开鲁盆地陆西凹陷原油地球化学特征

周树青; 黄海平; 刘玉明

doi:10.11781/sysydz200706598

开鲁盆地陆西凹陷原油地球化学特征

doi: 10.11781/sysydz200706598

中国地质大学能源学院, 北京 100083

基金项目: 教育部科学技术研究重点项目(106112)

详细信息

作者简介:
周树青(1969- ),女(汉族),河南浚县人,博士研究生,主要从事石油地质、成藏地球化学研究.

中图分类号: TE133.1
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出版历程
- 收稿日期: 2007-01-22
- 修回日期: 2007-10-29
- 刊出日期: 2007-11-28

GEOCHEMICAL CHARACTERISTICS OF THE CRUDE OIL IN THE LUXI SAG, THE KAILU BASIN

School of Energy Resources, Chinese University of Geosciences, Beijing 100083, China

摘要

摘要: 开鲁盆地陆西凹陷是辽河外围盆地中勘探程度最高、发现油藏最多的地区。通过原油样品的精细地球化学分析,研究了陆西凹陷包1块和包14块原油的成熟度、生源输入和沉积环境特征。陆西凹陷包1块和包14块原油具有相似的地球化学特征:Pr/Ph小于0.6;甾烷分布以C₂₉甾烷为主;三环萜明显小于五环萜,三环萜/五环萜比值小于0.15,三环萜以C₂₃为基峰,五环萜以C₃₀为基峰,Ts/Tm在0.7~1.0左右,含有一定量的γ蜡烷。但二者也有一定差异,包14块成熟度略高;正构烷烃分布包1块多以C₂₀为基峰,包14块多以C₂₁为基峰;包1块C_15-21/C_22-28比值比包14块高;包1块具有较高的γ蜡烷指数,指示沉积时较强的盐度环境;包1块藿烷/甾烷比值较低,可能反映藻类比较发育和高盐度对细菌的抑制作用。
- 生物标志物 /
- 原油 /
- 地球化学特征 /
- 生源输入 /
- 沉积环境 /
- 陆西凹陷 /
- 开鲁盆地
Abstract: The Luxi Sag is the area which has the highest exploration degree and the most oil and gas discoveries among the peripheral basins of Liaohe Basin.The crude oil maturity,the organic matter input and the depositional environment of Bao 1 Block and Bao 14 Block in the Luxi Sag have been studied based on the precise geochemical analysises of the crude oil samples.Many similar geochemical characteristics between the crude oils from Bao 1 Block and Bao 14 Block have been found,in Cluding:the Pr/Ph ratio is less than 0.6;the regular sterane distribution is dominated by C₂₉-steranes;the tricy Clic/pentacy Clic terpane ratio is less than 0.15,with the content of tricy Clic terpane being obviously less than pentacy Clic terpane;the base peak of the tricy Clic terpane is C₂₃ and that of the pentacy Clic terpanes is C₃₀,with the Ts/Tm ratio ranging from 0.7 to 1.0 and certain amount of gamacerene.But some differences between the two blocks also exist.Bao 14 Block has a slightly higher maturity,the base peak of n-alkanes in Bao 1 Block is mostly characterized by C₂₀,and that in Bao 14 Block is mostly characterized by C₂₁;the ratio of C_15-21/C_22-28 in Bao 1 Block is higher than that in Bao 14 Block;and Bao 1 Block has higher gamacerene index,indicating that Bao 1 Block was deposited under a higher salinity environment.The hopane/sterane ratio in Bao 1 Block is lower,suggesting that the algae were rather developed and the higher salinity environment may suppress the bateria.
- biomarker /
- crude oil /
- geochemical characteristics /
- organic matter input /
- depositional environment /
- the Luxi Sag /
- the Kailu Basin

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参考文献(28)

[1]	Seifert W K,Moldowan J M.Use of biological markers in petroleum exploration[A].In:Johns R B,ed.Methods in Geochemistry and Geophysics,Biological Markers in Sedimentary Re cord 24[C].Amsterdam:Elsevier,1986.261～290
[2]	Mackenzie A S.Application of biological markers in petroleum geochemistry[A].In:Brooks J,Welte D,eds.Advances in Petroleum Geochemistry I[C].London:Academic Press,1984.115～214
[3]	Seifert W K,Moldowan J M.Paleoreconstruction by biological markers[J].Geochimica et Cosmochimica Acta,1981,45:783～794
[4]	Moldowan J M,Fago F J,Carlson R M K,et al.Rearranged hopanes in sediments and petroleum[J].Geochimica et Cosmochimica Acta,1991,55:3333～3353
[5]	Mackenzie A S,Hoffmann C F,Maxwell J R.Molecular parameters of maturation in the Toarcian shales,Paris Basin,France III.Changes in aromatic steroid hydrocarbons[J].Geochimica et Cosmochimica Acta,1981,45:1345～1355
[6]	Peters K E,Moldowan J.M.The biomarker guide:interpreting molecular fossils in petroleum and ancient sediments[M].Englewood Cliffs:Prentice Hall,1993.1～363
[7]	Didyk B M,Simoneit B R T,Brassell S C,et al.Organic geochemical indicators of palaeoenvironmental conditions of sedimentation[J].Nature,1978,272:216～222
[8]	Peters K E,Moldowan J M,Schoell M,et al.Petroleum isotopic and biomarker composition related to source rock organic matter and depositional environment[J].Organic Geochemistry,1986,10:17～27
[9]	Hughes W B,Holba A G,Dzou L I P.The ratios of dibenzothiophene to phenanthrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks[J].Geochimica et Cosmochimica Acta,1995,59:3581～3598
[10]	ten Haven H L,de Leeuw J W,Sinninghe Damsté J S,et al.Application of biological markers in the recognition of palaeohypersaline environments[A].In:Kdts K,Fleet A J,Talbot M,eds.Lacustrine Petroleum Source-rocks,Geological Society Special Publication 40[C].London:Blackwell,1988.123～130
[11]	Volkman J K.Biological marker compounds as indicators of the depositional environments of petroleum source-rocks[A].In:Kdts K,Fleet A J,Talbot M,eds.Lacustrine Petroleum Source-rocks,Geological Society Special Publication 40[C].London:Blackwell,1988.103～121
[12]	Volkman J K,Barrett S M,Blackburn S I,et al.Microalgal biomarkers:A review of recent research developments[J].Organic Geochemistry,1998,29:1163～1179
[13]	Philp R P,Gilbert T D.Biomarker distribution in oils predominantly derived from terrigenous source material[J].Organic Geochemistry,1986,10:73～84
[14]	Mello M R,Telnaes N,Gaglianone P C,et al.Organic geochemical characterization of depositional paleoenvironments in Brazilian marginal basins[J].Organic Geochemistry,1988,13:31～46
[15]	Moldowan J M,Seifert W K,Gallegos E J.Relationship between petroleum composition and depositional environment of petroleum source-rocks[J].AAPG Bulletin,1985,69:1255～1268
[16]	Connan J.Biodegradation of crude oils in reservoirs[A].In:Brooks J,Welte D,eds.Advances in Petroleum Geochemistry I[C].London:Academic Press,1984.299～335
[17]	ten Haven H L,de Leeuw J W,Rullktter J,et al.Restricted utility of the pristane/phytane ratio as a palaeoenvironmental indicator[J].Nature,1987,330:641～643
[18]	Dahl J E P,Moldowan J M,Teerman S C,et al.Source-rock quality determination from oil biomarkers Ⅰ.A new geochemical technique[J].AAPG Bulletin,1994,78:1507～1526
[19]	Moldowan J M,Lee C Y,Sundararaman P,et al.Source correlation and maturity assessment of select oils and rocks from the Central Adriatic basin (Italy and Yugoslavia)[A].In:Moldowan J M,Albrecht P,Philp R P,eds.Biological Markers in Sediments and Petroleum[C].Englewood Cliffs:Prentice Hall,1992.370～401
[20]	Peters K E,Moldowan J M,McCaffrey M A,et al.Selective biodegradation of extended hopanes to 25-norhopanes in petroleum reservoirs:Insights from molecular mechanics[J].Organic Geochemistry,1996,24:765～783
[21]	Damsté J S,Kenig F,Koopmans M P,et al.Evidence of gammacerane as an indicator of water column stratification[J].Geochimica et Cosmochimica Acta,1995,59:1895～1900
[22]	Mello M R,Telnaes N,Gaglianone P C,et al.Organic geochemical characterization of depositional paleoenvironments in Brazilian marginal basins[J].Organic Geochemistry,1988,13:31～46
[23]	Peters K E,Moldowan J M.Effects of source,thermal maturity and biodegradation on the distribution and isomerization of homohopanes in petroleum[J].Organic Geochemistry,1991,17:47～61
[24]	Rohmer M,Bisseret P,Neunlist S.The hopanoids,prokaryotic triterpenoids and precursors of ubiquitous molecular fossils[A].In:Moldowan J M,Albrecht P,Philp R P,eds.Biological Markers in Sediments and Petroleum[C].Englewood Cliffs:Prentice Hall,1992.1～17
[25]	Farrimond P,Fox P A,Innes H E,et al.Bacterial sources of hopanoids in recent sediments:improving our understanding of ancient hopane biomarkers[J].Ancient Biomolecules,1998,2:147～166
[26]	Volkman J K,Barrett S M,Dunstan G A,et al.Sterol biomarkers for microalgae from the green algal Class prasinophyceae[J].Organic Geochemistry,1994,21:1211～1218
[27]	Huang Y,Meinschein W G.Sterols as ecological indicators[J].Geochimica et Cosmochimica Acta,1979,43:739～745
[28]	Obermajer M,Fowler M G,Snowdon L R.Depositional environment and oil generation in Ordovician source rocks from southwestern Ontario,Canada:Organic geochemical and petrological approach[J].AAPG Bulletin,1999,83:1426～1453