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Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2011  >  33(6): 645-651
Li Shuifu, Hu Shouzhi, Cao Jian, He Sheng, Ma Jun, Wang Xulong, Zhang Dongmei, Chen Yuyao. Comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry of hydrocarbon in crude oil：application of inverse column set[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(6): 645-651. doi: 10.11781/sysydz201106645
Citation: Li Shuifu, Hu Shouzhi, Cao Jian, He Sheng, Ma Jun, Wang Xulong, Zhang Dongmei, Chen Yuyao. Comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry of hydrocarbon in crude oil：application of inverse column set[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(6): 645-651. doi: 10.11781/sysydz201106645
shu

Comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry of hydrocarbon in crude oil：application of inverse column set

doi: 10.11781/sysydz201106645
  • 1.

    Key Laboratory of Tectonics and Petroleum Resources (China University of Geosciences), Ministry of Education, Wuhan, Hubei 430074, China

  • 2. Faculty of Earth Resources, China University of Geosciences, Wuhan, Hubei 430074, China

  • 3. School of Earth Sciences and Engineering, Nanjing University, Nanjing, Jiangsu 210093, China

  • 4. Research Institute of Petroleum Exploration and Development, Xinjiang Branch Company, PetroChina, Karamay, Xinjiang 834000, China

  • Received Date: 2011-05-05
  • Rev Recd Date: 2010-09-29
  • Publish Date: 2011-12-28
    Abstract
  • Petroleum hydrocarbons,which span a wide range of boiling point and polarity,are very complicated.The comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry is one of the most effective methods to separate complex mixtures.An inverse column set was used to analyze petroleum hydrocarbons,and to distinguish some critical compounds,providing data for the comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry of hydrocarbons in crude oil.It was concluded that,the inverse column set worked perfectly in separating two dimensionally the saturated hydrocarbons,especially isoalkane and cyclane with low molecular weight.It could be used to distinguish the UCMs (unresolved complex mixtures) from saturated hydrocarbons of biodegradation oil.

     

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    • References(20)
  • [1]
    Aguiar A,Silva Júnior A I,Azevedo D A,et al.Application of comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry to biomarker characterization in Brazilian oils[J].Fuel,2010,89:2760-2768.
    [2]
    Ventura G T,Raghuraman B,Nelson R K,et al.Compound class oil fingerprinting techniques using comprehensive two-dimensional gas chromatography (GC×GC)[J].Organic Geochemistry,2010,41:1026-1035.
    [3]
    Frysinger G S,Gaines R B.Separation and identification of petroleum biomarkers by comprehensive two-dimensional gas chromatography [J].Journal of Separation Sciences,2001,24:87-96.
    [4]
    Von Mühlen C,Oliveira E C,Morrison P D,et al.Qualitative and quantitative study of nitrogen-containing compounds in heavy gas oil using comprehensive two-dimensional gas chromatography with nitrogen phosphorus detection [J].Journal of Separation Sciences,2007,30:3223-3232.
    [5]
    Li M,Zhang S,Jiang C,et al.Two-dimensional gas chroma-tograms as fingerprints of sour gas-associated oils[J].Organic Geochemistry,2008,39:1144-1149.
    [6]
    Ventura G T,Kenig F,Reddy C M,et al.Analysis of unresolved complex mixtures of hydrocarbons extracted from Late Archean sediments by comprehensive two-dimensional gas chromatography (GC×GC)[J].Organic Geochemistry,2008,39:846-867.
    [7]
    Avila B M F,Aguilar A,Gomes A O,et al.Characterization of extra heavy gas oil biomarkers using comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry [J].Organic Geochemistry,2010,41:863-866.
    [8]
    王汇彤,翁娜,张水昌,等.全二维气相色谱/飞行时间质谱对原油芳烃分析的图谱识别[J].科学通报,2010,55(21):2124-2130.
    [9]
    王汇彤,翁娜,张水昌,等.全二维气相色谱/飞行时间质谱对饱和烃分析的图谱识别及特征[J].质谱学报,2010,31(1):18-27.
    [10]
    蒋启贵,王强,马媛媛,等.全二维色谱飞行时间质谱在石油地质样品分析中的应用[J].石油实验地质,2009,31(6):627-632.
    [11]
    李水福,胡守志,何生,等.原油中常见化合物的全二维气相色谱—飞行时间质谱分析[J].地质科技情报,2010,29(5):46-50.
    [12]
    Tran T C,Logan G A,Grosjean E,et al.Comparison of column phase configurations for comprehensive two dimensional gas chromatographic analysis of crude oil and bitumen[J].Organic Geochemistry,2006,37:1190-1194.
    [13]
    Kohla A,Cochranb J,Cropek D M.Characterization of military fog oil by comprehensive two-dimensional gas Chromatography[J].Journal of Chromatography A,2010,1217:550-557.
    [14]
    Tran T C,Logan G A,Grosjean E,et al.Use of comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry for the characterization of biodegradation and unresolved complex mixtures in petroleum.[J].Geochimica et Cosmochimica Acta,2010,74:6468-6484.
    [15]
    鹿洪亮,赵明月,刘惠民,等.全二维气相色谱/质谱的原理及应用综述[J].烟草科技/烟草化学,2005(3):22-25.
    [16]
    王汇彤,魏彩云,宋孚庆,等.细硅胶层析柱对饱和烃和芳烃的分离[J].石油实验地质,2009,31(3):312-314.
    [17]
    菲利普 R P.化石燃料生物标志物:应用与谱图[M].北京:科学出版社,1987.
    [18]
    中华人民共和国能源部.中华人民共和国石油天然气行业标准[S].生物标志物谱图 SY5397-91.北京:石油工业出版社,1992.
    [19]
    王培荣.生物标志物质量色谱图集[M].北京:石油工业出版社,1993.
    [20]
    Chen J H,Fu J M,Sheng G Y,et al.Diamondoid hydrocarbon ratios:Novel maturity indices for highly mature crude oils[J].Organic Geochemistry,1996,25(3):179-190.
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