手持式X荧光光谱仪在济阳坳陷古近系陆相页岩岩心分析中的应用

马晓潇; 黎茂稳; 庞雄奇; 黄振凯; 蒋启贵; 李志明; 曹婷婷; 李政

doi:10.11781/sysydz201602278

手持式X荧光光谱仪在济阳坳陷古近系陆相页岩岩心分析中的应用

doi: 10.11781/sysydz201602278

1.
中国石油大学, 北京 102249
2. 中国石化石油勘探开发研究院无锡石油地质研究所, 江苏无锡 214126
3. 中国石化胜利油田分公司地质科学研究院, 山东东营 257015

基金项目: 国家重点基础研究计划(973 计划)项目(2014CB239101)资助。

详细信息

作者简介:
马晓潇(1989-),女,硕士,油气勘探地质工程专业。E-mail:maxiaoxiaocool@163.com。

通讯作者:
黎茂稳(1962-),男,研究员,从事有机地球化学研究。E-mail:limw.syky@sinopec.com。

中图分类号: TE135⁺.1
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出版历程
- 收稿日期: 2015-01-30
- 修回日期: 2015-12-23
- 刊出日期: 2016-03-28

Application of hand-held X-ray fluorescence spectrometry in the core analysis of Paleogene lacustrine shales in the Jiyang Depression

1.
China University of Petroleum, Beijing 102249, China
2. Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi, Jiangsu 214126, China
3. Geological Science Research Institute of SINOPEC Shengli Oilfield Company, Dongying, Shandong 257015, China

摘要

摘要: 中国陆相湖盆沉积相变快,表现出很强的岩石组构和化学组成非均质性。为高效刻画这种非均质性,需要获得高密度地质样品的元素地球化学特征等基础信息。利用X荧光光谱(XRF)分析技术,以济阳坳陷沙三、沙四层段泥页岩系统岩心为主要研究对象,优化手持式X荧光光谱仪岩心测试的实验条件,并选取泥页岩和砂岩典型样品进行方法测试,明确了不同岩性的XRF响应特征。通过对系统岩心高密度XRF测试,实现了高效获取岩心元素组成和岩石学特征的目的。初步应用结果表明,该方法可以有效运用于岩性和岩相划分、岩石矿物组成分布特征分析、泥页岩非均质性表征等方面,并为页岩油赋存机理研究重点样品优选奠定基础。
- 手持式X荧光光谱仪 /
- 实验优化条件 /
- 元素组成 /
- 泥页岩 /
- 古近系 /
- 济阳坳陷
Abstract: Lacustrine sedimentary facies vary rapidly in rift basins in China, exhibiting significant heterogeneity in shale fabric and chemical composition. In order to characterize the heterogeneity effectively, the analysis of closely spaced geological samples is required to obtain such data as element geochemistry. We employed the technique of X-ray fluorescence spectral analysis (XRF) to study core samples systematically collected from the mudstone/shale section of the third and fourth members of the Eocene Shahejie Formation in the Jiyang Depression, and optimized the experiment conditions of core testing conducted using a hand-held X-ray fluorescence spectrometer. Subsequently, this method was tested with selected shale and sandstone samples to determine the XRF response of diverse lithologies. Through the closely spaced XRF testing on cores, we determined the element composition and petrologic characteristics of cores. Preliminary applications showed the effectiveness of the technique for determining shale lithology and lithofacies, and thus provided a diagnostic tool for shale heterogeneity characterization.
- hand-held X-ray fluorescence spectrometer /
- optimized experiment conditions /
- elemental composition /
- mud shale /
- Paleogene /
- Jiyang Depression

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参考文献(25)

[1]	Norrish K,Hutton J T.An accurate X-ray spectrographic method for the analysis of a wide range of geological samples[J].Geochimica et Cosmochimica Acta,1969,33(4):431-453.
[2]	Potts P J,Webb P C.X-ray uorescence spectrometry[J].Journal of Geochemical Exploration,1992,44(1/3):251-296.
[3]	Fitton G.X-ray uorescence spectrometry[M]//Gill R.Modern analytical geochemistry.Harlow:Addison Wesley Longman,1997:329.
[4]	Jansen J H F,Van der Gaast S J,Koster B,et al.CORTEX,a shipboard XRF-scanner for element analyses in split sediment cores[J].Marine Geology,1999,151(1-4):143-153.
[5]	Rimmer S M.Geochemical paleoredox indicators in Devonian-Mississippian black shales,Central Appalachian Basin (USA)[J].Chemical Geology,2004,206(3-4):373-391.
[6]	Algeo T J,Maynard J B.Trace-metal covariation as a guide to water-mass conditions in ancient anoxic marine environments[J].Geosphere,2008,4(5):872-887.
[7]	徐长明.XRF技术在岩心样品快速分析中的应用研究.成都:成都理工大学,2011. Xu Changming.Application research on XRF technology applied in the quick analysis of core samples.Chengdu:Chengdu University of Technology,2011.
[8]	Rowe H,Hughes N,Robinson K.The quantification and application of handheld energy-dispersive X-ray uorescence(ED-XRF) in mudrock chemostratigraphy and geochemistry[J].Chemical Geology,2012,324-325:122-131.
[9]	雷国良,张虎才,常凤琴,等.湖泊沉积物XRF元素连续扫描与常规ICP-OES分析结果的对比及校正:以兹格塘错为例[J].湖泊科学,2011,23(2):287-294. Lei Guoliang,Zhang Hucai,Chang Fengqin,et al.Comparison and correction of element measurements in lacustrine sediments using X-ray fluorescence core-scanning with ICP-OES method:A case study of Zigetang Co[J].Journal of Lake Sciences,2011,23(2):287-294.
[10]	Tjallingii R,Röhl U,Kölling M,et al.Influence of the water content on X-ray fluorescence core scanning measurements in soft marine sediments[J].Geochemistry Geophysics Geosystems,2007,8(2):Q02004.
[11]	Brumsack H J.Geochemistry of recent TOC-rich sediments from the Gulf of California and the Black Sea[J].Geologische Rundschau,1989,78(3):851-882.
[12]	田景春,陈高武,张翔,等.沉积地球化学在层序地层分析中的应用[J].成都理工大学学报:自然科学版,2006,33(1):30-35. Tian Jingchun,Chen Gaowu,Zhang Xiang,et al.Application of sedimentary geochemistry in the analysis of sequence stratigraphy[J].Journal of Chengdu University of Technology:Science & Technology Edition,2006,33(1):30-35.
[13]	孙镇城,杨藩,张枝焕,等.中国新生代咸化湖泊沉积环境与油气生成[M].北京:石油工业出版社,1997. Sun Zhencheng,Yang Fan,Zhang Zhihuan,et al.Brackish lacustrine environment and hydrocarbon generation during Cenozoic in China[M].Beijing:Petroleum Industry Press,1997.
[14]	谭红兵,于升松.我国湖泊沉积环境演变研究中元素地球化学的应用现状及发展方向[J].盐湖研究,1999,7(3):58-65. Tan Hongbing,Yu Shengsong.Present situation and future development of elemental geochemistry in the study of lake sediments' evolution[J].Journal of Salt Lake Research,1999,(3):758-65.
[15]	Couch E L.Calculation of paleosalinities from boron and clay mineral data[J].AAPG Bulletin,1971,55(10):1829-1837.
[16]	Drummond C N,Wilkinson B H,Lohmann K C,et al.Effect of regional topography and hydrology on the lacustrine isotopic record of Miocene paleoclimate in the Rocky Mountains[J].Palaeogeography,Palaeoclimatology,Palaeoceology,1993,101(1/2):67-79.
[17]	何起祥.沉积岩和沉积矿床[M].北京:地质出版社,1978. He Qixiang.Sedimentary rocks and sedimentary deposits[M].Beijing:Geological Publishing House,1978.
[18]	王良忱,张金亮.沉积环境和沉积相[M].北京:石油工业出版社,1996. Wang Liangchen,Zhang Jinliang.Sedimentary environment and sedimentary facies[M].Beijing:Petroleum Industry Press,1996.
[19]	胡晓峰,刘招君,柳蓉,等.抚顺盆地始新统计军屯组微量元素特征及油页岩的有利成矿条件[J].吉林大学学报:地球科学版,2012,42(增刊1):60-71. Hu Xiaofeng,Liu Zhaojun,Liu Rong,et al.Trace element characteristics of Eocene Jijuntun Formation and the favorable metallogenic conditions of oil shale in Fushun Basin[J].Journal of Jilin University:Earth Science Edition,2012,42(S1):60-71.
[20]	宋明水.东营凹陷南斜坡沙四段沉积环境的地球化学特征[J].矿物岩石,2005,25(1):67-73. Song Mingshui.Sedimentary environment geochemistry in the Shasi section of southern ramp,Dongying Depression[J].Journal of Mineralogy and Petrology,2005,25(1):67-73.
[21]	Lewan M D,Maynard J B.Factors controlling enrichment of vanadium and nickel in the bitumen of organic sedimentary rocks[J].Geochimica et Cosmochimica Acta,1982,46(12):2547-2560.
[22]	Murray R W,Brink M R B,Brumsack H J,et al.Rare earth elements in Japan Sea sediments and diagenetic behavior of Ce/Ce*:Results from ODP Leg 127[J].Geochimica et Cosmochimica Acta,1991,55(9):2453-2466.
[23]	Norman M D,De Deckker P.Trace metals in lacustrine and marine sediments:A case study from the Gulf of Carpentaria,northern Australia[J].Chemical Geology,1990,82:299-318.
[24]	席胜利,郑聪斌,李振宏.鄂尔多斯盆地西缘奥陶系地球化学特征及其沉积环境意义[J].古地理学报,2004,6(2):196-206. Xi Shengli,Zheng Congbin,Li Zhenhong.Geochemical characteristics and its sedimentary environment significance of the Ordovician in the western margin of Ordos Basin[J].Journal of Palaeogeography,2004,6(2):196-206.
[25]	Rowe H,Hughes N.Strategy for developing and calibrating shale and mudstone chemostratigraphies using handheld X-ray fluorescence units[Z].AAPG Poster,2010:40634.

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