STUDY ON THE OIL SOURCE OF CRUDE OILS FROM WELL QUN-5 AND WELL QU-1 IN THE TARIM BASIN-NEW EVIDENCES FROM FATTY ACIDS AND ALKYL CYCLOHEXANES SERIES COMPOUNDS
-
摘要: 塔里木盆地群5井和曲1井原油中的脂肪酸主要来自母源,其组成特征反映了母质主要为菌藻类.群5井和曲1井原油含有丰富的烷基环己烷系列化合物.脂肪酸和烷基环己烷系列分布特征,在群5井和曲1井原油中差别显著,反映了它们具有不同的油源.结合原油的碳同位素、长链三环萜烷、藿烷和甾烷组成特征,认为塔里木盆地群5井原油可能来自寒武-奥陶系海相碳酸盐岩生油岩,而曲1井原油可能来自石炭系海相泥岩生油岩.Abstract: Oils from well Qun-5 and well Qu-1 in the Tarim Basin contain abundant fatty acids and a series of long-chain alkyl cyclohexanes.The compositions of fatty acids are in the range of C10-C26,and exhibit a model distribution with maximum at C16 for oil from well Qun-5 and at C 15 for oil from well Qu-1.Studied data show that these fatty acids come mainly from their source rocks and are derived from algae and bacteria.The compositions of long-chain alkyl cyclohexanes are in the range of C12-C32.They contain a model distribution with maximum at C13 for oil from well Qun-5 and bimodel distributions with maxima at C14,C15 or C19.Significant differences in the distributions of fatty acids and long-chain alkyl cyclohexanes in oils from well Qun-5 and well Qu-1 indicatethat these oils have different oil sources.Together with the features of compositions of carbon isotopes,long-chain tricyclic terpanes,hopanes and steranes,it is suggested that oil from well Qun-5 originate from Cambrian-Ordovician marine carbonate source rock and oil from well Qu-1 originate from Carboniferous marine mudstone source rock.
-
Key words:
- fatty acid /
- long-chain alkyl cyclohexane /
- crude oil /
- the Tarim Basin /
-
[1] 刘洛夫,王伟华,徐新德,等.塔里木盆地群5井原油芳烃地球化学研究[J].沉积化学报,1996,14(2):47-55. [2] JafféR,Gallardo M T.Application of carboxylic acid biomarkers as indicators of biodegradation and migration of crude oils from the Maracaibo Basin,Western Venezuela[J].Org Geochem,1993,20(7):973-984. [3] JafféR,Gardinali P R.Generation and maturation of carboxylic acids in ancient sedimdnts of the Maracaibe Basin,Venezuela[J].Org Geochem,1990,16:211-218. [4] Heras X,Grimalt J O,Albaiges J,et al.Origin and diagenesis of the organic matter in Miocene freswater lacustrine phosphates(Cerandya Basin,Eastern Pyrencos)[J].Org Geochem,1989,14:667-677. [5] 段毅,罗斌杰,钱古盛,等.南沙海洋沉积物中脂肪酸组成和分布特征[J].海洋地质与第四纪地质,1996,16(2):23-31. [6] Matsuda H,Koyama T.Early diagenesis of fatty acids in lacustrine sedimdnts-I.Identification and distribution of fatty acids in recent seniment from a freshwater lake[J].Geochim Cosmochim Acta,1977,41:771-783. [7] 段毅,崔明中,罗斌杰,等.我国海洋沉降颗粒物质的有机地球化学研究——I.有机质通量及烃类化合物和脂肪酸分布特征[J].中国科学(D辑),1997,(5):442-446. [8] Duan Yi,Wen Qibin,Zheng Guodong,et al.Isotopic composition and probable origins of individual fatty acids in modern sediments from Ruoergai Marsh and Nansha Sea,China[J].Organic Geochemistry,1997,(7/8):583-589. [9] Mackenzie A S,Wolff G A,Maxwell J R.Fatty acids in some biodegraded petroleums.Possible origin and significance[A].Bior ф y,et al.Advances in Organic Geochemistry,1981[C].Wiley,Chichester,1983.637-649. [10] 妥进才,曾凡刚,黄杏珍.泌阳凹陷湖相碳酸盐岩中的三环萜烷及其热演化[J].地球化学,1999,28(1):34-41. [11] Volkman J K.A review of sterol markers for marine and terrigenous organic matter[J].Org Geochem,1986,(9):83-99. [12] 段毅,惠荣耀,丁安娜,等.塔里木盆地原油的成因研究[J].甘肃地质学报,1997,6(1):67-73.
计量
- 文章访问数: 681
- HTML全文浏览量: 73
- PDF下载量: 333
- 被引次数: 0