Advanced Search
Volume 37 Issue 2
. 
Turn off MathJax
Article Contents
Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2015  >  37(2): 220-225
Zhao Jing, Liang Qianyong, Xiong Yongqiang, Li Yun, Fang Chenchen. Application of headspace single-drop microextraction (HS-SDME) technique in geochemical exploration for petroleum[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2015, 37(2): 220-225. doi: 10.11781/sysydz201502220
Citation: Zhao Jing, Liang Qianyong, Xiong Yongqiang, Li Yun, Fang Chenchen. Application of headspace single-drop microextraction (HS-SDME) technique in geochemical exploration for petroleum[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2015, 37(2): 220-225. doi: 10.11781/sysydz201502220
shu

Application of headspace single-drop microextraction (HS-SDME) technique in geochemical exploration for petroleum

doi: 10.11781/sysydz201502220
  • 1.

    Guangzhou Marine Geological Survey, Guangzhou, Guangdong 510760, China

  • 2. State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640, China

  • 3. Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China

  • Received Date: 2013-12-04
  • Rev Recd Date: 2015-01-06
  • Publish Date: 2015-03-28
    Abstract
  • All surface geochemical exploration methods for oil and gas are based on the theory that hydrocarbons generated and trapped at depth seep in varying but detectable quantities to the surface, and the main components detected are usually C1-C5 hydrocarbons. The C1-C4 hydrocarbons could come from degradation of organic matter by microbial organisms, while the gasoline range hydrocarbons are totally sourced from thermogenic processes. Therefore, the detection of gasoline range hydrocarbons in soils or sediments could be the most direct evidence for hydrocarbon seepage and the method used to detect the C6-C12 range hydrocarbons could be a useful technique for surface geochemical exploration method for petroleum. However, because the concentration of gasoline range hydrocarbons in the soils or sediments are usually very low, and the present techniques for detecting those hydrocarbons are not adequate, the gasoline range hydrocarbons have seldom been used in surface geochemical exploration for oil and gas. In this study, the headspace single-drop microextraction (HS-SDME) technique coupled with gas chromatography-flame ionization detection (GC-FID) was employed to determine C6-C12 gasoline range hydrocarbons in well drilling mud sample. The results show that the C6-C12 hydrocarbons in the samples could be detected by HS-SDME, and the reservoir depth determined by the concentration of C6-C12 hydrocarbons was the same with the actual petroleum reservoir depth, which indicated further that the HS-SDME method could be used in geochemical exploration for petroleum.

     

    • FullText(HTML)
  • loading
    • References(30)
  • [1]
    Leythaeuser D,Schaefer R G,Pooch H.Diffusion of light hydrocarbons in subsurface sedimentary rocks[J].AAPG Bulletin,1983,67(6):889-892.
    [2]
    Kross B M,Leythaesser D.Molecular diffusion of light hydrocarbons in sedimentary rocks and its role in the migration and dissipation of natural gas[J].AAPG Memoir,1996,66(14):173-183.
    [3]
    Conant B H,Gillham R W,Mendoza C A.Vapor transport of trichloroethylene in the unsaturated zone:field and numerical modeling investigations[J].Water Resources Research,1996,32(1):9-22.
    [4]
    Whiticar M J.Carbon and hydrogen isotope systematics of bacterial formation and oxidation of methane[J].Chemical Geology,1999,161(1-3):291-314.
    [5]
    Abrams M A,Dahdah N F,Francu E.Development of methods to collect and analyze gasoline range (C5-C12) hydrocarbons from seabed sediments as indicators of subsurface hydrocarbon generation and entrapment[J].Applied Geochemistry,2009,24(10):1951-1970.
    [6]
    Harris S A,Whiticar M J,Eek M K.Molecular and isotopic analysis of oils by solid phase microextraction of gasoline range hydrocarbons[J].Organic Geochemistry,1999,30(8):721-737.
    [7]
    胡斌,李双林,李广之,等.固相微萃取技术及其在油气地球化学探测中的应用[J].海洋地质动态,2009,25(12):8-12,35. Hu Bin,Li Shuanglin,Li Guangzhi,et al.Solid phase micro-extraction technique and its application in geochemical exploration for oil and gas[J].Marine Geology Letters,2009,25(12):8-12,35.
    [8]
    袁子艳.固相微萃取技术在油气化探中的应用[J].物探与化探,2012,36(2):237-241. Yuan Ziyan.The application of solid phase micro-extraction technique to oil and gas geochemical exploration[J].Geophysical & Geochemical Exploration,2012,36(2):237-241.
    [9]
    George S C,Boreham C J,Minifie S A,et al.The effect of minor to moderate biodegradation on C5 to C9 hydrocarbons in crude oils[J].Organic Geochemistry,2002,33(12):1293-1317.
    [10]
    Belardi R G,Pawliszyn J B.The application of chemically modified fused silica fibers in the extraction of organic from water matrix samples and their rapid transfer to capillary columns[J].Water Pollution Research Journal of Canada,1989,24:179-191.
    [11]
    Rocha S,Ramalheira V,Barros A,et al.Headspace solid phase microextraction (SPME) analysis of flavor compounds in wines.Effect of the matrix volatile composition in relative response factors in a wine model[J].Journal of Agricultural and Food Che-mistry,2001,49(11):5142-5151.
    [12]
    Akiyama M,Murakami K,Ohtani N,et al.Analysis of volatile compounds released during the Grinding of Roasted Coffee Beans using solid-phase microextraction[J].Journal of Agriculture and Food Chemistry,2003,51(7):1961-1969.
    [13]
    Theis A L,Waldack A J,Hansen S M,et al.Headspace solvent microextraction[J].Analytical Chemistry,2001,73(23):5651-5654.
    [14]
    Fang Chenchen,Xiong Yongqiang,Liang Qianyong,et al.Optimization of headspace single-drop microextraction technique for extraction of light hydrocarbons (C6–C12) and its potential applications[J].Organic Geochemistry,2011,42(4):316-322.
    [15]
    Li Yun,Xiong Yongqiang,Fang Chenchen,et al.A new application of headspace single-drop micro-extraction technique for compound specific carbon isotopic determination of gasoline range hydrocarbons[J].Organic Geochemistry,2011,42(5):559-565.
    [16]
    李芸.溢油源鉴别中有机地球化学技术和方法的拓展及应用[D].广州:中国科学院广州地球化学研究所,2011. Li Yun.Development and application of organic geochemical techniques and methods in the identification of oil spill sources[D].Guangzhou:Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,2011.
    [17]
    房忱琛.原油裂解过程中金刚烷类化合物的演化分析与模拟[D].广州:中国科学院广州地球化学研究所,2013. Fang Chenchen.Analysis and simulation of diamondoids evolution during oil cracking[D].Guangzhou:Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,2013.
    [18]
    Odden W,Patience R L,van Graas G W.Application of light hydrocarbons (C4-C13) to oil/source rock correlations:a study of the light hydrocarbon compositions of source rocks and test fluids from offshore Mid-Norway[J].Organic Geochemistry,1998,28(12):823-847.
    [19]
    Harris S A,Whiticar M J,Eek M K.Molecular and isotopic ana-lysis of oils by solid phase microextraction of gasoline range hydrocarbons[J].Organic Geochemistry,1999,30(8):721-737.
    [20]
    Wang Yi,Huang Yongsong.Hydrogen isotopic fractionation of low molecular weight n-alkanes during progressive vaporization[J].Organic Geochemistry,2001,32(8):991-998.
    [21]
    George S C,Boreham C J,Minifie S A,et al.The effect of minor to moderate biodegradation on C5 to C9 hydrocarbons in crude oils[J].Organic Geochemistry,2002,33(12):1293-1317.
    [22]
    Smallwood B J,Philp R P,Allen J D.Stable carbon isotopic composition of gasolines determined by isotope ratio monitoring gas chromatography mass spectrometry[J].Organic Geochemistry,2002,33(2):149-159.
    [23]
    Cañipa-Morales N K,Garlán-Vidal C A,Guzmán-Vega M A,et al.Effect of evaporation on C7 light hydrocarbon parameters[J].Organic Geochemistry,2003,34(6):813-826.
    [24]
    Erdman J G,Morris D A.Geochemical correlation of petroleum[J].AAPG Bulletin,1974,58(11):2326-2337.
    [25]
    Phillippi G T.The deep subsurface temperature controlled origin of the gaseous and gasoline-range hydrocarbons or petroleum[J].Geochimica et Cosmochimica Acta,1975,39(10):1353-1373.
    [26]
    Thompson K F M.Fractionated aromatic petroleums and the generation of gas-condensates[J].Organic Geochemistry,1987,11(6):573-590.
    [27]
    Thompson K F M.Gas-condensates migration and oil fractionation in deltaic systems[J].Marine and Petroleum Geology,1988,5(3):237-246.
    [28]
    Mango F D.An invariance in the isoheptanes of petroleum[J].Science,1987,237(4814):514-517.
    [29]
    Mango F D.The light hydrocarbons in petroleum:a critical review[J].Organic Geochemistry,1997,26(7/8):417-440.
    [30]
    Halpern H I.Development and application of light-hydrocarbon-based star diagrams[J].AAPG Bulletin,1995,79(6):801-815.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Citation
    XML
    PDF-CN

    Article Metrics

    Article views (1115) PDF downloads(462) Cited by()
    Proportional views
    Related

    Website Copyright © Wuxi Research Institute of Petroleum Geology, SINOPEC 苏ICP备15009037号 苏公网安备32021102000780号

    Address：No. 2060, Lihu Avenue, Wuxi, Jiangsu   (214126) Tel：0510-68787204，68787203 Fax：0510-68787113 Email：sysydz.syky@sinopec.com

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return