HTML全文

图 1 南襄盆地泌阳凹陷区域地质概况(a)和地层岩性柱状图(b)

Figure 1. Regional geological overview (a) and stratigraphic lithology histogram (b) of Biyang Sag, Nanxiang Basin

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图 2 南襄盆地泌阳凹陷古近系核桃园组三段页岩矿物组成(a)及岩相划分(b)

Figure 2. Mineral composition (a) and lithofacies division (b) of shale in third member of Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

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图 3 南襄盆地泌阳凹陷古近系核桃园组三段页岩典型岩相类型

a.岩心照片，长英质页岩相，①小层，深度2 742.3 m；b.图a的岩心薄片照片；c.岩心照片，云灰质页岩相，②小层，深度2 799.7 m；d.图c的岩心薄片照片；e.岩心照片，混合质页岩相，①小层，深度2 764.7 m；f.图e的岩心薄片照片。

Figure 3. Typical lithofacies types of shale in third member of Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

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图 4 南襄盆地泌阳凹陷古近系核桃园组三段烃源岩品质类型

Figure 4. Quality types of source rocks in third member of Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

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图 5 南襄盆地泌阳凹陷古近系核桃园组三段页岩有机质类型划分

Figure 5. Classification of shale organic matter types in third member of Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

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图 6 南襄盆地泌阳凹陷古近系核桃园组三段页岩典型有机显微组分

a.层状藻类体，黄绿色荧光，①小层，深度2 742.3 m；b.结构藻类体，亮黄色荧光，②小层，深度2 774.6 m；c.孢粉体，黄绿色荧光，②小层，深度2 774.6 m；d.烃类体，绿色荧光，②小层，深度2 804.8 m；e.镜质体，微弱黄褐色荧光，②小层，深度2 804.8 m。

Figure 6. Typical organic macerals of shale in third member of Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

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图 7 南襄盆地泌阳凹陷古近系核桃园组三段页岩含油性及烃类赋存状态综合评价

Figure 7. Comprehensive evaluation of oil-bearing potential and hydrocarbon occurrence in shale in third member of Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

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图 8 南襄盆地泌阳凹陷古近系核桃园组三段页岩总有机碳含量与游离烃S₁的关系

Figure 8. Relationship between TOC content and free hydrocarbon S₁ of shale in third member of Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

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图 9 南襄盆地泌阳凹陷古近系核桃园组三段页岩含油饱和度指数与热演化程度(a)及生产力指数(b)的相关性

Figure 9. Correlation between oil saturation index with thermal evolution degree (a) and productivity index (b) of shale in third member of Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

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图 10 南襄盆地泌阳凹陷古近系核桃园组三段页岩游离烃(a)、吸附烃(b)含量与总有机碳含量的相关性

Figure 10. Correlation between free hydrocarbon (a) and adsorbed hydrocarbon (b) contents with TOC content of shale in third member of Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

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图 11 南襄盆地泌阳凹陷古近系核桃园组三段页岩游离烃(a)、吸附烃(b)含量与T_max的相关性

Figure 11. Correlation between free hydrocarbon (a) and adsorbed hydrocarbon (b) contents with T_max of shale in third member of Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

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图 12 南襄盆地泌阳凹陷古近系核桃园组三段页岩游离烃(a-c)、吸附烃(d-f)含量与不同类型矿物含量的相关性

Figure 12. Correlation between free hydrocarbon (a-c) and adsorbed hydrocarbon (d-f) contents with different mineral contents of shale in third member of Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

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