LIU Quanyou, LIU Wenhui, QIN Shengfei, WANG Wanchun, GAO Bo. GAS-GENERATING CHARACTERISTICS OF COAL ROCK AND ITS MARCERAL IN THERMAL SIMULATION[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2002, 24(2): 147-151. doi: 10.11781/sysydz200202147
Citation: LIU Quanyou, LIU Wenhui, QIN Shengfei, WANG Wanchun, GAO Bo. GAS-GENERATING CHARACTERISTICS OF COAL ROCK AND ITS MARCERAL IN THERMAL SIMULATION[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2002, 24(2): 147-151. doi: 10.11781/sysydz200202147

GAS-GENERATING CHARACTERISTICS OF COAL ROCK AND ITS MARCERAL IN THERMAL SIMULATION

doi: 10.11781/sysydz200202147
  • Received Date: 2001-01-02
  • Rev Recd Date: 2002-03-05
  • Publish Date: 2002-03-25
  • The coal rock and its marceral six series of samples were conducted a thermal simulation experiment.The temperature was programmed from 250 to 550℃ with a temperature step of 50℃.The gas products were analyzed systematically.The results show that the gas production rate is increasing with temperature for the coal rock and its marceral,is varied at the same temperature for different simulated material,and is different under various temperature for the same simulated material.It is also revealed that the vitrinite and exinite have stronger gas potential,the gas production of the fusinite and semifusinite is very low,and the bulk coal samples display the synthetic hydrocarbon-generating effects of each marceral.CO2 and N2 make up larger percentage in the gas products mainly within low temperature bands.

     

  • loading
  • [1]
    Vassayevich N B,et al.The role of clays in oil formation[J].Internet Geology Rev,1976,118(2):125-134.
    [2]
    Alomon W R,Johns W D.Petroleum forming reactions:the mechanism and rate of clay catalyzed fatty acid decarboxiolation[J].Advance of Organic Geochemistry,1975:157-170.
    [3]
    Behar F,Vandenbroucke M,Tang Y,et al.Thermal cracking of kerogen in open and closed systems:determination of kinetic parameters and stoichiometric coefficient for oil and gas generation[J].Org Geochemistry,1997,126(5/6):321-339.
    [4]
    Orem W H,Neazil S G,Lerch H E,et al.Experimental early-stage coalification of a peat sample and a peatified wood sample from Indonesia[J].Org Geochemistry,1996,124(2):111-125.
    [5]
    石卫,郭绍辉,秦匡宗.烃源岩在水介质下热压模拟的研究[A].第五届全国有机地球化学会议论文集[C].南京:江苏科学出版社,1994.238.
    [6]
    姜峰,杜建国,王万春,等.高温超高压模拟实验研究:(Ⅰ)温压条件对有机质成熟作用的影响[J].沉积学报,1998,16(3):153-155.
    [7]
    孟祥吉,李术元,郭绍辉.水介质热压模拟法研究干酪根的催化生烃特征[A].第五届全国有机地球化学会议论文集[C].南京:江苏科学出版社,1994.169.
    [8]
    张枝焕.粘土矿物对干酪根热解生烃过程的影响[J].石油勘探与开发,1994,21(5):29-37.
    [9]
    Khorasani G K,Michelsen J K.Geological and laboratory evidence for early generation of large amount of liquid hydrocarbons from suberinite and subereous components[J].Org Geochemi-stry,1991,17(6):849-863.
    [10]
    刘全有,刘文汇,秦胜飞,等.煤岩及煤岩加不同介质的热模拟地球化学实验—气态和液态产物的产率以及演化特征[J].沉积学报,2001,19(3):465-468.
    [11]
    杨天宇,王涵云.褐煤干酪根煤化作用成气的模拟实验及其地质意义[J].石油勘探与开发,1983,10(6):30-36.
    [12]
    李杰生.褐煤煤化作用的加压加热模拟实验及其意义[J].石油实验地质,1988,10(1):72-78.
    [13]
    李丽.褐煤煤化作用的模拟实验[J].石油与天然气地质,1985,6(2):121-126.
    [14]
    秦建中,贾蓉芬,郭爱明,等.华北地区煤系烃源层油气生成、运移、评价[M].北京:科学出版社,2000.38-95.
    [15]
    傅家谟,刘德汉,盛国英.煤成烃地球化学[M].北京:科学出版社,1992.46-47.
    [16]
    Seewald J S,Benitez-Netson B C,Whelan J K.Laboratory and theoretical constraints on the generation and composition of natural gas[J].Geochimica et Cosmochimica Acta,1998,62(9):1 599-1 617.
    [17]
    Tannenbaum E,Kaplan I R.Low-mature hydrocarbons genera-ted during hydrous and dry pyrolysis of kerogen[J].Nature,1985:708-709.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (816) PDF downloads(537) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return