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Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2016  >  38(5): 685-691
Ma Yuanyuan, Jiang Qigui, Song Xiaoying, Qian Menhui, Liu Peng. Analysis of organic acids in crude oil by comprehensive two-dimensional gas chromatography and time-of-flight mass spectrometry[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2016, 38(5): 685-691. doi: 10.11781/sysydz201605685
Citation: Ma Yuanyuan, Jiang Qigui, Song Xiaoying, Qian Menhui, Liu Peng. Analysis of organic acids in crude oil by comprehensive two-dimensional gas chromatography and time-of-flight mass spectrometry[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2016, 38(5): 685-691. doi: 10.11781/sysydz201605685
shu

Analysis of organic acids in crude oil by comprehensive two-dimensional gas chromatography and time-of-flight mass spectrometry

doi: 10.11781/sysydz201605685
  • 1.

    Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi, Jiangsu 214126, China

  • 2. SINOPEC Key Laboratory of Petroleum Accumulation Mechanism, Wuxi, Jiangsu 214126, China

  • Received Date: 2015-03-27
  • Rev Recd Date: 2016-07-04
  • Publish Date: 2016-09-28
    Abstract
  • The composition of organic acids in crude oil samples was determined using comprehensive two-dimensional gas chromatography and time-of-flight mass spectrometry (GC×GC-TOFMS) for the first time by analyzing the deviations of acidic components in crude oil. Aliphatic acids (straight chain monocarboxylic acid, isoprenoid acid, 2-ethyl alkanoic acid methyl esters and straight chain dicarboxylic acid) and naphthenic acids (monocyclic long chain aliphatic acid, 1,4-dimethoxyanthracene, dehydroabietic acid and steroid acid) were detected in crude oil. GC×GC-TOFMS provides a new high resolution geochemical analysis of petroleum acid compositions.

     

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