AROMATIC—STERANES AND THEIR IDENTIFICATION BY GC—MS
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摘要: 作者在总结国内外资料的基础上,论述了芳甾烷的来源、演化、结构等地球化学特征,并通过色谱-质谱分析,鉴定出15种新的芳甾烷化合物。同时作者还详细介绍了芳甾烷的质谱反应机理,为研究芳甾烷的结构和鉴定供了依据。Abstract: Based on the summerization of information home and abroad,geochem-ical characteristics i.e.source,evolution,and texture of aromatic steranes are described.15 new compounds of aromatic sterane were identified by GC-MS.In addition,the authors explained in detail the MS reactional mechanism of the compounds of aromatic steranes,which would provide evidences for the study and identification of the texture of aromatic steranes.
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[1] 王忠然等,单芳幽烷的GC/MS鉴定及其在石油勘探上的应用,沉积学报,1983年第1期. [2] 史继扬、A.S.Mackenzie等,胜利油田原油和生油岩中的生物标志化合物及其应用,地球化学,1982年第1期。 [3] A.S.Mackeazie et al.,1981,Molecular Parameters of Maturatioa in the Toarcian Shales,Paris Basin,France-Changes is Aromatic Steroid HYdrocabons. Geochemica et Cosmochi-mica Acta,Vol.45,No.8,P.1345. [4] A.S.Mackenzie et al.,1982,Chemical Fossils:The Geological Fate of Sleroids.Scieaces,217(4559),P.491. [5] J.Riolo et al.,Distribution of Aromatic Steroids in Geological Samples:Their Evaluation os Geochemical Parameters.Organic Geochemistry.No.,P.981 [6] W.K.Selfert et al.1978,Application of Steranes,Terpanes and Momoaromatics of Matura-tion,Migration and Source of Crude Oils.Geochemica et Cosmochimeca Acta Vo1.No.1,P.77 [7] W.K.Seifert et al.,1981,Geomemetic Synthesis,Structure Assignment,and Geochemical Correlation Applicatioa of Moaoaromatized Petroloum Storoids.Advances in Organic Geoche-mistrY,P.710-724.
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