塔里木盆地顺南1井奥陶系原油中乙基桥键金刚烷化合物的二维气相色谱分析

余晓; 马安来; 李贤庆; 朱秀香; 费剑炜

doi:10.11781/sysydz202302327

塔里木盆地顺南1井奥陶系原油中乙基桥键金刚烷化合物的二维气相色谱分析

doi: 10.11781/sysydz202302327

余晓^{1, 2,},
马安来^3, ,,
李贤庆^{1, 2},
朱秀香⁴,
费剑炜⁴

1.
中国矿业大学(北京) 煤炭资源与安全开采国家重点实验室, 北京 100083
2.
中国矿业大学(北京) 地球科学与测绘工程学院, 北京 100083
3.
中国石化石油勘探开发研究院, 北京 102206
4.
中国石化西北油田分公司, 乌鲁木齐 830060

基金项目:

国家自然科学基金项目 42272167

国家自然科学基金项目 U19B6003

国家自然科学基金项目 41772153

中国石化科技部项目 P19024-5

中国石化科技部项目 P20058-1

中国石化科技部项目 P21085-8

详细信息

作者简介:
余晓(1996-), 男, 硕士生, 矿产普查与勘探专业, 从事油气地质和地球化学研究。E-mail: 1399209246@qq.com

通讯作者:
马安来(1969-), 男, 博士, 研究员, 从事油气地球化学与成藏机理研究。E-mail: maal.syky@sinopec.com

中图分类号: TE122.1
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- 被引次数: 0
出版历程
- 收稿日期: 2022-06-08
- 修回日期: 2023-01-17
- 刊出日期: 2023-03-28

GC×GC-TOFMS analysis of ethanodiamondoids in Ordovician oil from well SN1, Tarim Basin

YU Xiao^{1, 2
,},
MA Anlai^{3
, ,},
LI Xianqing^{1, 2},
ZHU Xiuxiang⁴,
FEI Jianwei⁴

1.
State Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology (Beijing), Beijing 100083, China
2.
College of Geoscience and Surveying Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
3.
SINOPEC Petroleum Exploration and Production Research Institute, Beijing 102206, China
4.
SINOPEC Northwest Oilfield Company, Urumqi, Xinjiang 830060, China

摘要

摘要: 运用全二维气相色谱—飞行时间质谱方法（GC×GC-TOFMS）从塔里木盆地顺托果勒地区顺南1井奥陶系原油中定量检测到81个1~3笼的乙基桥键金刚烷化合物，包括47个乙基桥键单金刚烷化合物，总含量为27 594.0 μg/g；32个乙基桥键双金刚烷化合物，总含量为4 415.1 μg/g；2个乙基桥键三金刚烷系列化合物，总含量为16.8 μg/g；建立了金刚烷—乙基桥键金刚烷的二维色谱保留指数图版。结果显示，金刚烷类和乙基桥键金刚烷类化合物保留时间位置具有如下关系：单金刚烷系列 < 乙基桥键单金刚烷系列 < 双金刚烷系列 < 乙基桥键双金刚烷系列 < 三金刚烷系列 < 乙基桥键三金刚烷系列 < 四金刚烷系列。作为石油中热稳定性最高的饱和烃类，乙基桥键金刚烷化合物的定量分析结果，有望为原油裂解和硫酸盐热化学还原反应（TSR）等油藏次生改造作用提供新的指标。
- 乙基桥键金刚烷 /
- 全二维气相色谱—飞行时间质谱 /
- 奥陶系 /
- 顺南1井 /
- 塔里木盆地
Abstract: By 2D gas chromatography and time-of-flight mass spectrometry (GC×GC-TOFMS), 81 ethanodiamondoids with 1-3 cages were detected quantitatively in Ordovician crude oil from well SN1, Shuntuoguole area, Tarim Basin, including 47 ethanoadamantanes with total content of 27 594.0 μg/g, 32 ethanodiamantanes with total content of 4 415.1 μg/g, and 2 ethanotriamantanes with total content of 16.8 μg/g. The template of 2D chromatogram retention index of diamondoids-ethanodiamondoids was constructed. The results demonstrated that the position of retention time of diamondoids and ethanodiamondoids has the following relationship, namely, adamantanes < ethanoadamantanes < diamantanes < ethanodiamantanes < triadamantanes < ethanotriamantanes < tetradamantanes. Quantitative analytical result of ethanoadamantanes as saturated hydrocarbons with the highest thermal stability in crude oil, is expected to provide new indexes for secondary reservoir reconstruction, i.e. crude oil cracking and thermochemical sulfate reduction (TSR).
- ethanodiamondoids /
- GC×GC-TOFMS /
- Ordovician /
- well SN1 /
- Tarim Basin

HTML全文

图 1 金刚烷、乙基桥键金刚烷化学结构

Figure 1. Chemical structures of diamondoids and ethanodiamondoids

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图 2 塔里木盆地顺托果勒地区顺南1井(SN1)构造位置

Figure 2. Structural location of well SN1 in Shuntuoguole area, Tarim Basin

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图 3 塔里木盆地顺托果勒地区顺南1井原油GC×GC-TOFMS总离子流图

Figure 3. TIC (total ion chromatogram) by GC×GC-TOFMS of crude oil from well SN1, Shuntuoguole area, Tarim Basin

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图 4 塔里木盆地顺托果勒地区顺南1井原油中乙基桥键金刚烷GC×GC—TOFMS点阵图

a.乙基桥键单金刚烷系列；b.乙基桥键双金刚烷系列；c.乙基桥键三金刚烷系列

Figure 4. GC×GC-TOFMS lattice diagram of ethanodiamondoids in crude oil from well SN1, Shuntuoguole area, Tarim Basin

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图 5 塔里木盆地顺托果勒地区顺南1井原油中乙基桥键单金刚烷系列化合物质谱图

Figure 5. Mass spectrum of ethanoadamantanes in crude oil from well SN1, Shuntuoguole area, Tarim Basin

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图 6 塔里木盆地顺托果勒地区顺南1井原油中乙基桥键双金刚烷化合物质谱图

Figure 6. Mass spectrum of ethanodiamantanes in crude oil from well SN1, Shuntuoguole area, Tarim Basin

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图 7 塔里木盆地顺托果勒地区顺南1井原油乙基桥键三金刚烷化合物质谱图

Figure 7. Mass spectrum of ethanotriamantanes in crude oil from well SN1, Shuntuoguole area, Tarim Basin

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图 8 塔里木盆地顺托果勒地区顺南1井原油金刚烷和乙基桥键金刚烷保留时间

Figure 8. Retention time of diamondoids and ethanodiamondoids in crude oil from well SN1, Shuntuoguole area, Tarim Basin

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表 1 塔里木盆地顺托果勒地区顺南1井原油中乙基桥键金刚烷定性和定量结果

Table 1. Qualitative and quantitative analysis results of ethanodiamondoids in crude oil from well SN1, Shuntuoguole area, Tarim Basin

序号	峰号	化合物名称	分子式	一维保留时间/s	二维保留时间/s	定量质量数	含量/(μg·g^-1)
0	I.S.-1	D₁₆-金刚烷	C₁₀D₁₆	1 796	1.41	152	332.9
1	EA-1	乙基桥键单金刚烷	C₁₂H₁₈	2 484	1.83	162	424.8
2	EA-2	1-甲基-乙基桥键单金刚烷	C₁₃H₂₀	2 524	1.65	161	737.4
3	EA-3	6-甲基-乙基桥键单金刚烷	C₁₃H₂₀	2 564	1.69	161	2 269.6
4	EA-4	2-甲基-乙基桥键单金刚烷	C₁₃H₂₀	2 596	1.77	161	833.8
5	EA-5	C₁-乙基桥键单金刚烷	C₁₃H₂₀	2 620	1.74	161	77.5
6	EA-6	C₁-乙基桥键单金刚烷	C₁₃H₂₀	2 676	1.83	161	314.7
7	EA-7	C₁-乙基桥键单金刚烷	C₁₃H₂₀	2 700	1.88	161	87.4
8	EA-8	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 884	1.77	161	402.8
9	EA-9	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 892	1.81	161	477.2
10	EA-10	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 596	1.51	175	2 196.1
11	EA-11	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 636	1.55	175	1 713.5
12	EA-12	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 660	1.56	175	358.9
13	EA-13	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 668	1.64	175	930.3
14	EA-14	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 692	1.57	175	668.5
15	EA-15	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 700	1.59	175	1 139.1
16	EA-16	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 700	1.7	175	153.7
17	EA-17	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 716	1.64	175	733.0
18	EA-18	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 740	1.66	175	1 794.8
19	EA-19	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 756	1.66	175	715.7
20	EA-20	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 772	1.72	175	452.5
21	EA-21	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 780	1.79	175	375.5
22	EA-22	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 796	1.73	175	706.9
23	EA-23	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 812	1.76	175	505.8
24	EA-24	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 836	1.79	175	150.9
25	EA-25	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 852	1.82	175	357.1
26	EA-26	C₂-乙基桥键单金刚烷	C₁₄H₂₂	2 908	1.91	175	156.3
27	EA-27	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 684	1.45	189	493.2
28	EA-28	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 716	1.46	189	345.8
29	EA-29	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 724	1.41	189	1 261.2
30	EA-30	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 732	1.5	189	141.2
31	EA-31	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 764	1.47	189	931.0
32	EA-32	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 804	1.51	189	388.9
33	EA-33	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 828	1.61	189	188.8
34	EA-34	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 844	1.56	189	763.4
35	EA-35	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 852	1.59	189	1 069.3
36	EA-36	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 860	1.59	189	277.5
37	EA-37	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 868	1.56	189	457.6
38	EA-38	C₃-乙基桥键单金刚烷	C₁₅H₂₄	2 884	1.65	189	271.9
39	EA-39	C₄-乙基桥键单金刚烷	C₁₆H₂₆	2 740	1.26	203	211.5
40	EA-40	C₄-乙基桥键单金刚烷	C₁₆H₂₆	2 764	1.29	203	634.2
41	EA-41	C₄-乙基桥键单金刚烷	C₁₆H₂₆	2 828	1.43	203	51.2
42	EA-42	C₄-乙基桥键单金刚烷	C₁₆H₂₆	2 852	1.46	203	439.4
43	EA-43	C₄-乙基桥键单金刚烷	C₁₆H₂₆	2 860	1.47	203	194.8
44	EA-44	C₄-乙基桥键单金刚烷	C₁₆H₂₆	2 892	1.44	203	222.7
45	EA-45	C₄-乙基桥键单金刚烷	C₁₆H₂₆	2 964	1.52	203	427.8
46	EA-46	C₅-乙基桥键单金刚烷	C₁₇H₂₈	2 860	1.17	217	75.9
47	EA-47	C₅-乙基桥键单金刚烷	C₁₇H₂₈	2 916	1.2	217	13.2
48	ED-1	乙基桥键双金刚烷	C₁₆H₂₂	3 452	2.53	214	260.5
49	ED-2	乙基桥键双金刚烷	C₁₆H₂₂	3 540	2.62	214	52.6
50	ED-3	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 468	2.27	213	103.9
51	ED-4	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 476	2.25	213	197.4
52	ED-5	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 500	2.32	213	322.6
53	ED-6	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 532	2.41	213	129.3
54	ED-7	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 556	2.45	213	115.1
55	ED-8	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 564	2.32	213	85.9
56	ED-9	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 604	2.49	213	41.8
57	ED-10	C1-乙基桥键双金刚烷	C₁₇H₂₄	3 620	2.6	213	72.5
58	ED-11	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 636	2.57	213	33.2
59	ED-12	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 652	2.57	213	101.8
60	ED-13	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 676	2.54	213	29.5
61	ED-14	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 684	2.65	213	53.1
62	ED-15	C₁-乙基桥键双金刚烷	C₁₇H₂₄	3 692	2.6	213	27.1
63	ED-16	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 772	2.38	213	49.4
64	ED-17	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 780	2.43	213	57.5
65	ED-18	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 476	1.95	227	312.9
66	ED-19	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 524	2.06	227	125.6
67	ED-20	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 548	2.14	227	148.7
68	ED-21	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 564	2.19	227	165.8
69	ED-22	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 596	2.21	227	111.2
70	ED-23	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 628	2.21	227	97.2
71	ED-24	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 652	2.26	227	303.7
72	ED-25	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 700	2.38	227	149.4
73	ED-26	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 724	2.45	227	119.5
74	ED-27	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 756	2.41	227	128.5
75	ED-28	C₂-乙基桥键双金刚烷	C₁₈H₂₆	3 788	2.51	227	311.7
76	ED-29	C₃-乙基桥键双金刚烷	C₁₉H₂₈	3 492	1.75	241	272.4
77	ED-30	C₃-乙基桥键双金刚烷	C₁₉H₂₈	3 572	1.88	241	59.8
78	ED-31	C₃-乙基桥键双金刚烷	C₁₉H₂₈	3 748	2.21	241	249.4
79	ED-32	C₃-乙基桥键双金刚烷	C₁₉H₂₈	3 796	2.21	241	126.3
80	ET-1	乙基桥键三金刚烷	C₂₀H₂₆	4 276	3.3	266	11.4
81	ET-2	C₁-乙基桥键三金刚烷	C₂₁H₂₈	4 348	3.15	265	5.5

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