Qian Yu, Wang Zuodong, Tuo Jincai, Zhang Ting, He Yonghong. Origin and significance of monomethylalkanes from Yanchang Formation source rocks in Ordos Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2017, 39(1): 86-93. doi: 10.11781/sysydz201701086
Citation: Qian Yu, Wang Zuodong, Tuo Jincai, Zhang Ting, He Yonghong. Origin and significance of monomethylalkanes from Yanchang Formation source rocks in Ordos Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2017, 39(1): 86-93. doi: 10.11781/sysydz201701086

Origin and significance of monomethylalkanes from Yanchang Formation source rocks in Ordos Basin

doi: 10.11781/sysydz201701086
  • Received Date: 2016-06-01
  • Rev Recd Date: 2016-11-30
  • Publish Date: 2017-01-28
  • Monomethylalkanes are common branched alkanes in the saturated hydrocarbon fraction of lacustrine source rocks. However, there is no agreement about their original source. The abundance of monomethylalkanes, from the Triassic Yanchang Formation source rocks in the Ordos Basin is relatively high. Determination of TOC, Rock-Eval, compound specific carbon isotopic composition, and GC-MS analysis of saturated hydrocarbons show that the organic matter of source rocks from Chang7-Chang10 have a mixed source, and that the type of organic matter is Ⅱ-Ⅲ. The steroid hydrocarbon distributions of source rocks showed nearly equal abundances of C27 and C29 steranes, suggesting mixed organic matter. The monomethylalkanes have 12 to 32 carbons, having a similar distribution to the n-alkanes, and the 2-MMAs and 3-MMAs are predominant. The δ13C values of Pr and Ph are 1‰ to 2‰ heavier than corresponding n-alkanes. 2-MMAs and 3-MMAs with the same carbon number have almost the same δ13C value, indicating they have the same source. The δ13C values of monomethylalkanes range from -29.3‰ to -32.8‰, which are higher than n-alkanes. Moreover, combining with the sedimentary environment information of the Ordos Basin, it appears that the monomethylalkanes might come from phytoplankton and heterotrophic bacteria, and they can be used as a biomarker to judge the predecessor of sediment and petroleum.

     

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  • [1]
    菲尔普 R P.化石燃料生物标志物:应用与谱图[M].傅家谟,盛国英,译.北京:科学出版社,1987:44-48. Philp R P.Fossil fuel biomarkers:Applications and spectra[M].Fu Jiamo,Sheng Guoying,trans.Beijing:Science Press,1987:44-48.
    [2]
    Fowler M G,Douglas A G.Saturated hydrocarbon biomarkers in oils of Late PreCambrian age from Eastern Siberia[J].Organic Geochemistry,1987,11(3):201-213.
    [3]
    Kenig F,Damsté J S S,Kock-van Dalen A C,et al.Occurrence and origin of mono-,di-,and trimethylalkanes in modern and Holocene cyanobacterial mats from Abu Dhabi,United Arab Emirates[J].Geochimica et Cosmochimica Acta,1995,59(14):2999-3015.
    [4]
    Lu Hong,Peng Ping'an,Sun Yongge.Molecular and stable carbon isotopic composition of monomethylalkanes from one oil sand sample:Source implications[J].Organic Geochemistry,2003,34(6):745-754.
    [5]
    Kenig F.C16-C29 homologous series of monomethylalkanes in the pyrolysis products of a Holocene microbial mat[J].Organic geochemistry,2000,31(2/3):237-241.
    [6]
    Thiel V,Jenisch A,W rheide G,et al.Mid-chain branched alkanoic acids from "living fossil" demosponges:A link to ancient sedimen-tary lipids?[J].Organic Geochemistry,1999,30(1):1-14.
    [7]
    Kenig F,Damsté J S S,de Leeuw J W,et al.Molecular palaeontological evidence for food-web relationships?[J].Naturwissenschaften,1994,81(3):128-130.
    [8]
    Summons R E,Powell T G,Boreham C J.Petroleum geology and geochemistry of the Middle Proterozoic Mcarthur Basin,Northern Australia:Ⅲ.Composition of extractable hydrocarbons[J].Geochimica et Cosmochimica Acta,1988,52(7):1747-1763.
    [9]
    Summons R E.Branched alkanes from ancient and modern sediments:Isomer discrimination by GC/MS with multiple reaction monitoring[J].Organic Geochemistry,1987,11(4):281-289.
    [10]
    Klomp U C.The chemical structure of a pronounced series of iso-alkanes in South Oman crudes[J].Organic Geochemistry,1986,10(4/6):807-814.
    [11]
    Kissin Y V.Catagenesis and composition of petroleum:Origin of n-alkanes and isoalkanes in petroleum crudes[J].Geochimica et Cosmochimica Acta,1987,51(9):2445-2457.
    [12]
    Love G D,Stalvies C,Grosjean E,et al.Analysis of molecular biomarkers covalently bound within Neoproterozoic sedimentary kerogen//Kelley P H,Bambach R K.From evolution to Geobio-logy:Research questions driving paleontology at the start of a new century,Paleontological Society Short Course,October 4,2008.Paleontological Society Papers 14.:The Paleontological Society,2008:67-83.
    [13]
    Logan G A,Hinman M C,Walter M R,et al.Biogeochemistry of the 1 640 Ma McArthur River (HYC) lead-zinc ore and host sediments,Northern Territory,Australia[J].Geochimica et Cosmochimica Acta,2001,65(14):2317-2336.
    [14]
    Arouri K,Conaghan P J,Walter M R,et al.Reconnaissance sedimentology and hydrocarbon biomarkers of Ediacarian microbial mats and acritarchs,Lower Ungoolya Group,Officer Basin[J].Precambrian Research,2000,100(1/3):235-280.
    [15]
    Logan G A,Calver C R,Gorjan P,et al.Terminal Proterozoic mid-shelf benthic microbial mats in the Centralian Superbasin and their environmental significance[J].Geochimica et Cosmochimica Acta,1999,63(9):1345-1358.
    [16]
    Han J,Calvin M.Branched alkanes from blue-green algae[J].Journal of the Chemical Society D:Chemical Communications,1970(22):1490-1491.
    [17]
    Jackson M J,Powell T G,Summons R E,et al.Hydrocarbon shows and petroleum source rocks in sediments as old as 1.7×109 years[J].Nature,1986,322(6081):727-729.
    [18]
    Audino M,Grice K,Alexander R,et al.Unusual distribution of monomethylalkanes in Botryococcus braunii-rich samples:Origin and significance[J].Geochimica et Cosmochimica Acta,2001,65(12):1995-2006.
    [19]
    Shiea J,Brassell S C,Ward D M.Mid-chain branched mono- and dimethyl alkanes in hot spring cyanobacterial mats:A direct biogenic source for branched alkanes in ancient sediments?[J].Organic Geochemistry,1990,15(3):223-231.
    [20]
    Kenig F,Huc A Y,Purser B H,et al.Sedimentation,distribution and diagenesis of organic matter in a recent carbonate environment,Abu Dhabi,U.A.E.[J].Organic Geochemistry,1990,16(4/6):735-747.
    [21]
    卢鸿,孙永革,彭平安.单甲基支链烷烃的单体碳同位素研究[J].沉积学报,2003,21(2):360-365. Lu Hong,Sun Yongge,Peng Ping'an.Molecular stable carbon isotopic compositions of mono-methyl branched alkanes[J].Acta Sedimentologica Sinica,2006,21(2):360-365.
    [22]
    卢鸿,孙永革,彭平安.塔里木轮南14井三叠系油砂中长链单甲基支链烷烃及其单体碳同位素组成[J].地质论评,2002,48(S1):218-224. Lu Hong,Sun Yongge,Peng Ping'an.Molecular and stable carbon isotopic compositions of long-chain monomethylalkanes from an oil sand sample in the Lunnan Oilfield,Tarim Basin,NW China[J].Geological Review,2002,48(S1):218-224.
    [23]
    钱宇,王作栋,贾冬,等.烃源岩中单甲基烷烃化合物分析与鉴定[J].沉积学报,2015,33(5):1033-1042. Qian Yu,Wang Zuodong,Jia Dong,et al.Analysis and identification of monomethylalkanes in source rocks[J].Acta Sedimentologica Sinica,2015,33(5):1033-1042.
    [24]
    McCarthy E D,Han J,Calvin M.Hydrogen atom transfer in mass spectrometric fragmentation patterns of saturated aliphatic hydrocarbons[J].Analytical Chemistry,1968,40(10):1475-1480.
    [25]
    Grice K,Audino M,Boreham C J,et al.Distributions and stable carbon isotopic compositions of biomarkers in torbanites from different palaeogeographical locations[J].Organic Geochemistry,2001,32(10):1195-1210.
    [26]
    吉利明,李剑峰,宋之光.鄂尔多斯盆地延长组葡萄藻的石油地质意义[J].石油勘探与开发,2009,36(2):156-165. Ji Liming,Li Jianfeng,Song Zhiguang.Petroleum geological significance of Botryococcus in Triassic Yanchang Formation,Ordos Basin[J].Petroleum Exploration and Development,2009,36(2):156-165.
    [27]
    Shiea J,Brassel S C,Ward D M.Comparative analysis of extrac-table lipids in hot spring microbial mats and their component photosynthetic bacteria[J].Organic Geochemistry,1991,17(3):309-319.
    [28]
    Robinson N,Eglinton G.Lipid chemistry of Icelandic hot spring microbial mats[J].Organic Geochemistry,1990,15(3):291-298.
    [29]
    Van Kaam-Peters H M E,Damsté J S S.Characterisation of an extremely organic sulphur-rich,150 Ma old carbonaceous rock:Palaeoenvironmental implications[J].Organic Geochemistry,1997,27(7/8):371-397.
    [30]
    张文正,关德师.液态烃分子系列碳同位素地球化学[M].北京:石油工业出版社,1997:20-35. Zhang Wenzheng,Guan Deshi.Carbon isotope geochemistry of liquid hydrocarbon molecular series[M].Beijing:Petroleum Industry Press,1997:20-35.
    [31]
    Collister J W,Lichtfouse E,Hieshima G,et al.Partial resolution of sources of n-alkanes in the saline portion of the Parachute Creek Member,Green River Formation (Piceance Creek Basin,Colorado)[J].Organic Geochemistry,1994,21(6/7):645-659.
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