Yue Changtao, Li Shuyuan, Ling Ruifeng. Catalytic hydropyrolysis of over-mature source rock in northeast Sichuan Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(5): 540-545. doi: 10.11781/sysydz201105540
Citation: Yue Changtao, Li Shuyuan, Ling Ruifeng. Catalytic hydropyrolysis of over-mature source rock in northeast Sichuan Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(5): 540-545. doi: 10.11781/sysydz201105540

Catalytic hydropyrolysis of over-mature source rock in northeast Sichuan Basin

doi: 10.11781/sysydz201105540
  • Received Date: 2010-12-31
  • Rev Recd Date: 2011-08-31
  • Publish Date: 2011-10-28
  • The over-mature kerogen samples from the northeast Sichuan Basin were studied by catalytic hydropyrolysis in a fixed-bed reactor.The products were analyzed with GC-MS and were compared with source rock extracts.The distribution features and geochemical information of sterane,terpane in saturate hydrocarbon and dibenzothiophene and fluorene in aromatic hydrocarbon were studied.According to parameters such as hopane index,Pr/Ph,gammacerane index,regular sterane/17α(H)-hopane,C27-C28-C29 regular sterane,rearranged sterane/regular sterane,dibenzothiophene and fluorene,the source rocks in the northeast Sichuan Basin were marine carbonate ones with little clay deposited in anoxygenous and unhypersaline environment.The biogenic sources were plankton.

     

  • loading
  • [1]
    Love G D,Snape C E,Carr A D,et al.Release of covalentlybound alkane biomarkers in high yields from kerogen via catalytic hydropyrolysis[J]. Organic Geochemistry, 1995,23(10):981-986.
    [2]
    Bishop A N,Love G D,Mcaulay C E,et al.Release of kerogen-bound hopanoids by hydropyrolysis[J].Organic Geochemistry,1998,29(4):989-1001.
    [3]
    Murray I P,Love G D,Snape C E,et al.Comparison of covalently bound aliphatic biomarkers released via hydropyrolysis with their solvent-extractable counterparts for a suit of Krimmeridge clays[J].OrganicGeochemistry,1998,29(5-7):1487-1505.
    [4]
    Rocha J D,Brown S D,Love G D,et al.Hydropyrolysis:a versatile technique for solid fuel liquefaction,sulphur speciation and biomarker release[J].Journal of Analytical and Applied Pyrolysis,1997,40-41(1-2):91-103.
    [5]
    Love G D,Bowden S A,Jahnke L L,et al.A catalytic hydropyrolysis method for the rapid screening of microbial cultures for lipid biomarkers[J].Organic Geochemistry,2005,36(1):63-82.
    [6]
    Jochen J B,Love G D,Snape C E,et al.Release of bound aromatic hydrocarbons from late Archean and Mesoprotero zoic kerogens via hydropyrolysis[J].Geochimica et Cosmochimica Acta,2003,67(8):1521-1530.
    [7]
    Bowden S A,Farrimond P,Snape C E,et al.Compositional differences in biomarker constituents of the hydrocarbon,resin,asphaltene and kerogen fractions:An example from the Jet Rock (Yorkshire,UK)[J].Organic Geochemistry,2006,37(3):369-383.
    [8]
    Lockhart R S,Meredith W,Love G D,et al.Release of bound aliphatic biomarkers via hydropyrolysis from type Ⅱ kerogen at high maturity[J].Organic Geochemistry,2008,8(39):1119-1124.
    [9]
    孙永革,Meredith W,Snape C E,等.加氧催化裂解技术用于高演化源岩有机质表征研究[J] ,石油与天然气地质,2008,29(2):276-282.
    [10]
    周建伟,李术元,岳长涛,等.催化加氢热解反应催化剂前驱物四硫代钼酸铵的表征[J].化学试剂,2006,28(2):86-88.
    [11]
    周建伟,李术元,岳长涛,等.HYPY/SE提取固体有机质中生物标志化合物的研究[J].化学通报,2006,15(5):337-341.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (3053) PDF downloads(910) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return