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Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2005  >  27(3): 288-292
Ma Anlai, Zhang Shuichang, Zhang Dajiang, Jin Zhijun, Chen Zhilin. RUTHENIUM-IONS-CATALYZED OXIDATION OF AN ASPHALTENE OF A BIODGRADED OIL FROM CAOQIAO OIILFIELD, DONGYING DEPRESSION, BOHAIWAN BASIN-THE DISTRIBUTION OF BIOMARKERS AND THE GEOLOGICAL SIGNIFICANCE[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2005, 27(3): 288-292. doi: 10.11781/sysydz200503288
Citation: Ma Anlai, Zhang Shuichang, Zhang Dajiang, Jin Zhijun, Chen Zhilin. RUTHENIUM-IONS-CATALYZED OXIDATION OF AN ASPHALTENE OF A BIODGRADED OIL FROM CAOQIAO OIILFIELD, DONGYING DEPRESSION, BOHAIWAN BASIN-THE DISTRIBUTION OF BIOMARKERS AND THE GEOLOGICAL SIGNIFICANCE[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2005, 27(3): 288-292. doi: 10.11781/sysydz200503288
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RUTHENIUM-IONS-CATALYZED OXIDATION OF AN ASPHALTENE OF A BIODGRADED OIL FROM CAOQIAO OIILFIELD, DONGYING DEPRESSION, BOHAIWAN BASIN-THE DISTRIBUTION OF BIOMARKERS AND THE GEOLOGICAL SIGNIFICANCE

doi: 10.11781/sysydz200503288
  • 1.

    Research Institute of Petroleum Exploration and Production, SINOPEC, Beijing 100083, China

  • 2. China University of Petroleum, Beijing 102200, China

  • 3. Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China

  • 4. Research Institute of Geological Sciences, Shengli Oilfield, SINOPEC, Dongying, Shandong 257015, China

  • Received Date: 2004-02-27
  • Rev Recd Date: 2005-04-27
  • Publish Date: 2005-05-25
    Abstract
  • The asphaltene of a biodegraded oil from Caoqiao oilfield,Dongying depression,Bohaiwan Basin has been investigated by ruthenium-ions-catalyzed oxidation technique (RICO).The products of asphaltene RICO included n-alkanoic acids,dialkanoic acids,tricyclic terpernoid acids,hopanoic acids,gammacerane carboxylic acids,pregnanoic acids,sterane carboxylic acids and so on.The biomarkers were bounded on the asphaltene with specific carbon position respectively.The high ratios of gammacerane carboxylic acids to C30 hopanoic carboxylic acids and a complete series of 4-methyl,4,4-dimethyl steranoic acids indicated that the oil is a mixing oil originated from Es4 and Es3 source rock.The low isomerization of the biomarker acids showed that the maturity of the oil is low.Ruthenium-ions-catalyzed oxidation of the asphaltene provided a new pathway for the oil-oil correlation and oil-source correlation of heavily biodegraded oil.

     

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    • References(11)
  • [1]
    Djerassi C,Engle R R.Oxidations with ruthenium tetroxide[J].Journal of American Chemical Society,1953,75(5):3838～3840
    [2]
    Carlson P H J,Kalsuhi T,Martin V S,et al.A greatly improved procedure for ruthenium tetraoxide catalyzed oxidations of organic compound[J].Journal of Organic Chemistry,1981,46(19):3936～3938
    [3]
    Mojelsky T W,Ignasiak M,Frakman Z,et al.Structural features of Alberta oil sand bitumen and heavy oil asphaltenes[J].Energy and Fuel,1992,6(1):83～964 Strausz O P,Mojelsky T W,Lown E M.Structural features of Boscan and Duri Asphaltene[J].Energy and Fuel,1999,13(2):228～247
    [4]
    Strsusz O P,Mojelsky T W,Farhad F,et al.Additional structural details on Athabasca asphaltene and their ramifications[J].Energy and Fuel,1999,13(2):207～227
    [5]
    Peng P,Fu J,Sheng G,et al.Ruthenium-iron-catalyzed oxidation of an immature asphaltene:Structural features and biomarker distribution[J].Energy and Fuel,1999,13(2):266～277
    [6]
    熊永强,耿安松,王春江等.实验温度对沥青质热解的影响[J].石油实验地质,2000,22(1):85～89
    [7]
    廖泽文,耿安松.沥青质轻度化学降解产物中正庚烷可溶组分的特征[J].石油实验地质,2003,25(1):45～52
    [8]
    徐冠军,张大江,王培荣.用沥青质中生物标志化合物判识生物降解油的油源[J].科学通报,2003,48(4):400～404
    [9]
    马安来,张水昌,张大江等.盆地原油沥青质钌离子催化氧化及油源[J].石油勘探与开发,2004,31(3):54～58
    [10]
    王子军.减压渣油的钌离子催化氧化:[博士论文].东营:中国石油大学(东营),1996
    [11]
    朱军.石油沥青质化学组成与结构特征的研究:[博士论文].北京:中国石油大学(北京),2002
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