松辽盆地天然气中稀有气体地球化学特征及其地质意义

李伟; 陈践发; 王杰; 王晓波; 何大祥; 王东良; 刘凯旋; 尤兵; 陈聪; 付娆; 唐帅旗; 张佳琦

doi:10.11781/sysydz202403576

松辽盆地天然气中稀有气体地球化学特征及其地质意义

doi: 10.11781/sysydz202403576

李伟^{1, 2,},
陈践发^1, ,,
王杰³,
王晓波⁴,
何大祥⁵,
王东良⁴,
刘凯旋¹,
尤兵¹,
陈聪¹,
付娆¹,
唐帅旗¹,
张佳琦¹

1.
中国石油大学(北京) 地球科学学院油气资源与工程全国重点实验室, 北京 102249
2.
天水师范学院资源与环境工程学院, 甘肃天水 741000
3.
中国石化石油勘探开发研究院无锡石油地质研究所, 江苏无锡 214126
4.
中国石油天然气股份有限公司勘探开发研究院, 北京 100089
5.
长江大学湖北省油气地球化学与环境重点实验室, 武汉 430100

基金项目:

国家重点研发计划项目 2021YFA071900

“十三五”国家科技重大专项 2016ZX05007003-004

甘肃省教育科技项目 2022QB-146

天水师范学院基金项目 CXJ2020-27

详细信息

作者简介:
李伟(1986—)，男，博士生，从事稀有气体地球化学、天然气地质学研究。E-mail：liwei05@lzu.edu.cn

通讯作者:
陈践发(1961—)，男，博士，教授，从事天然气地球化学研究。E-mail：jfchen@cup.edu.cn

中图分类号: TE133.1
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出版历程
- 收稿日期: 2023-11-05
- 修回日期: 2024-03-18
- 刊出日期: 2024-05-28

Geochemical characteristics and geological significance of noble gases in natural gas from Songliao Basin, China

1.
National Key Laboratory of Petroleum Resources and Engineering, College of Geosciences, China University of Petroleum (Beijing), Beijing 102249, China
2.
School of Resources and Environmental Engineering, Tianshui Normal University, Tianshui, Gansu 741000, China
3.
Wuxi Research Institute of Petroleum Geology, SNOPEC, Wuxi, Jiangsu 214126, China
4.
Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100089, China
5.
Hubei Key Laboratory of Oil & Gas Geochemistry and Environment, Yangtze University, Wuhan, Hubei 430100, China

摘要

摘要: 稀有气体地球化学已运用于地球深部物质及天体陨石研究，随着测量技术的进步，在天然气研究中也开始得到越来越多的应用。使用目前最先进的稀有气体质谱仪，对中国东部松辽盆地中深部天然气的稀有气体全组分丰度及同位素进行了系统的分析，明确了断陷盆地稀有气体的组成特征。研究表明，天然气中稀有气体的丰度从轻稀有气体到重稀有气体具有逐渐减小的反“厂”字形趋势。稀有气体的同位素比值³He/⁴He为2.64×10^-6、²⁰Ne/²²Ne为9.94、²¹Ne/²²Ne为0.029 22、⁴⁰Ar/³⁶Ar为743.7，均高于大气值，⁸⁰Kr、⁸⁴Kr、⁸⁶Kr、^131-136Xe均表现出相对大气过剩的特征，显示天然气中有幔源气体的混入。综合稀有气体的组成特征，说明松辽盆地中深部天然气均为壳幔混源的无机成因，而且不同构造区块、不同类别天然气的幔源组分贡献存在一定差异。对比稀有气体组成与天然气类型发现，轻稀有气体可以较好地区分天然气的类型，而重稀有气体的组成在各种天然气中没有明显差别。稀有气体同位素除了可以示踪天然气来源外，还可以应用在判别天然气成因、区分天然气类型、表征大地构造等方面。
- 稀有气体 /
- 稀有气体同位素 /
- 地球化学特征 /
- 氦源 /
- 壳幔混源 /
- 松辽盆地
Abstract: Geochemistry of noble gases has been applied to the study of deep Earth materials and celestial meteorites. With advancements in measurement technology, it is also increasingly being used in natural gas research. Using the most advanced noble gas mass spectrometer, a systematic analysis was conducted on the abundance and isotopes of noble gas samples collected from the middle and deep Songliao Basin in eastern China to elucidate the compositional characteristics of noble gases in a faulted basin. The findings reveal that the abundance of noble gases in natural gas decreases from light noble gases to heavy noble gases in a left-to-right reversed L-shaped pattern. Specifically, the isotopic ratios of noble gases are: ³He/⁴He at 2.64×10^-6, ²⁰Ne/²²Ne at 9.94, ²¹Ne/²²Ne at 0.029 22, and ⁴⁰Ar/³⁶Ar at 743.7, all of which are higher than atmospheric values. The isotopes ⁸⁰Kr, ⁸⁴Kr, ⁸⁶Kr, and ^131-136Xe show relative excess compared to atmospheric levels, indicating the mixing of mantle-derived gases in the natural gas. Based on the compositional characteristics of noble gases, this study suggests that the natural gas in the middle and deep Songliao Basin originated from inorganic crust and mantle mixing. Additionally, certain differences exist in the contribution of mantle-derived components across different tectonic blocks and categories of natural gas within the basin. Comparison between noble gas compositions and the types of natural gas demonstrates that light noble gases distinguish effectively between different types of natural gas, whereas the composition of heavy noble gases shows no significant differences among various types of natural gas. Noble gas isotopes, in addition to tracing the source of natural gas, can also be used to determine natural gas genesis, distinguish natural gas types and characterize tectonic settings.
- noble gas /
- isotope of noble gas /
- geochemical characteristics /
- helium source /
- crust-mantle mixed source /
- Songliao Basin
注释:

利益冲突声明/Conflict of Interests

所有作者声明不存在利益冲突。

All authors disclose no relevant conflict of interests.

作者贡献/Authors’Contributions

李伟、陈践发参与实验设计；李伟、王晓波、何大祥、刘凯旋完成实验操作；李伟、陈践发、王杰、王东良、尤兵、陈聪、付娆、唐帅旗、张佳琦参与论文写作和修改。所有作者均阅读并同意最终稿件的提交。

The study was designed by LI Wei and CHEN Jianfa. The experimental operation was completed by LI Wei, WANG Xiaobo, HE Daxiang and LIU Kaixuan. The manuscript was drafted and revised by LI Wei, CHEN Jianfa, WANG Jie, WANG Dongliang, YOU Bing, CHEN Cong, FU Rao, TANG Shuaiqi and ZHANG Jiaqi. All authors have read the last version of the paper and consented to its submission.

HTML全文

图 1 松辽盆地构造背景

据参考文献[25, 32]修改。

Figure 1. Tectonic background of Songliao Basin

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图 2 松辽盆地天然气中稀有气体分布直方图

Figure 2. Histogram of noble gas distribution in natural gas of Songliao Basin

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图 3 松辽盆地天然气中稀有气体系列特征

Figure 3. Characteristics of noble gas series in natural gas of Songliao Basin

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图 4 松辽盆地天然气中He、Ne的丰度及其同位素比值相关性

图b据参考文献[42]修改。

Figure 4. Abundance of He and Ne and their isotope ratio correlations in natural gas of Songliao Basin

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图 5 松辽盆地天然气中Ar的丰度与其同位素比值的相关性

Figure 5. Correlation between Ar abundance and its isotope ratios in natural gas of Songliao Basin

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图 6 松辽盆地天然气中Kr各同位素比值相关性

Figure 6. Correlation of Kr isotope ratios in natural gas of Songliao Basin

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图 7 松辽盆地天然气中Xe同位素比值系列与相关关系

图f据参考文献[7]修改。

Figure 7. Correlations of Xe isotope ratio series in natural gas of Songliao Basin

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图 8 松辽盆地天然气中稀有气体同位素系列特征

Figure 8. Characteristics of noble gas isotope series in natural gas of Songliao Basin

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图 9 稀有气体判识松辽盆地天然气成因及来源

图b据参考文献[43]修改；图c据参考文献[42]修改；图d据参考文献[20]修改。

Figure 9. Identification of genesis and sources of natural gas of Songliao Basin by noble gases

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表 1 松辽盆地天然气主要组分与稀有气体组分测试结果

Table 1. Test results of main components and noble gas components of natural gas in Songliao Basin

构造区域	井名	C₁/%	C₂₊/%	CO₂/%	N₂/%	He/10^-6	Ne/10^-6	Ar/10^-6	Kr/10^-6	Xe/10^-6
长岭断陷	长深2	1.57	0.01	97.45	0.71	129.52	10.02	37.337	0.007 4	0.000 750
	长深4	0.69	0.00	98.56	0.00	82.29	4.28	8.289	0.002 8	0.000 104
	长深1	71.44	1.24	22.04	4.93	449.11	224.82	318.238	0.332 8	0.019 636
	长深1-2	65.79	1.20	28.12	4.55	451.40	257.14	288.638	0.225 3	0.011 667
	长深D1-1	92.18	1.89	0.58	4.67	452.67	410.64	374.687	0.546 6	0.032 186
	长深平2	68.17	1.19	25.65	4.70	513.95	240.12	311.047	0.324 2	0.014 402
	长深平3	67.49	1.17	26.54	4.66	486.30	195.35	319.622	0.180 4	0.007 934
	长深平4	69.41	1.21	24.41	4.78	563.49	232.07	345.812	0.220 7	0.011 482
	长深平7	65.43	1.14	28.31	4.48	422.30	0.93	261.093	0.093 6	0.004 462
徐家围子断陷	升深1-1	94.85	2.23	0.00	2.88	345.07	544.63	185.021	0.633 5	0.030 205
	升深平1	92.53	1.86	2.30	3.23	339.79	159.86	129.482	0.142 3	0.005 868
	徐深1	94.08	2.95	1.67	1.23	145.89	171.10	80.570	0.147 1	0.008 692
	徐深1-101	94.76	3.33	0.41	1.34	158.92	98.24	218.811	0.143 6	0.017 782
	徐深1-205	93.34	3.21	1.95	1.38	152.06	336.48	243.370	0.347 9	0.048 496
	徐深1-3	95.56	2.85	0.27	1.28	139.79	231.13	233.080	0.267 2	0.051 738
	徐深6	95.22	3.05	0.40	0.30	192.60	220.99	111.375	0.201 7	0.014 847
	徐深603	96.53	2.47	0.00	1.16	129.71	493.46	518.918	0.653 7	0.136 657
	徐深6-101	96.42	2.56	0.00	1.00	140.96	167.29	93.406	0.153 6	0.012 089
	徐深6-3	96.01	2.73	0.00	1.24	153.77	359.64	106.900	0.434 2	0.021 722
注: He、Ne、Ar、Kr、Xe的大气标准值分别为5.24×10^-6、18.18×10^-6、0.934%、1.14×10^-6、8.7×10^-9。

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表 2 地球各圈层的稀有气体同位素比值

Table 2. Noble gas isotope ratios of Earth's spheres

来源	(³He/⁴He)/10^-6	²⁰Ne/²²Ne	²¹Ne/²²Ne	⁴⁰Ar/³⁶Ar	¹²⁹Xe/¹³⁰Xe	¹³⁶Xe/¹³⁰Xe	备注
MORB	12.60	13.20	0.697	1 600	6.5~7.0	2.1~2.4	文献[7, 40]
地壳	0.03	0.30	0.470	4 400			文献[41]
大气	1.40	9.80	0.029	295.5	6.496	2.18	文献[7]

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表 3 松辽盆地天然气中轻稀有气体同位素分布

Table 3. Isotopic distribution of light noble gases in natural gas of Songliao Basin

天然气类型	样品数/个	(³He/⁴He)/10^-6	²⁰Ne/²²Ne	²¹Ne^/22Ne	³⁸Ar/³⁶Ar	⁴⁰Ar/³⁶Ar
C-Gas	2	5.06	10.00	0.028 75	0.176 9	501.7
L-Gas	7	3.37	9.91	0.029 44	0.189 2	1 288.6
X-Gas	10	1.64	9.95	0.029 16	0.188 6	410.6

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表 4 松辽盆地天然气中Kr同位素分布

Table 4. Kr isotope distribution in natural gas of Songliao Basin

天然气类型	样品数/个	⁷⁸Kr/⁸³Kr	⁸⁰Kr/⁸³Kr	⁸²Kr/⁸³Kr	⁸⁴Kr/⁸³Kr	⁸⁶Kr/⁸³Kr
C-Gas	2	0.031 4	0.188 1	0.973	5.23	1.83
L-Gas	7	0.030 6	0.194 9	0.990	5.32	1.70
X-Gas	10	0.030 8	0.194 7	1.000	5.29	1.72

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表 5 松辽盆地天然气中Xe同位素分布

Table 5. Xe isotope distribution in natural gas of Songliao Basin

天然气类型	样品数/个	¹²⁴Xe/¹³⁰Xe	¹²⁶Xe/¹³⁰Xe	¹²⁸Xe/¹³⁰Xe	¹²⁹Xe/¹³⁰Xe	¹³¹Xe/¹³⁰Xe	¹³²Xe/¹³⁰Xe	¹³⁴Xe/¹³⁰Xe	¹³⁶Xe/¹³⁰Xe
C-Gas	2	0.024 2	0.023 1	0.476 5	6.478	5.271	7.53	2.86	2.41
L-Gas	7	0.022 3	0.021 5	0.469 1	6.542	5.289	7.17	2.81	2.43
X-Gas	10	0.021 3	0.021 0	0.460 0	6.466	5.288	6.98	2.77	2.41

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