Advanced Search
Volume 32 Issue 4
. 
Turn off MathJax
Article Contents
Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2010  >  32(4): 400-404
Zhang Jianyong, Liu Wenhui, Ten ger, Fan Ming, Zheng Lunju, Wang Xiaofang, Liu Jinzhong. MATERIAL SELECTION OF TSR SIMULATION EXPERIMENT INSTRUMENTS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2010, 32(4): 400-404. doi: 10.11781/sysydz201004400
Citation: Zhang Jianyong, Liu Wenhui, Ten ger, Fan Ming, Zheng Lunju, Wang Xiaofang, Liu Jinzhong. MATERIAL SELECTION OF TSR SIMULATION EXPERIMENT INSTRUMENTS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2010, 32(4): 400-404. doi: 10.11781/sysydz201004400
shu

MATERIAL SELECTION OF TSR SIMULATION EXPERIMENT INSTRUMENTS

doi: 10.11781/sysydz201004400
  • 1.

    Hangzhou Research Institute of Petroleum Geology, Hangzhou, Zhejiang 310023, China

  • 2. Lanzhou Institute of Geology, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China

  • 3. SINOPEC Exploration & Production Research Institute, Beijing 100083, China

  • 4

  • Received Date: 2010-03-10
  • Rev Recd Date: 2010-06-08
  • Publish Date: 2010-08-28
    Abstract
  • Thermochemical sulfate reduction(TSR) is the major mechanism of gas reservoirs with high content of sulfureted hydrogen.The complexity of TSR mechanism demands further research which needs comprehensive simulation experiment,but different simulation experiments with different instruments lead to great diversity.In order to investigate the influence of instrument material on experimental results,a series of contrast experiments have been done.With the experiments,the followings are confirmed: ①The metal in high temperature and pressure kettle reacts with sulfur to generate metallic sulfide,so composition metal kettle is not suitable to be used as an instrument for TSR simulation experiment;②In high temperature and pressure conditions,quartz reacts with sulfate to generate silicate,so quartz tube can not be used for TSR simulation experiment;③Gold does not react with the reactant,intermediate reaction product or final reaction product,for the limited bulk volume of golden cube,the hydrocarbon product is not enough for testing light hydrocarbon,but it's enough for testing gaseous hydrocarbon components and carbon isotopes,so it is the best option to use golden cube for such kind of simulation experiment.

     

    • FullText(HTML)
  • loading
    • References(41)
  • [1]
    朱光有,张水昌,李剑,等.中国高含硫化氢天然气的形成及其分布[J].石油勘探与开发,2004,31(3):18-21.
    [2]
    ORR W L.Changes in sulfur content and isotopic ratios of sulfur during petroleum maturation-Study of Big Horn Basin Paleozoic oil[J].AAPG Bulletin,1974,58(11):2295-2318.
    [3]
    张子枢.四川碳酸盐岩气田的硫化氢[J].石油实验地质,1983,5(4):304-307.
    [4]
    KROUSE H R,CHRISTIAN A V,LESLIE S E,et al.Chemical and isotopic evidence of thermochemical sulphate reduction by light hydrocarbon gases in deep carbonate reservoirs[J].Nature,1988,333(2):415-419.
    [5]
    EZAT H,CLYDE H M.Burial diagenesis and thermochemical sulfate reduction Smackover Formation,southeastern Mississippi salt basin[J].Geology,1989,17(12):1080-1084.
    [6]
    WORDEN R H,SMALLEY P C,OXTOBY N H.The effects of thermochemical sulfate reduction upon formation water salinity and oxygen isotopes in carbonate gas reservoir[J].Geochimica et Cosmochimica Acta,1996,60(20):3925-3931.
    [7]
    MANZANO B K,FOWLER M G,MACHEL H G.The influence of thermochmical sulphate reduction on hydrocarbon composition in Nisku reservoirs,Brazeau river area,Alberata,Canada[J].Org Geochem,1997,27(7-8):507-521.
    [8]
    EZAT H.The Role of Burial Diagenesis in Hydrocarbon Destruction and H2S Accumulation,Upper Jurassic Smackover Formation,Black Creek Field,Mississippi[J].AAPG Bulletin,1997,81(1):26-45.
    [9]
    WILSON L O.Changes in sulfur content and isotopic ratios of sulfur during petroleum maturation-Study of Big Horn Basin Paleozoic oils[J].AAPG bulletin,1974,58(11):2295-2318.
    [10]
    戴金星.中国含硫化氢的天然气分布特征、分类及其成因探讨[J].沉积学报,1985,3(4):109-117.
    [11]
    WORDEN R H,SMALLEY P C.H2S producing reactions in deep carbonate gas reservoirs:Khuff Formation,Abu Dhabi[J].Chemical Geology,1996,133(1-4):157-171.
    [12]
    王一刚,窦立荣,文应初,等.四川盆地东北部三叠系飞仙关组高含硫气藏H2S成因研究[J].地球化学,2002,31(6):517-524.
    [13]
    CAI CHUNFANG,RICHARD H W,SIMON H B,et al.Thermochemical sulphate reduction and the generation of hydrogen sulphide and thiols(mercaptans)in Triassic carbonate reservoirs from the Sichuan Basin,China[J].Che mical Geology,2003,202(1-2):39-57.
    [14]
    马永生,傅强,郭彤楼,等.川东北地区普光气田长兴—飞仙关气藏成藏模式与成藏过程[J].石油实验地质,2005,27(5):455-461.
    [15]
    WORDEN R H,CAI CHUNFANG.Geochemical characteristics of the Zhaolanzhuang sour gas accumulation and thermochemical sulfate reduction in the Jixian Sag of Bohai Bay Basin by Zhang et al.(Organic Geochemistry 36,1717-1730)[J].Organic Geochemistry,2006,37(4):511-514.
    [16]
    张水昌,朱光有,梁英波.四川盆地普光大型气田H2S及优质储层形成机理探讨:读马永生教授的"四川盆地普光大型气田的发现与勘探启示"有感[J].地质论评,2006,52(2):230-234.
    [17]
    WORDEN R H,SMALLEY P C,OXTOBY N H.Gas Souring by Thermochemical Sulfate Reduction at 140°C[J].AAPG Bulletin,1995,79(6):854-863.
    [18]
    WORDEN R H,SMALLEY P C,CROSS M M.The influence of rock fabric and mineralogy on the thermochemical sulfate reduction:Khuff Formation,Anudhabi[J].Journal of Sedimentary Research,2000,70(5):1210-1221.
    [19]
    YANG CHAO,HUTCHEON I,KROUSE H R.Fluid inclusion and stable isotopic studies of thermochemical sulphate reduction from Burnt Timber and Crossfield East gas fields in Alberta,Canada[J].Bulletin of Canadian Petroleum Geology,2001,49(1):149-164.
    [20]
    BILDSTEIN O,WORDEN R H,BROSSE E.Assessment of anhydrite dissolution as the rate-limiting step during thermochemical sulfate reduction[J].Chemical Geology,2001,176(1-4):173-189.
    [21]
    刘德汉,肖贤明,熊永强,等.四川东部飞仙关组鲕滩气藏储层含自然硫不混溶包裹体及硫化氢成因研究[J].中国科学D辑,2006,36(6):520-532.
    [22]
    ORR W L.Geologic and geochemical controls on the distribution of hydrogen sulfide in natural gas[C]/ CAMPO R,GONI J,eds.Advances in Organic Geochemistry.Madrid:Enadimsa,1977:571-595.
    [23]
    GOLDHABER M B,ORR W L.Kinetic controls on thermochemical sulfate reduction as a source of sedimentary H2S[J].American Chemical Society Symposium Series,1995,612:412-425.
    [24]
    沈平,徐永昌,王晋江,等.天然气中硫化氢硫同位素组成及沉积地球化学相[J].沉积学报,1997,15(2):216-219.
    [25]
    MACHEL H G.Bacterial and thermochemical sulfate reduction in diagenetic settings:old and new insights[J].Sedimentary Geology,2001,140(1-2):143-175.
    [26]
    CAI CHUNFANG,XIE ZENGYE,WORDEN R H,et al.Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin,China:towards prediction of fatal H2S concentrations[J].Marine and Petroleum Geology,2004,21(10):1265-1279.
    [27]
    MARTIN M C,DAVID A C,SIMON H B,et al.Thermochemical sulphate reduction(TSR):experimental determination of reaction kinetics and implications of the observed reaction rates for petroleum reservoirs[J].Organic Geochemistry,2004,35(4):393-404.
    [28]
    岳长涛,李术元,丁康乐,等.碳酸盐岩系TSR系统中铁的硫化物生成模拟实验研究[J].沉积学报,2004,22(4):743-749.
    [29]
    蔡春芳,李宏涛.沉积盆地热化学硫酸盐还原作用评述[J].地球科学进展,2005,20(10):1100-1105.
    [30]
    ZHANG SHUICHANG,ZHU GUANGYU,LIANG YINGBO,et al.Geochemical characteristics of the Zhaolanzhuang sour gas accumulation and thermochemical sulfate reduction in the Jixian Sag of Bohai Bay Basin[J].Organic Geochemistry,2005,36(12):1717-1730.
    [31]
    朱光有,张水昌,梁英波,等.川东北地区飞仙关组高含H2S天然气TSR成因的同位素证据[J].中国科学D辑,2005,35(11):1037-1045.
    [32]
    朱光有,张水昌,梁英波,等.川东北飞仙关组高含H2S气藏特征与TSR对烃类的消耗作用[J].沉积学报,2006,24(2):300-307.
    [33]
    杜春国,郝芳,邹华耀,等.热化学硫酸盐还原作用对碳酸盐岩气藏的化学改造:以川东北地区长兴组—飞仙关组气藏为例[J].地质学报,2007,81(1):119-125.
    [34]
    MOUGIN P,VAR V L,BARITEAU A,et al.Thermodynamic of thermochemical sulphate reduction[J].Journal of Petroleum Science and Engineering,2007,58(3-4):413-427.
    [35]
    岳长涛,李术元,丁康乐,等.甲烷和固态硫酸钙的热化学还原反应模拟实验初步研究[J].地球化学,2003,32(6):601-605.
    [36]
    岳长涛,李术元,丁康乐,等.影响天然气保存的TSR反应体系模拟实验研究[J].中国科学D辑,2005,35(1):48-53.
    [37]
    代金友,陈安定,何顺利.模拟硫化氢生成的热化学还原反应实验研究[J].石油实验地质,2008,30(2):200-202.
    [38]
    谢增业,李志生,王春怡,等.硫化氢生成模拟实验研究[J].石油实验地质,2008,30(2):192-195.
    [39]
    于林平,潘长春,刘金钟,等.氧化作用对气态烃组成和碳同位素组成的影响[J].地球化学,2005,34(3):269-276.
    [40]
    PAN CHANGCHUN,YU LINPING,LIU JINZHONG,et al.Chemical and carbon isotopic fractionations of gaseous hydrocarbons during abiogenic oxidation[J].Earth and Planetary Science Letters,2006,246(1-2):70-89.
    [41]
    ZHANG TONGWEI,GEOFFREY S E,WANG KANGSHI,et al.Effect of hydrocarbon type on thermochemical sulfate reduction[J].Organic Geochemistry,2007,38(6):897-910.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Citation
    XML
    PDF-CN

    Article Metrics

    Article views (1330) PDF downloads(902) Cited by()
    Proportional views
    Related

    Website Copyright © Wuxi Research Institute of Petroleum Geology, SINOPEC 苏ICP备15009037号 苏公网安备32021102000780号

    Address：No. 2060, Lihu Avenue, Wuxi, Jiangsu   (214126) Tel：0510-68787204，68787203 Fax：0510-68787113 Email：sysydz.syky@sinopec.com

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return