苏北盆地溱潼凹陷古近系阜宁组二段页岩油基本特征及成因分析

昝灵; 白鸾羲; 印燕铃; 张琬璐

doi:10.11781/sysydz202302356

苏北盆地溱潼凹陷古近系阜宁组二段页岩油基本特征及成因分析

doi: 10.11781/sysydz202302356

中国石化华东油气分公司, 南京 210019

基金项目:

中国石化科技部项目 P20049-3

中国石化科技部项目 P21112

详细信息

作者简介:
昝灵(1984-), 男, 博士, 研究员, 从事页岩油地质研究。E-mail: zanl.hdsj@sinopec.com

中图分类号: TE122.116
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出版历程
- 收稿日期: 2022-03-11
- 修回日期: 2023-03-01
- 刊出日期: 2023-03-28

Basic characteristics and genesis analysis of shale oil in the second member of Paleogene Funing Formation in Qintong Sag, Subei Basin

East China Oil and Gas Company, SINOPEC, Nanjing, Jiangsu 210019, China

摘要

摘要: 苏北盆地溱潼凹陷古近系阜宁组二段陆相页岩油具有高产、稳产特征，在剖析页岩油形成条件的基础上，通过原油物性和地化特征分析，揭示了阜二段页岩油的成因。溱潼凹陷阜二段泥页岩分布广、厚度大，有机质丰度和热演化程度适中，具备形成页岩油的良好物质基础。阜二段页岩油具有低气油比、高异常压力特征，为低含硫轻质—中质油，饱和烃和轻烃含量较高，原油伴生气以甲烷为主。页岩油β-胡萝卜烷、伽马蜡烷含量高，ααα-C₂₉甾烷（20R）含量高于ααα-C₂₇甾烷（20R），形成于咸水的还原环境。热演化程度是控制陆相页岩油品质的关键因素，深凹带阜二段处于生烃高峰，页岩油流动性较好。阜二段Ⅰ、Ⅱ亚段泥页岩普遍含有木栓质体（6.6%）和底栖藻无定型体（11.5%），在成熟阶段既生油又生气，有利于形成轻质组分。阜二段泥页岩具有相对适中的有机质丰度和矿物组成，吸附油能力较弱，滞留油以游离油（69%~96%）为主。
- 热演化程度 /
- 有机质类型 /
- 有机质丰度 /
- 页岩油 /
- 阜宁组二段 /
- 古近系 /
- 溱潼凹陷 /
- 苏北盆地
Abstract: The continental shale oil in the second member of Paleogene Funing Formation in the Qintong Sag, Subei Basin has the characteristics of high and stable production. Based on the analysis of the formation conditions of shale oil, the genesis of shale oil is revealed according to crude oil geochemical characteristics and physical properties. Results show that the mud shale in the second member of Funing Formation in the Qintong Sag is widely distributed and thick, with medium organic matter abundance and moderate thermal evolution, which provides a good material basis for the formation of shale oil. The shale oil in the second member of Funing Formation has the characteristics of low gas/oil ratio and high pressure, which belongs to low sulfur and light to medium oil, with high content of saturated hydrocarbon and light hydrocarbon, and the associated gas of crude oil is mainly methane. The shale oil has high content of β-daucane and gammacerane, and its sterane content of ααα-C₂₉ (20R) is higher than that of ααα-C₂₇ (20R), indicating that it is formed in the reduction environment of salt water. Thermal evolution is the key factor controlling the quality of continental shale oil. The second member of Funing Formation in the deep sag zone is at the peak of hydrocarbon generation, and the shale oil has good fluidity. The mud shale in the Ⅰ and Ⅱ submembers of the second member of Funing Formation generally contains suberinite (6.6%) and amorphous body of benthic algal (11.5%), and can generate oil and gas at the mature stage, which is conducive to the formation of light components. The mud shale in the second member of Funing Formation has the characteristics of moderate organic matter abundance and mineral composition, and its oil adsorption capacity is poor, making the remaining oil mainly free oil (69%-96%).
- thermal evolution /
- organic matter type /
- organic matter abundance /
- shale oil /
- the second member of Funing Formation /
- Qintong Sag /
- Subei Basin /

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图 1 苏北盆地溱潼凹陷阜宁组二段暗色泥岩(有机碳含量大于0.5%)厚度分布

Figure 1. Thickness of dark mudstone (TOC>0.5%) in the second member of Funing Formation in Qintong Sag, Subei Basin

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图 2 苏北盆地溱潼凹陷阜宁组二段泥页岩综合柱状图

Figure 2. Composite columnar section of mud shale in the second member of Funing Formation in Qintong Sag, Subei Basin

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图 3 苏北盆地溱潼凹陷阜宁组二段泥页岩有机质类型划分

Figure 3. Classification of organic matter types of mud shale in the second member of Funing Formation in Qintong Sag, Subei Basin

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图 4 苏北盆地溱潼凹陷阜宁组二段泥页岩R_o随埋深变化趋势

Figure 4. Variation trend of mud shale R_o with buried depth in the second member of Funing Formation in Qintong Sag, Subei Basin

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图 5 苏北盆地溱潼凹陷阜宁组二段页岩油和泥页岩生物标志化合物对比

Figure 5. Comparison of biomarkers between shale oil and mud shale in the second member of Funing Formation in Qintong Sag, Subei Basin

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图 6 苏北盆地溱潼凹陷阜宁组二段页岩油和泥页岩生标指纹对比

T1.13β(H), 14α(H)-C₁₉三环萜烷；T2.13β(H), 14α(H)-C₂₀三环萜烷；T3.13β(H), 14α(H)-C₂₁三环萜烷；T4.13β(H), 14α(H)-C₂₂三环萜烷；T5.13β(H), 14α(H)-C₂₃三环萜烷；T6.13β(H), 14α(H)-C₂₄三环萜烷；T7.C₂₄-四环萜烷；T8.13β(H), 14α(H)-C₂₆三环萜烷(R)；T9.13β(H), 14α(H)-C₂₆-三环萜烷(S)；T10.13β(H), 14α(H)-C₂₈三环萜烷(R)；T11.13β(H), 14α(H)-C₂₈三环萜烷(S)；T12.13β(H), 14α(H)-C₂₉三环萜烷(R)；T13.13β(H), 14α(H)-C₂₉三环萜烷(S)；S1.C₂₁-5α(H)-孕甾烷；S2.C₂₂-5α(H)-升孕甾烷；S3.5α(H), 14α(H), 17α(H)-胆甾烷(20S)；S4.5α(H), 14β(H), 17β(H)-胆甾烷(20R)；S5.5α(H), 14β(H), 17β(H)-胆甾烷(20S)；S6.5α(H), 14α(H), 17α(H)-胆甾烷(20R)；S7.24-甲基-5α(H), 14α(H), 17α(H)-胆甾烷(20S)；S8.24-甲基-5α(H), 14β(H), 17β(H)-胆甾烷(20R)；S9.24-甲基-5α(H), 14β(H), 17β(H)-胆甾烷(20S)；S10.24-甲基-5α(H), 14α(H), 17α(H)-胆甾烷(20R)；S11.24-乙基-5α(H), 14α(H), 17α(H)-胆甾烷(20S)；S12.24-乙基-5α(H), 14β(H), 17β(H)-胆甾烷(20R)；S13.24-乙基-5α(H), 14β(H), 17β(H)-胆甾烷(20S)

Figure 6. Comparison of biological standard fingerprints between shale oil and mud shale in the second member of Funing Formation in Qintong Sag, Subei Basin

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图 7 苏北盆地溱潼凹陷阜宁组二段含油饱和度指数(OSI)、氯仿沥青“A”随深度变化关系

Figure 7. Variation of oil saturation index (OSI) and chloroform bitumen "A" with depth in the second member of Funing Formation in Qintong Sag, Subei Basin

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图 8 苏北盆地溱潼凹陷阜宁组二段泥页岩有机显微组分

Figure 8. Organic macerals of mud shale in the second member of Funing Formation in Qintong Sag, Subei Basin

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图 9 苏北盆地溱潼凹陷深凹带阜宁组二段泥页岩生烃转化率对比

Figure 9. Comparison of hydrocarbon generation conversion rate of mud shale in the second member of Funing Formation in deep sag zone of Qintong Sag, Subei Basin

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图 10 苏北盆地溱潼凹陷阜宁组二段泥页岩有机质丰度、矿物组成与含油性关系

Figure 10. Relationship between organic matter abundance, mineral components and oil content of mud shale in the second member of Funing Formation in Qintong Sag, Subei Basin

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图 11 苏北盆地溱潼凹陷阜宁组二段游离油和束缚油随深度变化趋势

S_1-1为游离轻质油；S_1-2为游离中质油；S_2-1为吸附油

Figure 11. Variation trend of free oil and bound oil with depth in the second member of Funing Formation in Qintong Sag, Subei Basin

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表 1 苏北盆地溱潼凹陷阜宁组二段页岩油物性特征

Table 1. Physical properties of shale oil in the second member of Funing Formation in Qintong Sag, Subei Basin

井号	埋深/m	密度/(g·cm^-3)	动力黏度(50 ℃)/(mPa·s)	含硫/%
SY3-7HF	3 636~3 815	$\frac{0.868\;1 \sim 0.888\;3}{0.878\;1}$	$\frac{31.54 \sim 292.14}{108.15}$	$\frac{0.17 \sim 0.35}{0.25}$
SD1	3 826~3 952	$\frac{0.879\;1 \sim 0.898\;7}{0.888\;1}$	$\frac{40.04 \sim 118.37}{67.18}$	$\frac{0.16 \sim 0.51}{0.34}$
QY1	4 015~4 165	$\frac{0.838\;1 \sim 0.870\;0}{0.850\;0}$	$\frac{11.45 \sim 26.64}{16.98}$	$\frac{0.08 \sim 0.26}{0.14}$
注：表中分式意义为$\frac{ { 最小值 \sim 最大值 }}{ { 平均值 }}$。

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表 2 苏北盆地溱潼凹陷阜宁组二段有机显微组分分布

Table 2. Distribution of organic macerals in the second member of Funing Formation in Qintong Sag, Subei Basin

层位	腐泥组/%	壳质组/%	镜质组/%	惰质组/%	类型指数	干酪根类型
Ⅴ亚段	12.2	74.2	11.9	1.7	38.7	Ⅱ₂型
Ⅳ亚段	38.6	53.5	6.9	1.0	59.2	Ⅱ₁型
Ⅲ亚段	23.4	63.4	10.8	2.4	44.6	Ⅱ₁型
Ⅱ亚段	14.4	64.0	17.1	4.5	29.1	Ⅱ₂型
Ⅰ亚段	7.6	66.6	22.1	3.7	20.6	Ⅱ₂型

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