利用咔唑类化合物研究油气的运移——以塔里木盆地环阿瓦提凹陷志留系古油藏为例

刘洛夫; 霍红; 李超; 赵素平; 陈元壮; 陈利新; 郭永强; 李燕; 李双文

doi:10.11781/sysydz200604366

利用咔唑类化合物研究油气的运移——以塔里木盆地环阿瓦提凹陷志留系古油藏为例

doi: 10.11781/sysydz200604366

刘洛夫^1,2,
霍红^1,2,
李超^1,2,
赵素平^1,2,
陈元壮^1,2,
陈利新^1,2,
郭永强^1,2,
李燕^1,2,
李双文^1,2

1.
中国石油大学教育部石油天然气成藏机理重点实验室, 北京 102249
2. 中国石油大学盆地与油藏研究中心, 北京 102249

基金项目: 国家重点科技攻关项目(96-111-01-03-04).

详细信息

作者简介:
刘洛夫(1958- ),男(汉族),教授、博士生导师,主要从事地球化学和石油地质学的教学与科研工作.

中图分类号: TE122.12
计量
- 文章访问数: 735
- HTML全文浏览量: 60
- PDF下载量: 280
- 被引次数: 0
出版历程
- 收稿日期: 2005-12-21
- 修回日期: 2006-05-18
- 刊出日期: 2006-07-28

STUDY OF PETROLEUM MIGRATION OF THE SILURIAN ANCIENT POOLS AROUND AWATI SAG IN THE TARIM BASIN USING CARBAZOLE COMPOUNDS

1.
Key Laboratory for Hydrocarbon Accumulation Mechanism, Ministry of Education, China University of Petroleum, Beijing 102249, China
2. Basin and Reservoir Research Center, China University of Petroleum, Beijing, 102249, China

摘要

摘要: 咔唑类化合物是原油中极性较大的化合物,是研究油气运移的有效指标.在油气运移过程中,咔唑类与围岩发生作用而被吸附;苯并咔唑比苯并咔唑运移速度快;C₃-咔唑的极性相对于C₂-咔唑的较小而运移较快.因此,随运移距离增大,原油中的咔唑类化合物的含量将不断减少,苯并咔唑/苯并咔唑比值增大,C₂-咔唑/C₃-咔唑比值变小.塔里木盆地的第二期油气成藏发生在海西晚期,阿瓦提凹陷在海西期不断沉降,为塔里木盆地主要的生油凹陷,寒武系—下奥陶统源岩此时处于大量排烃期,根据上述几项含氮化合物指标的研究可知,排出的油气从生烃中心向四周呈辐射状运移,在构造高部位聚集成藏,晚海西期运动时被抬升至地表形成现今广泛分布的干沥青.
- 咔唑类化合物 /
- 油气运移 /
- 古油藏 /
- 志留系 /
- 塔里木盆地
Abstract: Carbazoles are polar compounds in oils,and they are useful indicators for study of hydrocarbon migration.In oil migration,carbazoles have effects with and can be adsorbed to country rocks;Benzo[a]carbazole migrates faster than benzo[c]carbazole;C₃-carbazole has smaller polarity than C₂-carbazole and the former can migrates faster.Therefore,with increasing the migrating distance,amount of carbazole in oil decreases,Benzo[a]carbazole/ benzo[c]carbazole ratio increases,and C₂-carbazole/C₃-carbazole value reduces.The second period of hydrocarbon reservoir formation in the Tarim Basin took place in later Hercynian.In Hercynian,the Awati Sag kept subsiding,and it was the major hydrocarbon-generating sag in the Tarim Basin.At that time,the Cambrian-lower Ordovician source rocks in the Awati sag were in the phase of large-scale hydrocarbon expulsion,and based on the above-mentioned indices of nitrogen compounds,the expelled hydrocarbons migrated in all directions from the hydrocarbon generation center and were trapped in structural highs.These hydrocarbon pools rose to the surface in the end of Hercynian and the hydrocarbons formed widely distributed dry asphalts.
- carbazole compound /
- hydrocarbon migration /
- ancient pool /
- Silurian /
- the Tarim Basin

HTML全文

参考文献(14)

[1]	丁勇,王允诚,徐明军.塔河油田志留系成藏条件分析[J].石油实验地质,2005,29(3):232～237
[2]	李贤庆,侯读杰,肖贤明等.应用含氮化合物探讨油气运移和注入方向[J].石油实验地质,2004,26(2):200～205
[3]	邵志兵.塔里木盆地塔河油区奥陶系原油中性含氮化合物特征与运移研究[J].石油实验地质,2005,27(5):496～501
[4]	李素梅,刘洛夫,王铁冠.生物标志化合物和含氮化合物作为油气运移指标有效的对比研究[J].石油勘探与开发,2000,27(4):95～98
[5]	李素梅,刘洛夫,王铁冠等.利用非烃技术探讨尕斯库勒油田E13油藏的充注模式[J].地球科学--中国地质大学学报,2001,26(6):621～626
[6]	王铁冠,李素梅,张爱云等.利用原油含氮化合物研究油气运移[J].石油大学学报(自然科学版),2000,24(4):83～86
[7]	刘洛夫,徐新德.含氮化合物与石油运移研究[J].勘探家,1996,1(2):33～37
[8]	刘洛夫,毛东风.石油运移研究的新方法[J].地球科学进展,1996,11(6):607～610
[9]	刘洛夫,徐新德,毛东风等.咔唑类化合物在油气运移研究中的应用初探[J].科学通报,1997,42(4):420～423
[10]	Liu Luofu.Distribution and significance of carbazole compounds in Paleozoic oils from the Tazhong Uplift,Tarim[J].Acta Geologica Sinica,1998,72(1):87～93
[11]	刘洛夫.塔里木盆地群4井原油吡咯类含氮化合物地球化学研究[J].沉积学报,1997,15(2):184～187
[12]	刘洛夫,康永尚.运用原油吡咯类含氮化合物研究塔里木盆地塔中地区石油的二次运移[J].地球化学,1998,27(5):475～482
[13]	Liu Luofu,Kang Yongshang.Study on secondary migration of hydrocarbons in Tazhong area of Tarim basin in terms of carbazole compounds[J].Chinese Journal of Geochemistry,1999,18(2):97～103
[14]	Liu Luofu,Xu Xinde,Mao Dongfeng,et al.Application of carbazole compounds in study of hydrocarbon migration[J].Chinese Science Bulletin,1997,42(23):1970～1973