Chen Zulin, Zhang Min, Liu Haiyu. Micro-column convenient chromatography for separation of aromatic hydrocarbon compound and GC/IRMS analysis[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2013, 35(3): 347-350. doi: 10.11781/sysydz201303347
Citation: Chen Zulin, Zhang Min, Liu Haiyu. Micro-column convenient chromatography for separation of aromatic hydrocarbon compound and GC/IRMS analysis[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2013, 35(3): 347-350. doi: 10.11781/sysydz201303347

Micro-column convenient chromatography for separation of aromatic hydrocarbon compound and GC/IRMS analysis

doi: 10.11781/sysydz201303347
  • Received Date: 2012-05-12
  • Rev Recd Date: 2013-04-18
  • Publish Date: 2013-05-28
  • An easy and economic method to separate alkylated napthalenes and alkylated phenanthrenes from aromatic hydrocarbons was introduced in this paper.The GC-MS tests showed that this method could provide a complete and enriched separation of alkylated napthalenes and alkylated phenanthrenes from crude oils and sedimentary samples,solving the problem that several methyls were difficult to determine accurately by GC-MS tests because of heavy co-elution and laying the foundation for free carbon isotope tests.As an application,this method can be used for aromatic hydrocarbons of monomer hydrocarbon carbon isotope analysis of pre treatment.

     

  • loading
  • [1]
    熊永强,耿安松,廖玉宏,等.原油中烷基萘和烷基菲的碳同位素组成研究[J].新疆石油地质,2004,25(4):355-357.
    [2]
    SY/T 5119-1995.岩石可溶有机物和原油族组分柱层析分析方法[S].北京:石油工业出版社,2004.
    [3]
    张文正,昝川莉,李先奇,等.塔里木盆地凝析油单体烃碳同位素特征与成因分析[J].沉积学报,1990,8(2):111-114.
    [4]
    赵孟军,黄第藩.不同沉积环境生成的原油单体烃碳同位素分布特征[J].石油实验地质,1995,17(2):171-179.
    [5]
    张晓宝,刘文汇.有机物质单体烃同位素国内外研究现状[J].天然气地球科学,1996,7(4):29-33.
    [6]
    熊永强,耿安松.GC-IRMS技术在地球化学中的应用现状与前景[J].矿物岩石地球化学通报,1996(2):128-137.
    [7]
    福尔G.同位素地质学原理[M].潘曙兰,乔广生,译.北京:科学出版社,1983.
    [8]
    王大锐.油气稳定同位素地球化学[M].北京:石油工业出版社,2000.
    [9]
    Grizzle P L,Thomson J S.Liquid chromatographic separation of aromatic hydrocarbons with chemically bonded (2,4-dinitroanilinopropyl) silica[J].Anal Chem,1982,54:1071.
    [10]
    Jiang C Q,Li M W,van Duin A C T.Inadequate separation of saturate and monoaromatic hydrocarbons in crude oils and rock extracts by alumina column chromatography[J].Organic Geochemistry,2000,31(7/8):751-756.
    [11]
    周佩瑜,孙永革.原油中萘系物柱色谱快速分离技术及其初步应用[J].地球化学,2008,37(5):512-518.
    [12]
    周佩瑜.石油烃中烷基萘的形成机理及其地球化学意义[J].地质科技情报,2008,28(5):92-98.
    [13]
    程中弟,肖延荣,葛修丽.气相色谱法分析原油及岩石抽提物中的链状烷烃及其应用[J].分析测试通报,1983,2(试刊):32-37.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (1370) PDF downloads(655) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return