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基于岩石热解参数图版的烃源岩内部排烃效率计算方法

张冬梅 张延延 郭隽菁 胡守志 李水福

张冬梅, 张延延, 郭隽菁, 胡守志, 李水福. 基于岩石热解参数图版的烃源岩内部排烃效率计算方法[J]. 石油实验地质, 2021, 43(3): 532-539. doi: 10.11781/sysydz202103532
引用本文: 张冬梅, 张延延, 郭隽菁, 胡守志, 李水福. 基于岩石热解参数图版的烃源岩内部排烃效率计算方法[J]. 石油实验地质, 2021, 43(3): 532-539. doi: 10.11781/sysydz202103532
ZHANG Dongmei, ZHANG Yanyan, GUO Junjing, HU Shouzhi, LI Shuifu. A calculation method for the efficiency of hydrocarbon expulsion based on parameter-diagram of source rock pyrolysis[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2021, 43(3): 532-539. doi: 10.11781/sysydz202103532
Citation: ZHANG Dongmei, ZHANG Yanyan, GUO Junjing, HU Shouzhi, LI Shuifu. A calculation method for the efficiency of hydrocarbon expulsion based on parameter-diagram of source rock pyrolysis[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2021, 43(3): 532-539. doi: 10.11781/sysydz202103532

基于岩石热解参数图版的烃源岩内部排烃效率计算方法

doi: 10.11781/sysydz202103532
基金项目: 

国家自然科学基金面上项目 41672136

国家自然科学基金面上项目 42073067

详细信息
    作者简介:

    张冬梅(1968-), 女, 硕士, 高级工程师, 从事石油工程和油气地球化学实验教学与研究。E-mail: zdm2007@cug.edu.cn

  • 中图分类号: TE122.1

A calculation method for the efficiency of hydrocarbon expulsion based on parameter-diagram of source rock pyrolysis

  • 摘要: 排烃效率是研究排烃作用的关键地质参数,准确计算烃源岩排烃效率对常规和非常规油气资源评价都有重要意义。在原始生烃潜力恢复法基础上,介绍了一种热解图版法。该方法是利用氢指数与最大热解峰温关系划分有机质类型的经典图版,将有机质类型分界线和成熟度趋势线均匀插值网格化,然后将样品的氢指数和最大热解峰温数据投点于图版中,沿着类型线向左追踪至与Ro为0.2%的成熟度线交点作为生烃指数的原始值,从而计算出排烃效率。通过南襄盆地泌阳凹陷泌页1井66个烃源岩实测数据,研究了排烃效率与烃源岩有机质丰度、类型、成熟度(ATM)特性以及页岩油富集程度的关系。结果表明,与人为赋值法相比,热解图版法获得的排烃效率与有机质ATM特性更具规律性,与页岩油富集程度的吻合度较高,而且计算过程与结果不会出现负值和排烃效率大于100%的现象。该方法计算的烃源岩内部排烃效率合理可行,可作为原始生烃潜力恢复法计算排烃效率的补充。

     

  • 图  1  岩石热解分析参数图版

    图中数据点为南襄盆地泌阳凹陷泌页1井样品的数据点。

    Figure  1.  Parameter chart of Rock-Eval pyrolysis analysis

    图  2  南襄盆地泌阳凹陷泌页1井烃源岩排烃效率与有机质特性(ATM)的关系(两种排烃效率计算方法对比)

    图a—c为人为赋值法计算结果,A—C为热解图版法计算结果。

    Figure  2.  Correlation between hydrocarbon expulsion efficiency and organic matter characteristics (ATM) of well BYHF 1, Biyang Sag, Nanxiang Basin

    图  3  南襄盆地泌阳凹陷泌页1井5号页岩层不同方法计算的排烃效率与页岩油富集程度吻合性

    Figure  3.  Correlation between hydrocarbon expulsion efficiency calculated by different methods and shale oil enrichment degree for No.5 shale layer, well BYHF1, Biyang Sag, Nanxiang Basin

    表  1  南襄盆地泌阳凹陷泌页1井烃源岩内部排烃效率

    Table  1.   Internal expulsion efficiency of source rock of well BYHF 1, Biyang Sag, Nanxiang Basin

    样品序号 Tmax /℃ 现今IH/(mg·g-1) 残烃指数/(mg·g-1) 干酪根类型 人为赋值法 热解图版法
    原始IH/(mg·g-1) 生烃指数/(mg·g-1) 排烃指数/(mg·g-1) 排烃效率/% 原始IH/(mg·g-1) 排烃指数/(mg·g-1) 生烃指数/(mg·g-1) 排烃效率/%
    BY01 451 613.91 20.86 750 136.09 115.24 84.67 980.21 345.45 366.30 94.31
    BY02 447 649.88 20.57 750 100.12 79.55 79.46 928.43 257.98 278.55 92.62
    BY03 446 634.17 15.60 750 115.83 100.23 86.53 908.79 259.02 274.62 94.32
    BY04 447 610.65 11.95 750 139.35 127.40 91.43 914.70 292.10 304.05 96.07
    BY05 450 615.41 12.37 750 134.59 122.22 90.81 962.27 334.49 346.86 96.43
    BY06 451 626.97 14.76 750 123.03 108.27 88.00 983.38 341.65 356.41 95.86
    BY07 449 654.26 18.94 750 95.74 76.81 80.22 955.80 282.61 301.54 93.72
    BY08 449 687.53 15.76 750 62.47 46.71 74.76 965.55 262.26 278.02 94.33
    BY09 446 609.86 15.02 750 140.14 125.12 89.28 898.58 273.70 288.72 94.80
    BY10 446 643.69 20.07 750 106.31 86.23 81.12 911.45 247.68 267.76 92.50
    BY11 446 615.31 19.39 750 134.69 115.31 85.61 901.06 266.37 285.75 93.22
    BY12 449 621.45 19.20 750 128.55 109.35 85.06 947.08 306.43 325.63 94.10
    BY13 439 415.28 31.94 1 550 134.72 102.78 76.29 527.82 80.60 112.54 71.62
    BY14 446 488.05 56.60 1 550 61.95 5.35 8.63 778.31 233.66 290.26 80.50
    BY15 444 489.37 34.55 1 550 60.63 26.08 43.01 719.99 196.07 230.62 85.02
    BY16 443 430.77 36.54 1 550 119.23 82.69 69.35 583.09 115.78 152.32 76.01
    BY17 447 536.78 23.37 1 550 13.22 -10.15 -76.81 874.95 314.80 338.17 93.09
    BY18 445 514.55 27.99 1 550 35.45 7.46 21.05 791.38 248.84 276.83 89.89
    BY19 441 423.67 87.92 1 550 126.33 38.41 30.40 559.61 48.02 135.94 35.32
    BY20 445 506.07 52.50 1 550 43.93 -8.57 -19.51 777.98 219.41 271.91 80.69
    BY21 444 516.11 54.03 1 550 33.89 -20.14 -59.44 767.53 197.39 251.42 78.51
    BY22 445 511.03 46.90 1 550 38.97 -7.93 -20.35 787.47 229.54 276.44 83.04
    BY23 444 406.36 38.56 1 550 143.64 105.08 73.16 570.51 125.59 164.15 76.51
    BY24 447 491.60 27.48 1 550 58.40 30.92 52.94 823.78 304.70 332.18 91.73
    BY25 446 525.64 23.85 1 550 24.36 0.51 2.11 835.27 285.78 309.63 92.30
    BY26 446 403.73 27.80 1 550 146.27 118.47 81.00 591.73 160.20 188.00 85.21
    BY27 445 525.94 19.45 1 550 24.06 4.61 19.15 812.16 266.77 286.22 93.20
    BY28 440 409.88 46.91 1 550 140.12 93.21 66.52 532.09 75.30 122.21 61.61
    BY29 440 493.86 32.13 1 550 56.14 24.01 42.77 633.71 107.72 139.85 77.02
    BY30 447 405.28 19.11 1 550 144.72 125.61 86.80 612.26 187.87 206.98 90.77
    BY31 448 477.57 26.84 1 550 72.43 45.59 62.94 835.32 330.91 357.75 92.50
    BY32 449 528.51 17.54 1 550 21.49 3.95 18.37 911.99 365.94 383.48 95.43
    BY33 444 525.46 35.28 1 550 24.54 -10.74 -43.75 780.43 219.69 254.97 86.16
    BY34 448 517.12 44.18 1 550 32.88 -11.30 -34.37 844.55 283.25 327.43 86.51
    BY35 444 573.28 22.22 1 550 -23.28 -45.50 195.45 841.38 245.88 268.10 91.71
    BY36 446 515.14 46.02 1 550 34.86 -11.16 -32.00 824.53 263.37 309.39 85.13
    BY37 446 450.57 53.99 1 550 99.43 45.44 45.70 694.33 189.77 243.76 77.85
    BY38 448 479.37 32.17 1 550 70.63 38.46 54.46 836.78 325.24 357.41 91.00
    BY39 447 532.62 18.20 1 550 17.38 -0.83 -4.76 873.20 322.37 340.58 94.66
    BY40 452 537.30 14.32 1 550 12.70 -1.62 -12.77 984.84 433.22 447.54 96.80
    BY41 447 436.51 36.93 1 550 113.49 76.56 67.46 693.93 220.49 257.42 85.65
    BY42 447 448.44 29.69 1 550 101.56 71.88 70.77 728.26 250.14 279.82 89.39
    BY43 446 524.23 16.64 1 550 25.77 9.13 35.44 834.67 293.80 310.44 94.64
    BY44 445 466.67 36.11 1 550 83.33 47.22 56.67 700.39 197.61 233.72 84.55
    BY45 449 401.39 46.88 1 550 148.61 101.74 68.46 688.17 239.91 286.78 83.65
    BY46 447 529.76 20.95 1 550 20.24 -0.71 -3.53 869.78 319.07 340.02 93.84
    BY47 446 458.92 20.96 1 550 91.08 70.11 76.98 714.95 235.06 256.03 91.81
    BY48 446 438.37 83.72 1 550 111.63 27.91 25.00 655.83 133.74 217.46 61.50
    BY49 445 507.99 26.04 1 550 42.01 15.97 38.02 781.52 247.49 273.53 90.48
    BY50 444 492.31 17.63 1 550 57.69 40.06 69.44 726.79 216.85 234.48 92.48
    BY51 447 580.90 10.67 1 550 -30.90 -41.57 134.55 902.47 310.90 321.57 96.68
    BY52 438 353.33 40.00 2 350 -3.33 -43.33 1 300.00 449.11 55.78 95.78 58.24
    BY53 438 253.13 43.75 2 350 96.88 53.13 54.84 325.40 28.53 72.28 39.47
    BY54 438 278.87 64.79 2 350 71.13 6.34 8.91 353.35 9.69 74.48 13.01
    BY55 445 395.35 44.96 2 350 -45.35 -90.31 199.15 570.27 129.96 174.92 74.30
    BY56 444 202.59 31.03 2 350 147.41 116.38 78.95 305.04 71.42 102.45 69.71
    BY57 443 373.30 38.64 2 350 -23.30 -61.93 265.85 527.28 115.35 153.98 74.91
    BY58 439 276.28 41.03 2 350 73.72 32.69 44.35 378.16 60.85 101.88 59.73
    BY59 438 358.33 33.33 2 350 -8.33 -41.67 500.00 453.55 61.88 95.22 64.99
    BY60 446 216.96 34.82 2 350 133.04 98.21 73.83 351.03 99.24 134.07 74.03
    BY61 447 389.72 50.47 2 350 -39.72 -90.19 227.06 591.69 151.50 201.97 75.01
    BY62 443 300.62 39.13 2 350 49.38 10.25 20.75 432.36 92.61 131.74 70.30
    BY63 442 246.95 51.22 2 350 103.05 51.83 50.30 348.83 50.66 101.88 49.73
    BY64 445 358.97 70.33 2 350 -8.97 -79.30 883.67 538.17 108.87 179.20 60.75
    BY65 446 372.67 27.91 2 350 -22.67 -50.58 223.08 562.00 161.42 189.33 85.26
    BY66 446 379.79 104.26 2 350 -29.79 -134.04 450.00 568.35 84.31 188.56 44.71
    注:人为赋值法中的原始IH为人为赋值数据,参考文献[19]获得;热解图版法中的原始IH为图版赋值数据,由图版(图 1)查得。
    下载: 导出CSV
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  • 收稿日期:  2020-11-26
  • 修回日期:  2021-03-29
  • 刊出日期:  2021-05-28

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