Jiang Qigui, Ma Yuanyuan, Qian Menhui, Song Xiaoying. Comparison between comprehensive 2d gas chromatography and conventional gas chromatography in geochemical analysis of petroleum geology[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2012, 34(3): 303-308. doi: 10.11781/sysydz201203303
Citation: Jiang Qigui, Ma Yuanyuan, Qian Menhui, Song Xiaoying. Comparison between comprehensive 2d gas chromatography and conventional gas chromatography in geochemical analysis of petroleum geology[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2012, 34(3): 303-308. doi: 10.11781/sysydz201203303

Comparison between comprehensive 2d gas chromatography and conventional gas chromatography in geochemical analysis of petroleum geology

doi: 10.11781/sysydz201203303
  • Received Date: 2011-07-18
  • Rev Recd Date: 2012-04-09
  • Publish Date: 2012-05-28
  • Geochemical analysis of petroleum geology has been made by using comprehensive 2d gas chromatography (GC×GC) and conventional gas chromatography. The parameters of light hydrocarbons and isoprenoids by oil direct injection and by saturated hydrocarbons or aromatics injection are comparable according to a comparative study of geochemistry, whereas part of the aromatics such as naphthalene series and benzfhiore tri-fluorene are characterized with obvious differences. Comparing with aromatics injection, the dimethylnaphthalene in crude oil direct injection is in dominant position and dibenzofurans is significant higher, which shows that the separation of compound-grouped fractions in pretreatment of sample changes the original appearance of aromatics. Therefore the establishment of the benzfhiore tri-fluorene chart which reflects organic deposition environment should not be applied to the analysis results of oil by GC×GC. Oil direct injection can provide more real information because there is no need for pretreatment.

     

  • loading
  • [1]
    Liu Zaiyou,Phillips J B.Comprehensive two-dimensional gas-chromatography using an on-column thermal modulator interface[J].Journal of Chromatographic Science,1991,29(6):227-231.
    [2]
    Philips J B,Beens J.Comprehensive two-dimensional gas-chromtography:a hyphenated method with strong coupling between the two dimensions[J].Journal of Chromatography A, 1999,856(1/2):331-347.
    [3]
    Blomberg J,Schoenmakers P J,Beens J,et al.Comprehensive two-dimensional gas chromatography(GC×GC)and its applicability to the characterization of complex (petrochemical) mixtures[J].Journal of High Resolution Chromatography,1997,20(10):539-544.
    [4]
    花瑞香,阮春海,王京华,等.全二维气相色谱法用于不同石油馏分的族组成分布研究[J].化学学报,2002,60(12):2185-2191.
    [5]
    路鑫,武建芳,吴建华,等.全二维气相色谱/飞行时间质谱用于柴油组成的研究[J].色谱,2004,22(1):5-11.
    [6]
    Frysinger G S,Gaines R B.Separation and identification of petroleum biomarkers by comprehensive two-dimensional gas chromatography[J].Journal of Separation Science,2001,24(2):87-96.
    [7]
    蒋启贵,王强,马媛媛,等.全二维色谱飞行时间质谱在石油地质样品分析中的应用[J].石油实验地质,2009,31(6):627-631.
    [8]
    王汇彤,翁娜,张水昌,等.全二维气相色谱/飞行时间质谱对原油芳烃分析的图谱识别[J].科学通报,2010,55(21):2124-2130.
    [9]
    李水福,胡守志,何生,等.原油中常见化合物的全二维气相色谱—飞行时间质谱分析[J].地质科技情报,2010,29(5):46-50.
    [10]
    Vendeuvre C,Bertoncini F,Duval L,et al.Comparison of conventional gas chromatography and comprehensive two-dimensional gas chromatography for the detailed analysis of petrochemical samples[J].Journal of Chromotography A,2004,1056(1/2):155-162.
    [11]
    张美珍,承秋泉,蒋启贵,等.原油轻烃反吹色谱分析[J].石油实验地质,2007,29(2):212-216.
    [12]
    苟爱仙,张艳丽,史群策,等.高效液相色谱测定润滑油烃族组成[J].黑龙江石油化工,1999,10(4):40-42.
    [13]
    苟捷,谢小渝.轻质原油(含凝析油)的烃族组分分析[J].石油实验地质,2000,22(1):94-96.
    [14]
    郭志军,张庭良,刘秀清,等.用TLC/FID棒薄层色谱测定重质油的族组成方法的研究[J].福建分析测试,2008,17(2):22-24.
    [15]
    田亮.多维气相色谱法测定油品的族组成[J].石化技术与应用,2004,18(2):119-121.
    [16]
    Peters K E,Fraser T H,Amris W,et al.Geochemistry of Crude Oils from Eastern Indonesia[J].AAPG Bulletin,1999,83(12):1927-1943.
    [17]
    李水福,何生.原油芳烃中三芴系列化合物的环境指示作用[J].地球化学,2008,37(1):45-501.
    [18]
    李素梅,庞雄奇,金之钧,等. 沉积物中NSO杂环芳烃的分布特征及其地球化学意义[J].地球化学,2001,30(4):347-352.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (3969) PDF downloads(2165) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return