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Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2005  >  27(6): 606-611
Li Meijun, Wang Tieguan. THE GENERATING MECHANISM OF METHYLATED NAPHTHALENE SERIES IN CRUDE OILS AND THE APPLICATION OF THEIR MATURITY PARAMETERS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2005, 27(6): 606-611. doi: 10.11781/sysydz200506606
Citation: Li Meijun, Wang Tieguan. THE GENERATING MECHANISM OF METHYLATED NAPHTHALENE SERIES IN CRUDE OILS AND THE APPLICATION OF THEIR MATURITY PARAMETERS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2005, 27(6): 606-611. doi: 10.11781/sysydz200506606
shu

THE GENERATING MECHANISM OF METHYLATED NAPHTHALENE SERIES IN CRUDE OILS AND THE APPLICATION OF THEIR MATURITY PARAMETERS

doi: 10.11781/sysydz200506606
  • 1.

    Key Laboratory for Hydrocarbon Accumulation Mechanism, Ministry of Education, China University of Petroleum, Beijing 102249, China

  • 2. Geochemical Laboratory of Resources and Information School, China University of Petroleum, Beijing 102249, China

  • Received Date: 2005-01-29
  • Rev Recd Date: 2005-09-10
  • Publish Date: 2005-11-25
    Abstract
  • Naphthalene and methylated naphthalene series in crude oils and sedimentary organic matters are formed through isomerization and disproportionation,which can be interpreted by aromatic electrophilic substitution process.The relative concentrations of various isomers are controlled by "electronic effect" and "steric effect".Geochemical parameters related to methylated naphthalenes can be used to indicate the differences of maturity,biodegradation,and source input between oil and sedimentary organic matters.Oil samples selected from Damintun Depression in Bohai Bay Basin have been analyzed for methylated naphthalene series.The results show that the high waxy oils are more thermally mature than normal oils,even though some saturated hydrocarbon composition such as steranes and terpanes isomeric ratios get to equilibrium end.This conclusion is consistent with the geological background and the basin modeling results in the study area.It is proved that these methylated naphthalene parameters are very useful geochemical indicators.

     

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    • References(25)
  • [1]
    Tissot B P,Welte D H.Petroleum formation and occurrence [M].New York:Springer-Verlag,1984
    [2]
    Puttmann W,Villar H.Occurrence and geochemical significance of 1,2,5,6-tetramethylnaphthalene[J].Geochimica et Cosmochimica Acta,1982,46:1～10
    [3]
    Strachan M G,Alexander R,Kagi R I.Trimethylnaphthalenes in crude oils and sediments:effects of source and maturity [J].Geochimica et Cosmochimica Acta,1988,52:1 255～1 264
    [4]
    陈致林,李素娟,王忠.低-中成熟演化阶段芳烃成熟度指标的研究[J].沉积学报,1997,15(2):193～197
    [5]
    黄海平,杨杰,Larter S R.生物降解作用对储层抽提物中多甲基萘分布的影响[J].地球科学,2003,28(3):281～288
    [6]
    王振平,曲佳燕,卢双舫.原油中萘菲化合物的分布与油藏聚集途径[J].大庆石油学院学报,2002,26(3):5～8
    [7]
    Radke M,Willsch H,Welte D H.Methylated dicyclic and tricyclic aromatic hydrocarbons in crude oils from the Handil field,Indonesia [J].Organic Geochemistry,1990,15:17～34
    [8]
    Radke M,Rullkotter J,Vriend S P.Distribution of naphthalenes in crude oils from the Java Sea:source and maturation effects[J].Geochimica et Cosmochimica Acta,1994,52:1 255～1 264
    [9]
    van Aaressen B G K,Hessels J K C,Abbink O A,et al.The occurrence of polycyclic sesqui-,tri-and oligoterpenoids derived from a resinouse polymeric cadinene in crude oils form South East Asia[J].Geochimica et Cosmochimica Acta,1992,56:1 231～1 246
    [10]
    Ellis L,Singh R K,Akecabser,et al.Formation of isohexyl alkyaromatic hydrocarbons form aromatization-rearrangement of terpenoids in the sedimentary environment:a new class of biomarker [J].Geochimica et Cosmochimica Acta,1996,60:4 747～4 763
    [11]
    Killops S D.Novel aromatic hydrocarbons of probable bacteria origin in a Jurassic lacustrine sequence [J].Organic geochemistry,1991,17:25～36
    [12]
    Alexander R,Bastow T P,Fisher S J,et al.Tetramethylnaphthalenes in crude oils[J].Journal of Polycyclic Aromatic Compounds,1993,3:629～634
    [13]
    Bastow T P,Alexander R,Sosrowidjojo I B,et al.Pentamethylnaphalenes and ralted compounds in sedimentary organic matter[J].Organic geochemistry,1998,28:585～596
    [14]
    Radke M,Welte D H,Willsch H.Geochimical study on a well in the Western Canada Basin:relation of the aromatic ditribution pattern to maturity of organic matter [J].Geochimica et Cosmochimica Acta,1982,46:1～10
    [15]
    Alexander R,Kagi R I,Rowland S J,et al.The effects of thermal maturity on distribution of dimethylnaphthalenes and trimethylnaphthalenes in some Ancient sediments and petroleums [J].Geochimica et Cosmochimica Acta,1985,49:385～395
    [16]
    van Aarssen B G K,Bastow T P,Alexander R,et al.Distributions of methylated naphthalenes in crude oils:indicators of maturity,biodegradation and mixing[J].Organic Geochemistry,1999,30:1 213～1 227
    [17]
    Bastow T P,Alexander R,Fisher S J,et al.Geosynthesis of organic compounds.PartⅤ-mehylation of alkylnaphthalenes[J].Organic Geochemistry,2000,31:523～534
    [18]
    黄志桂,吴兆荧,吴增元等.有机化学[M].重庆:西南师范大学出版社,1990
    [19]
    Huang Y S,Geng A S,Fu J M,et al.The investigation of characteristics of biomarker assemblages and their precursors in Damintun ultra-high wax oils and related source rocks[J].Organic Geochemistry,1992,19:29～39
    [20]
    郑容植,王贵珍.大民屯凹陷高凝油低凝油特征及其油气分布规律[J].石油实验地质,1988,10(3):256～267
    [21]
    黄海平,李虹,马刊创等.大民屯凹陷高蜡油的形成条件[J].石油与天然气地质,2001,22(1):64～71
    [22]
    黄海平.大民屯凹陷烃源岩中高分子量烃的形成与分布特征[J].石油实验地质,2000,22(4):297～301,318
    [23]
    谢文彦,张占文,姜建群等.辽河盆地大民屯凹陷油气性质及成因机制研究[J].石油实验地质,2004,26(3):292～297
    [24]
    李美俊.大民屯凹陷层序地层地球化学及油气成藏特征:[学位论文].北京:中国地质大学,2003
    [25]
    Huang H,Later S R,Love G D.Analysis of wax hydrocarbons in petroleum source rocks from the Damintun Depression,eastern China,using high temperature gas chromatography [J].Organic Geochemistry,2003,34(12):1 673～1 687
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