松辽盆地天然气中稀有气体地球化学特征及其地质意义

李伟; 陈践发; 王杰; 王晓波; 何大祥; 王东良; 刘凯旋; 尤兵; 陈聪; 付娆; 唐帅旗; 张佳琦

doi:10.11781/sysydz202403576

松辽盆地天然气中稀有气体地球化学特征及其地质意义

doi: 10.11781/sysydz202403576

李伟^{1, 2,},
陈践发^1, ,,
王杰³,
王晓波⁴,
何大祥⁵,
王东良⁴,
刘凯旋¹,
尤兵¹,
陈聪¹,
付娆¹,
唐帅旗¹,
张佳琦¹

1.
中国石油大学(北京) 地球科学学院油气资源与工程全国重点实验室, 北京 102249
2.
天水师范学院资源与环境工程学院, 甘肃天水 741000
3.
中国石化石油勘探开发研究院无锡石油地质研究所, 江苏无锡 214126
4.
中国石油天然气股份有限公司勘探开发研究院, 北京 100089
5.
长江大学湖北省油气地球化学与环境重点实验室, 武汉 430100

基金项目:

国家重点研发计划项目 2021YFA071900

“十三五”国家科技重大专项 2016ZX05007003-004

甘肃省教育科技项目 2022QB-146

天水师范学院基金项目 CXJ2020-27

详细信息

作者简介:
李伟(1986—)，男，博士生，从事稀有气体地球化学、天然气地质学研究。E-mail：liwei05@lzu.edu.cn

通讯作者:
陈践发(1961—)，男，博士，教授，从事天然气地球化学研究。E-mail：jfchen@cup.edu.cn

中图分类号: TE133.1
计量
- 文章访问数: 236
- HTML全文浏览量: 146
- PDF下载量: 33
- 被引次数: 0
出版历程
- 收稿日期: 2023-11-05
- 修回日期: 2024-03-18
- 刊出日期: 2024-05-28

Geochemical characteristics and geological significance of noble gases in natural gas from Songliao Basin, China

1.
National Key Laboratory of Petroleum Resources and Engineering, College of Geosciences, China University of Petroleum (Beijing), Beijing 102249, China
2.
School of Resources and Environmental Engineering, Tianshui Normal University, Tianshui, Gansu 741000, China
3.
Wuxi Research Institute of Petroleum Geology, SNOPEC, Wuxi, Jiangsu 214126, China
4.
Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100089, China
5.
Hubei Key Laboratory of Oil & Gas Geochemistry and Environment, Yangtze University, Wuhan, Hubei 430100, China

摘要

摘要: 稀有气体地球化学已运用于地球深部物质及天体陨石研究，随着测量技术的进步，在天然气研究中也开始得到越来越多的应用。使用目前最先进的稀有气体质谱仪，对中国东部松辽盆地中深部天然气的稀有气体全组分丰度及同位素进行了系统的分析，明确了断陷盆地稀有气体的组成特征。研究表明，天然气中稀有气体的丰度从轻稀有气体到重稀有气体具有逐渐减小的反“厂”字形趋势。稀有气体的同位素比值³He/⁴He为2.64×10^-6、²⁰Ne/²²Ne为9.94、²¹Ne/²²Ne为0.029 22、⁴⁰Ar/³⁶Ar为743.7，均高于大气值，⁸⁰Kr、⁸⁴Kr、⁸⁶Kr、^131-136Xe均表现出相对大气过剩的特征，显示天然气中有幔源气体的混入。综合稀有气体的组成特征，说明松辽盆地中深部天然气均为壳幔混源的无机成因，而且不同构造区块、不同类别天然气的幔源组分贡献存在一定差异。对比稀有气体组成与天然气类型发现，轻稀有气体可以较好地区分天然气的类型，而重稀有气体的组成在各种天然气中没有明显差别。稀有气体同位素除了可以示踪天然气来源外，还可以应用在判别天然气成因、区分天然气类型、表征大地构造等方面。
- 稀有气体 /
- 稀有气体同位素 /
- 地球化学特征 /
- 氦源 /
- 壳幔混源 /
- 松辽盆地
Abstract: Geochemistry of noble gases has been applied to the study of deep Earth materials and celestial meteorites. With advancements in measurement technology, it is also increasingly being used in natural gas research. Using the most advanced noble gas mass spectrometer, a systematic analysis was conducted on the abundance and isotopes of noble gas samples collected from the middle and deep Songliao Basin in eastern China to elucidate the compositional characteristics of noble gases in a faulted basin. The findings reveal that the abundance of noble gases in natural gas decreases from light noble gases to heavy noble gases in a left-to-right reversed L-shaped pattern. Specifically, the isotopic ratios of noble gases are: ³He/⁴He at 2.64×10^-6, ²⁰Ne/²²Ne at 9.94, ²¹Ne/²²Ne at 0.029 22, and ⁴⁰Ar/³⁶Ar at 743.7, all of which are higher than atmospheric values. The isotopes ⁸⁰Kr, ⁸⁴Kr, ⁸⁶Kr, and ^131-136Xe show relative excess compared to atmospheric levels, indicating the mixing of mantle-derived gases in the natural gas. Based on the compositional characteristics of noble gases, this study suggests that the natural gas in the middle and deep Songliao Basin originated from inorganic crust and mantle mixing. Additionally, certain differences exist in the contribution of mantle-derived components across different tectonic blocks and categories of natural gas within the basin. Comparison between noble gas compositions and the types of natural gas demonstrates that light noble gases distinguish effectively between different types of natural gas, whereas the composition of heavy noble gases shows no significant differences among various types of natural gas. Noble gas isotopes, in addition to tracing the source of natural gas, can also be used to determine natural gas genesis, distinguish natural gas types and characterize tectonic settings.
- noble gas /
- isotope of noble gas /
- geochemical characteristics /
- helium source /
- crust-mantle mixed source /
- Songliao Basin
注释:

利益冲突声明/Conflict of Interests

所有作者声明不存在利益冲突。

All authors disclose no relevant conflict of interests.

作者贡献/Authors’Contributions

李伟、陈践发参与实验设计；李伟、王晓波、何大祥、刘凯旋完成实验操作；李伟、陈践发、王杰、王东良、尤兵、陈聪、付娆、唐帅旗、张佳琦参与论文写作和修改。所有作者均阅读并同意最终稿件的提交。

The study was designed by LI Wei and CHEN Jianfa. The experimental operation was completed by LI Wei, WANG Xiaobo, HE Daxiang and LIU Kaixuan. The manuscript was drafted and revised by LI Wei, CHEN Jianfa, WANG Jie, WANG Dongliang, YOU Bing, CHEN Cong, FU Rao, TANG Shuaiqi and ZHANG Jiaqi. All authors have read the last version of the paper and consented to its submission.

HTML全文

图 1 松辽盆地构造背景

据参考文献[25, 32]修改。

Figure 1. Tectonic background of Songliao Basin

下载: 全尺寸图片幻灯片

图 2 松辽盆地天然气中稀有气体分布直方图

Figure 2. Histogram of noble gas distribution in natural gas of Songliao Basin

下载: 全尺寸图片幻灯片

图 3 松辽盆地天然气中稀有气体系列特征

Figure 3. Characteristics of noble gas series in natural gas of Songliao Basin

下载: 全尺寸图片幻灯片

图 4 松辽盆地天然气中He、Ne的丰度及其同位素比值相关性

图b据参考文献[42]修改。

Figure 4. Abundance of He and Ne and their isotope ratio correlations in natural gas of Songliao Basin

下载: 全尺寸图片幻灯片

图 5 松辽盆地天然气中Ar的丰度与其同位素比值的相关性

Figure 5. Correlation between Ar abundance and its isotope ratios in natural gas of Songliao Basin

下载: 全尺寸图片幻灯片

图 6 松辽盆地天然气中Kr各同位素比值相关性

Figure 6. Correlation of Kr isotope ratios in natural gas of Songliao Basin

下载: 全尺寸图片幻灯片

图 7 松辽盆地天然气中Xe同位素比值系列与相关关系

图f据参考文献[7]修改。

Figure 7. Correlations of Xe isotope ratio series in natural gas of Songliao Basin

下载: 全尺寸图片幻灯片

图 8 松辽盆地天然气中稀有气体同位素系列特征

Figure 8. Characteristics of noble gas isotope series in natural gas of Songliao Basin

下载: 全尺寸图片幻灯片

图 9 稀有气体判识松辽盆地天然气成因及来源

图b据参考文献[43]修改；图c据参考文献[42]修改；图d据参考文献[20]修改。

Figure 9. Identification of genesis and sources of natural gas of Songliao Basin by noble gases

下载: 全尺寸图片幻灯片

表 1 松辽盆地天然气主要组分与稀有气体组分测试结果

Table 1. Test results of main components and noble gas components of natural gas in Songliao Basin

构造区域	井名	C₁/%	C₂₊/%	CO₂/%	N₂/%	He/10^-6	Ne/10^-6	Ar/10^-6	Kr/10^-6	Xe/10^-6
长岭断陷	长深2	1.57	0.01	97.45	0.71	129.52	10.02	37.337	0.007 4	0.000 750
	长深4	0.69	0.00	98.56	0.00	82.29	4.28	8.289	0.002 8	0.000 104
	长深1	71.44	1.24	22.04	4.93	449.11	224.82	318.238	0.332 8	0.019 636
	长深1-2	65.79	1.20	28.12	4.55	451.40	257.14	288.638	0.225 3	0.011 667
	长深D1-1	92.18	1.89	0.58	4.67	452.67	410.64	374.687	0.546 6	0.032 186
	长深平2	68.17	1.19	25.65	4.70	513.95	240.12	311.047	0.324 2	0.014 402
	长深平3	67.49	1.17	26.54	4.66	486.30	195.35	319.622	0.180 4	0.007 934
	长深平4	69.41	1.21	24.41	4.78	563.49	232.07	345.812	0.220 7	0.011 482
	长深平7	65.43	1.14	28.31	4.48	422.30	0.93	261.093	0.093 6	0.004 462
徐家围子断陷	升深1-1	94.85	2.23	0.00	2.88	345.07	544.63	185.021	0.633 5	0.030 205
	升深平1	92.53	1.86	2.30	3.23	339.79	159.86	129.482	0.142 3	0.005 868
	徐深1	94.08	2.95	1.67	1.23	145.89	171.10	80.570	0.147 1	0.008 692
	徐深1-101	94.76	3.33	0.41	1.34	158.92	98.24	218.811	0.143 6	0.017 782
	徐深1-205	93.34	3.21	1.95	1.38	152.06	336.48	243.370	0.347 9	0.048 496
	徐深1-3	95.56	2.85	0.27	1.28	139.79	231.13	233.080	0.267 2	0.051 738
	徐深6	95.22	3.05	0.40	0.30	192.60	220.99	111.375	0.201 7	0.014 847
	徐深603	96.53	2.47	0.00	1.16	129.71	493.46	518.918	0.653 7	0.136 657
	徐深6-101	96.42	2.56	0.00	1.00	140.96	167.29	93.406	0.153 6	0.012 089
	徐深6-3	96.01	2.73	0.00	1.24	153.77	359.64	106.900	0.434 2	0.021 722
注: He、Ne、Ar、Kr、Xe的大气标准值分别为5.24×10^-6、18.18×10^-6、0.934%、1.14×10^-6、8.7×10^-9。

下载: 导出CSV

表 2 地球各圈层的稀有气体同位素比值

Table 2. Noble gas isotope ratios of Earth's spheres

来源	(³He/⁴He)/10^-6	²⁰Ne/²²Ne	²¹Ne/²²Ne	⁴⁰Ar/³⁶Ar	¹²⁹Xe/¹³⁰Xe	¹³⁶Xe/¹³⁰Xe	备注
MORB	12.60	13.20	0.697	1 600	6.5~7.0	2.1~2.4	文献[7, 40]
地壳	0.03	0.30	0.470	4 400			文献[41]
大气	1.40	9.80	0.029	295.5	6.496	2.18	文献[7]

下载: 导出CSV

表 3 松辽盆地天然气中轻稀有气体同位素分布

Table 3. Isotopic distribution of light noble gases in natural gas of Songliao Basin

天然气类型	样品数/个	(³He/⁴He)/10^-6	²⁰Ne/²²Ne	²¹Ne^/22Ne	³⁸Ar/³⁶Ar	⁴⁰Ar/³⁶Ar
C-Gas	2	5.06	10.00	0.028 75	0.176 9	501.7
L-Gas	7	3.37	9.91	0.029 44	0.189 2	1 288.6
X-Gas	10	1.64	9.95	0.029 16	0.188 6	410.6

下载: 导出CSV

表 4 松辽盆地天然气中Kr同位素分布

Table 4. Kr isotope distribution in natural gas of Songliao Basin

天然气类型	样品数/个	⁷⁸Kr/⁸³Kr	⁸⁰Kr/⁸³Kr	⁸²Kr/⁸³Kr	⁸⁴Kr/⁸³Kr	⁸⁶Kr/⁸³Kr
C-Gas	2	0.031 4	0.188 1	0.973	5.23	1.83
L-Gas	7	0.030 6	0.194 9	0.990	5.32	1.70
X-Gas	10	0.030 8	0.194 7	1.000	5.29	1.72

下载: 导出CSV

表 5 松辽盆地天然气中Xe同位素分布

Table 5. Xe isotope distribution in natural gas of Songliao Basin

天然气类型	样品数/个	¹²⁴Xe/¹³⁰Xe	¹²⁶Xe/¹³⁰Xe	¹²⁸Xe/¹³⁰Xe	¹²⁹Xe/¹³⁰Xe	¹³¹Xe/¹³⁰Xe	¹³²Xe/¹³⁰Xe	¹³⁴Xe/¹³⁰Xe	¹³⁶Xe/¹³⁰Xe
C-Gas	2	0.024 2	0.023 1	0.476 5	6.478	5.271	7.53	2.86	2.41
L-Gas	7	0.022 3	0.021 5	0.469 1	6.542	5.289	7.17	2.81	2.43
X-Gas	10	0.021 3	0.021 0	0.460 0	6.466	5.288	6.98	2.77	2.41

下载: 导出CSV

参考文献(53)

[1]	TOLSTIKHIN I, KAMENSKY I, TARAKANOV S, et al. Noble gas isotope sites and mobility in mafic rocks and olivine[J]. Geochimica et Cosmochimica Acta, 2010, 74(4): 1436-1447. doi: 10.1016/j.gca.2009.11.001
[2]	PINTI D L, MARTY B. Noble gases in crude oils from the Paris Basin, France: implications for the origin of fluids and constraints on oil-water-gas interactions[J]. Geochimica et Cosmochimica Acta, 1995, 59(16): 3389-3404. doi: 10.1016/0016-7037(95)00213-J
[3]	BALLENTINE C J, O'NIONS R K, OXBURGH E R, et al. Rare gas constraints on hydrocarbon accumulation, crustal degassing and groundwater flow in the Pannonian Basin[J]. Earth and Planetary Science Letters, 1991, 105(1/3): 229-246.
[4]	陈践发, 刘凯旋, 董勍伟, 等. 天然气中氦资源研究现状及我国氦资源前景[J]. 天然气地球科学, 2021, 32(10): 1436-1449. doi: 10.11764/j.issn.1672-1926.2021.08.006 CHEN Jianfa, LIU Kaixuan, DONG Qingwei, et al. Research status of helium resources in natural gas and prospects of helium resources in China[J]. Natural Gas Geoscience, 2021, 32(10): 1436-1449. doi: 10.11764/j.issn.1672-1926.2021.08.006
[5]	尤兵, 陈践发, 肖洪, 等. 富氦天然气藏氦源岩特征及关键评价参数[J]. 天然气工业, 2022, 42(11): 141-154. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG202211014.htm YOU Bing, CHEN Jianfa, XIAO Hong, et al. Characteristics and key evaluation parameters of helium source rocks in helium-rich natural gas reservoirs[J]. Natural Gas Industry, 2022, 42(11): 141-154. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG202211014.htm
[6]	QIN Shengfei, XU Dan, LI Jiyuan, et al. Genetic types, distribution patterns and enrichment mechanisms of helium in China's petroliferous basins[J]. Frontiers in Earth Science, 2022, 10: 675109. doi: 10.3389/feart.2022.675109
[7]	OZIMA M, PODOSEK F A. Noble gas geochemistry[M]. Cambridge: Cambridge University Press, 1983.
[8]	MANYRIN B A, TOLSTIKHIN I N. Helium isotopes in nature[M]. Amsterdam: Elsevier, 1984: 175-179.
[9]	LUPTON J E. Terrestrial inert gases: isotope tracer studies and clues to primordial components in the mantle[J]. Annual Review of Earth and Planetary Sciences, 1983, 11: 371-414. doi: 10.1146/annurev.ea.11.050183.002103
[10]	WAKITA H, SANO Y. ³He/⁴He ratios in CH₄-rich natural gases suggest magmatic origin[J]. Nature, 1983, 305(5937): 792-794. doi: 10.1038/305792a0
[11]	LOLLAr B S, O'NIONS R K, BALLENTINE C J. Helium and neon isotope systematics in carbon dioxide-rich and hydrocarbon-rich gas reservoirs[J]. Geochimica et Cosmochimica Acta, 1994, 58(23): 5279-5290. doi: 10.1016/0016-7037(94)90311-5
[12]	BALLENTINE C J, O'NIONS R K, COLEMAN M L. A Magnus opus: helium, neon, and argon isotopes in a North Sea oilfield[J]. Geochimica et Cosmochimica Acta, 1996, 60(5): 831-849. doi: 10.1016/0016-7037(95)00439-4
[13]	HE Daxiang, CHEN Jianfa, ZHANG Chen, et al. Compositions of non-hydrocarbon and noble gases in natural gas samples from Tarim Basin, China[J]. Geochemical Journal, 2015, 49(3): 271-282. doi: 10.2343/geochemj.2.0355
[14]	XU Yongchang, SHENG Ping, TAO Mingxin, et al. Distribution of the helium isotopes in natural gases from oil-gas-bearing basins in China[J]. Chinese Science Bulletin, 1994, 39(22): 1905-1911.
[15]	LIU Wenhui, XU Yongchang, TAO Mingxin, et al. Helium and argon isotope geochemistry of natural gases in China's petroliferous basins[J]. Chinese Journal of Geochemistry, 2011, 30(1): 19-32. doi: 10.1007/s11631-011-0483-9
[16]	徐永昌. 天然气中氦同位素分布及构造环境[J]. 地学前缘, 1997, 4(3/4): 185-190. https://www.cnki.com.cn/Article/CJFDTOTAL-DXQY7Z2.031.htm XU Yongchang. Helium isotope distribution of natural gasses and its structural setting[J]. Earth Science Frontiers, 1997, 4(3/4): 185-190. https://www.cnki.com.cn/Article/CJFDTOTAL-DXQY7Z2.031.htm
[17]	REN Jianguo, XU Sheng, SUN Mingliang, et al. Excess ³He and its distribution in the western Pacific seawater[J]. Chinese Science Bulletin, 1992, 37(15): 1288-1292.
[18]	杜建国, 徐永昌, 孙明良. 中国大陆含油气盆地的氦同位素组成及大地热流密度[J]. 地球物理学报, 1998, 41(4): 494-501. doi: 10.3321/j.issn:0001-5733.1998.04.008 DU Jianguo, XU Yongchang, SUN Mingliang. Helium isotopes and heat flow in the oil and gas bearing basins in China's continent[J]. Acta Geophysica Sinica, 1998, 41(4): 494-501. doi: 10.3321/j.issn:0001-5733.1998.04.008
[19]	王先彬. 稀有气体同位素地球化学和宇宙化学[M]. 北京: 科学出版社, 1989: 451. WANG Xianbin. Noble gas isotope geochemistry and cosmochemistry[M]. Beijing: Science Press, 1989: 451.
[20]	徐胜, 徐永昌, 沈平, 等. 中国东部盆地天然气中氖同位素组成及其地质意义[J]. 科学通报, 1996, 41(21): 1970-1972. doi: 10.3321/j.issn:0023-074X.1996.21.013 XU Sheng, XU Yongchang, SHENG Ping, et al. Neon isotopic composition and geological significance of natural gas in the East China Basin[J]. Chinese Science Bulletin, 1996, 41(21): 1970-1972. doi: 10.3321/j.issn:0023-074X.1996.21.013
[21]	刘文汇, 张殿伟, 王晓锋, 等. 天然气气-源对比的地球化学研究[J]. 沉积学报, 2004, 22(S1): 27-32. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB2004S1004.htm LIU Weihui, ZHANG Dianwei, WANG Xiaofeng, et al. Geochemistry study on gas-source correlation of natural gas[J]. Acta Sedimentologica Sinica, 2004, 22(S1): 27-32. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB2004S1004.htm
[22]	BUTLER W A, JEFFERY P M, REYNOLDS J H, et al. Isotopic variations in terrestrial xenon[J]. Journal of Geophysical Research, 1963, 68(10): 3283-3291. doi: 10.1029/JZ068i010p03283
[23]	徐胜, 徐永昌, 沈平, 等. 中国东部盆地天然气中氙同位素过剩[J]. 科学通报, 1997, 42(1): 78-80. doi: 10.3321/j.issn:0023-074X.1997.01.024 XU Sheng, XU Yongchang, SHENG Ping, et al. Excess of xenon isotope in natural gas from the eastern basin of China[J]. Chinese Science Bulletin, 1997, 42(1): 78-80. doi: 10.3321/j.issn:0023-074X.1997.01.024
[24]	刘文汇, 孙明良, 徐永昌. 鄂尔多斯盆地天然气稀有气体同位素特征及气源示踪[J]. 科学通报, 2001, 46(22): 1902-1905. doi: 10.3321/j.issn:0023-074X.2001.22.014 LIU Weihui, SUN Mingliang, XU Yongchang. Noble gas isotope characteristics and tracing of gas sources of natural gas in Ordos Basin[J]. Chinese Science Bulletin, 2001, 46(22): 1902-1905. doi: 10.3321/j.issn:0023-074X.2001.22.014
[25]	赵欢欢, 梁慨慷, 魏志福, 等. 松辽盆地富氦气藏差异性富集规律及有利区预测[J]. 天然气地球科学, 2023, 34(4): 628-646. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX202304004.htm ZHAO Huanhuan, LIANG Kaikang, WEI Zhifu, et al. Differential enrichment of helium-rich gas reservoirs in Songliao Basin and favorable area forecast[J]. Natural Gas Geoscience, 2023, 34(4): 628-646. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX202304004.htm
[26]	XU Sheng, NAKAI S, WAKITA H, et al. Helium isotope compositions in sedimentary basins in China[J]. Applied Geochemistry, 1995, 10(6): 643-656. doi: 10.1016/0883-2927(95)00033-X
[27]	霍秋立, 杨步增, 付丽. 松辽盆地北部昌德东气藏天然气成因[J]. 石油勘探与开发, 1998, 25(4): 17-19. doi: 10.3321/j.issn:1000-0747.1998.04.006 HUO Qiuli, YANG Buzeng, FU Li. Genesis of natural gas of eastern Changde gas pool in northern Songliao Basin[J]. Petroleum Exploration and Development, 1998, 25(4): 17-19. doi: 10.3321/j.issn:1000-0747.1998.04.006
[28]	王杰, 陈践发, 王铁冠, 等. 松辽盆地双城-太平川地区天然气成因类型及气源[J]. 石油学报, 2006, 27(3): 16-21. https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB200603003.htm WANG Jie, CHEN Jianfa, WANG Tieguan, et al. Gas source rocks and gas genetic type in Shuangcheng-Taipingchuan area of Songliao Basin[J]. Acta Petrolei Sinica, 2006, 27(3): 16-21. https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB200603003.htm
[29]	倪云燕, 戴金星, 周庆华, 等. 徐家围子断陷无机成因气证据及其份额估算[J]. 石油勘探与开发, 2009, 36(1): 35-45. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK200901006.htm NI Yunyan, DAI Jinxing, ZHOU Qinghua, et al. Geochemical characteristics of abiogenic gas and its percentage in Xujiaweizi Fault Depression, Songliao Basin, NE China[J]. Petroleum Exploration and Development, 2009, 36(1): 35-45. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK200901006.htm
[30]	YU Yunliang, NIU Wenqing, YANG Guang, et al. Mechanisms for the accumulation of deep gas in the southern Songliao Basin, China[J]. Journal of Petroleum Science and Engineering, 2019, 182: 106302. doi: 10.1016/j.petrol.2019.106302
[31]	陶士振, 戴金星, 邹才能, 等. 松辽盆地火山岩包裹体稀有气体同位素与天然气成因成藏示踪[J]. 岩石学报, 2012, 28(3): 927-938. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201203022.htm TAO Shizhen, DAI Jinxing, ZOU Caineng, et al. The trace of genesis, formation and mineral resources of natural gas and rare gas isotope existing in volcanic inclusion of Songliao Basin[J]. Acta Petrologica Sinica, 2012, 28(3): 927-938. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201203022.htm
[32]	FENG Zhiqiang, JIA Chengzai, XIE Xinong, et al. Tectonostratigraphic units and stratigraphic sequences of the nonmarine Songliao Basin, Northeast China[J]. Basin Research, 2010, 22(1): 79-95. doi: 10.1111/j.1365-2117.2009.00445.x
[33]	张玮, 李洪革, 李明杰. 松辽盆地南部长岭断陷区深层构造特征与天然气聚集[J]. 石油与天然气地质, 2008, 29(1): 120-127. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT200801021.htm ZHANG Wei, LI Hongge, LI Mingjie. Structural characteristics and gas accumulation in the deep of the Changling Fault Depression, the south Songliao Basin[J]. Oil & Gas Geology, 2008, 29(1): 120-127. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT200801021.htm
[34]	于丹, 吕延防, 付晓飞, 等. 松辽盆地北部徐家围子断陷断裂构造特征及对深层天然气的控制作用[J]. 地质论评, 2010, 56(2): 237-245. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP201002011.htm YU Dan, LV Yanfang, FU Xiaofei, et al. Characteristics of fault structure and its control on deep gas reservoir in Xujiaweizi Fault Depression, Songliao Basin[J]. Geological Review, 2010, 56(2): 237-245. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP201002011.htm
[35]	戴金星, 胡国艺, 倪云燕, 等. 中国东部天然气分布特征[J]. 天然气地球科学, 2009, 20(4): 471-487. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX200904002.htm DAI Jinxing, HU Guoyi, NI Yunyan, et al. Distribution characteristics of natural gas in Eastern China[J]. Natural Gas Geoscience, 2009, 20(4): 471-487. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX200904002.htm
[36]	WEI Guoqi, WANG Dongliang, WANG Xiaobo, et al. Characteristics of noble gases in the large Gaoshiti-Moxi gas field in Sichuan Basin, SW China[J]. Petroleum Exploration and Development, 2014, 41(5): 585-590. doi: 10.1016/S1876-3804(14)60069-0
[37]	何大祥, 唐友军, 胡锦杰, 等. 塔里木盆地天然气中稀有气体地球化学特征[J]. 石油与天然气地质, 2020, 41(4): 755-762. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT202004010.htm HE Daxiang, TANG Youjun, HU Jinjie, et al. Geochemical characteristics of noble gases in natural gases from the Tarim Basin[J]. Oil & Gas Geology, 2020, 41(4): 755-762. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT202004010.htm
[38]	孙明良. 天然气中稀有气体同位素的分析技术[J]. 沉积学报, 2001, 19(2): 271-275. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB200102017.htm SUN Mingliang. Measurement technology of noble gas isotopes in natural gases[J]. Acta Sedimentologica Sinica, 2001, 19(2): 271-275. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB200102017.htm
[39]	鲁雪松, 魏立春, 宋岩, 等. 松辽盆地南部长岭断陷高含CO₂气藏成藏机制分析[J]. 天然气地球科学, 2011, 22(4): 657-663. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201104014.htm LU Xuesong, WEI Lichun, SONG Yan, et al. Study on the pool-forming mechanism of high content CO₂ gas pools in Changling Fault-Depression, south Songliao Basin[J]. Natural Gas Geoscience, 2011, 22(4): 657-663. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201104014.htm
[40]	TRIELOFF M, KUNZ J, CLAGUE D A, et al. The nature of pristine noble gases in mantle plumes[J]. Science, 2000, 288(5468): 1036-1038.
[41]	BALLENTINE C J, PORCELLI D, WIELER R. Noble gases in mantle plumes[J]. Science, 2011, 291(5512): 2269.
[42]	BALLENTINE C J, O'NIONS R K. The nature of mantle neon contributions to Vienna Basin hydrocarbon reservoirs[J]. Earth and Planetary Science Letters, 1992, 113(4): 553-567.
[43]	XU Yongchang, SHEN Ping, TAO Mingxin, et al. Geochemistry on mantle-derived volatiles in natural gases from Eastern China oil/gas provinces (Ⅱ): helium, argon and hydrocarbons in mantle volatiles[J]. Science in China (Series D: Earth Sciences), 1997, 40(3): 315-321.
[44]	刚文哲, 高岗, 郝石生, 等. 论乙烷碳同位素在天然气成因类型研究中的应用[J]. 石油实验地质, 1997, 19(2): 164-167. doi: 10.11781/sysydz199702164 GANG Wenzhe, GAO Gang, HAO Shisheng, et al. Carbon isotope of ethane applied in the analyses of genetic types of natural gas[J]. Experiment Petroleum Geology, 1997, 19(2): 164-167. doi: 10.11781/sysydz199702164
[45]	MOREIRA M, RAQUIN A. The origin of rare gases on Earth: the noble gas'subduction barrier'revisited[J]. Comptes Rendus Géoscience, 2007, 339(14/15): 937-945.
[46]	STAUDACHER T, ALLōGRE C J. Terrestrial xenology[J]. Earth and Planetary Science Letters, 1982, 60(3): 389-406.
[47]	XU Yongchang, SHENG Ping, TAO Mingxin, et al. Industrial accumulation of mantle source helium and the Tanchenglujiang fracture zone[J]. Chinese Science Bulletin, 1991, 36(6): 494-498.
[48]	NOHDA S, CHEN Hai, TATSUMI Y. Geochemical stratification in the upper mantle beneath NE China[J]. Geophysical Research Letters, 1991, 18(1): 97-100.
[49]	TATSUMOTO M, BASU A R, HUANG Wankang. Sr, Nd, and Pb isotopes of ultramafic xenoliths in volcanic rocks of Eastern China: enriched components EMI and EMII in subcontinental lithosphere[J]. Earth and Planetary Science Letters, 1992, 113(1/2): 107-128.
[50]	陈俊, 王鹤年. 地球化学[M]. 北京: 科学出版社, 2004: 418. CHEN Jun, WANG Henian. Geochemistry[M]. Beijing: Science Press, 2004: 418.
[51]	云金表, 殷进垠, 金之钧. 松辽盆地深部地质特征及其盆地动力学演化[J]. 地震地质, 2003, 25(4): 595-608. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDZ200304007.htm YUN Jinbiao, YIN Jinyin, JIN Zhijun. Deep geological feature and dynamic evolution of the Songliao Basin[J]. Seismology and Geology, 2003, 25(4): 595-608. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDZ200304007.htm
[52]	POLYAK B G, PRASOLOV E M, ERMÁK V, et al. Isotopic composition of noble gases in geothermal fluids of the Krušné Hory Mts., Czechoslovakia, and the nature of the local geothermal anomaly[J]. Geochimica et Cosmochimica Acta, 1985, 49(3): 695-699.
[53]	徐永昌. 天然气中稀有气体地球化学[M]. 北京: 科学出版社, 1998: 231. XU Yongchang. Geochemistry of noble gas in natural gas[M]. Beijing: Science Press, 1998: 231.