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Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2011  >  33(6): 645-651
Li Shuifu, Hu Shouzhi, Cao Jian, He Sheng, Ma Jun, Wang Xulong, Zhang Dongmei, Chen Yuyao. Comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry of hydrocarbon in crude oil：application of inverse column set[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(6): 645-651. doi: 10.11781/sysydz201106645
Citation: Li Shuifu, Hu Shouzhi, Cao Jian, He Sheng, Ma Jun, Wang Xulong, Zhang Dongmei, Chen Yuyao. Comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry of hydrocarbon in crude oil：application of inverse column set[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(6): 645-651. doi: 10.11781/sysydz201106645
shu

Comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry of hydrocarbon in crude oil：application of inverse column set

doi: 10.11781/sysydz201106645
  • 1.

    Key Laboratory of Tectonics and Petroleum Resources (China University of Geosciences), Ministry of Education, Wuhan, Hubei 430074, China

  • 2. Faculty of Earth Resources, China University of Geosciences, Wuhan, Hubei 430074, China

  • 3. School of Earth Sciences and Engineering, Nanjing University, Nanjing, Jiangsu 210093, China

  • 4. Research Institute of Petroleum Exploration and Development, Xinjiang Branch Company, PetroChina, Karamay, Xinjiang 834000, China

  • Received Date: 2011-05-05
  • Rev Recd Date: 2010-09-29
  • Publish Date: 2011-12-28
    Abstract
  • Petroleum hydrocarbons,which span a wide range of boiling point and polarity,are very complicated.The comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry is one of the most effective methods to separate complex mixtures.An inverse column set was used to analyze petroleum hydrocarbons,and to distinguish some critical compounds,providing data for the comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry of hydrocarbons in crude oil.It was concluded that,the inverse column set worked perfectly in separating two dimensionally the saturated hydrocarbons,especially isoalkane and cyclane with low molecular weight.It could be used to distinguish the UCMs (unresolved complex mixtures) from saturated hydrocarbons of biodegradation oil.

     

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