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Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2018  >  40(6): 855-858
ZHANG Wenlong, HUANG Ling. Optimization of compound-specific hydrogen isotope analysis of natural gas[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2018, 40(6): 855-858. doi: 10.11781/sysydz201806855
Citation: ZHANG Wenlong, HUANG Ling. Optimization of compound-specific hydrogen isotope analysis of natural gas[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2018, 40(6): 855-858. doi: 10.11781/sysydz201806855
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Optimization of compound-specific hydrogen isotope analysis of natural gas

doi: 10.11781/sysydz201806855

  • Central Laboratory of Geological Sciences, Research Institute of Petroleum Exploration & Development, PetroChina, Beijing 100083, China

  • Received Date: 2018-08-03
  • Rev Recd Date: 2018-08-30
  • Publish Date: 2018-11-28
    Abstract
  • The conditioning method has an important influence on the compound-specific analysis results of hydrogen isotope ratios. The effects of three methods (injection of n-hexane or methane in the inlets, the reverse injection of methane) on the determination of hydrogen isotope values were investigated and compared. The results showed that the method of reverse injection of methane before each sample analysis can ensure the consistency of conditioning in the pyrolysis furnace tube, and can provide the best repeatability and accuracy of the compound-specific hydrogen isotope determination of natural gas.

     

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    • References(23)
  • [1]
    FARAMAWY S,ZAKI T,SAKR A E.Natural gas origin,composition,and processing:a review[J].Journal of Natural Gas Science and Engineering,2016,34:34-54.
    [2]
    SHARP Z.Principles of stable isotope geochemistry[M].New Jersey:Pearson Education,2007.
    [3]
    戴金星,倪云燕,黄士鹏,等.煤成气研究对中国天然气工业发展的重要意义[J].天然气地球科学,2014,25(1):1-22.

    DAI Jinxing,NI Yunyan,HUANG Shipeng,et al.Significant function of coal-derived gas study for natural gas industry development in China[J].Natural Gas Geoscience,2014,25(1):1-22.
    [4]
    司万霞.有机地球化学实验技术新进展[J].中外能源,2018,23(6):27-32.

    SI Wanxia.New progress of organic geochemistry experimental technology[J].Sino-Global Energy,2018,23(6):27-32.
    [5]
    VINSON D S,BLAIR N E,MARTINI A M,et al.Microbial methane from in situ biodegradation of coal and shale:a review and reevaluation of hydrogen and carbon isotope signatures[J].Chemical Geology,2017,453:128-145.
    [6]
    戴金星,倪云燕,吴小奇.中国致密砂岩气及在勘探开发上的重要意义[J].石油勘探与开发,2012,39(3):257-264.

    DAI Jinxing,NI Yunyan,WU Xiaoqi.Tight gas in China and its significance in exploration and exploitation[J].Petroleum Exploration and Development,2012,39(3):257-264.
    [7]
    杨涛,张国生,梁坤,等.全球致密气勘探开发进展及中国发展趋势预测[J].中国工程科学,2012,14(6),64-68.

    YANG Tao,ZHANG Guosheng,LIANG Kun,et al.The exploration of global tight sandstone gas and forecast of the development ten-dency in China[J].Engineering Science,2012,14(6):64-68.
    [8]
    路清华,顾忆,宋振响,等.松辽盆地梨树断陷金山地区天然气地球化学特征及其地质意义[J].石油实验地质,2016,38(2):259-265.

    LU Qinghua,GU Yi,SONG Zhenxiang,et al.Geochemical characteristics and geological significance of natural gas in Jinshan area of the Lishu Fault Depression[J].Petroleum Geology & Experiment,2016,38(2):259-265.
    [9]
    李凯,孟志勇,吉婧,等.四川盆地涪陵地区五峰-龙马溪组解吸气特征及影响因素分析[J].石油实验地质,2018,40(1):90-96.

    LI Kai,MENG Zhiyong,JI Jing,et al.Characteristics and influencing factors of desorption gas in Wufeng-Longmaxi formations in Fuling area,Sichuan Basin[J].Petroleum Geology & Experiment,2018,40(1):90-96.
    [10]
    赵省民,邓坚,饶竹,等.漠河盆地浅部气体特征及对天然气水合物形成的意义[J].石油学报,2018,39(3):266-277.

    ZHAO Xingmin,DENG Jian,RAO Zhu,et al.Shallow gas characteristics in Mohe Basin,Northeast China and its significance to gas hydrate formation[J].Acta Petrolei Sinica,2018,39(3):266-277.
    [11]
    史江龙,李剑,史海龙,等.四川盆地高石梯-磨溪地区震旦系-寒武系天然气的地球化学特征及成因[J].西安石油大学学报(自然科学版),2017,32(1):1-7. SHI Jianglong,LI Jian,SHI Hailong,et al.Geochemical characteristics and genesis of Sinian-Cambrian natural gas in Gaoshiti-Moxi region,Sichuan Basin[J].Journal of Xi'an Shiyou University (Natural Science Edition),2017,32(1):1-7.
    [12]
    WANG Xibin,LI Zhongping,XING Lantian,et al.Development of a new method for hydrogen isotope analysis of trace hydrocarbons in natural gas samples[J].Journal of Natural Gas Geoscience,2016,1(6):481-487.
    [13]
    秦胜飞,周国晓.气田水对甲烷氢同位素分馏作用[J].天然气地球科学,2018,29(3):311-316.

    QIN Shengfei,ZHOU Guoxiao.The effect of gas field water on hydrogen isotope fractionation of methane[J].Natural Gas Geoscience,2018,29(3):311-316.
    [14]
    雷知生,曹珺,刘坚,等.GC-IRMS测定白色块状天然气水合物气体中的碳氢同位素[J].化学分析计量,2015,24(1):23-27.

    LEI Zhisheng,CAO Jun,LIU Jian,et al.Measurement of stable carbon and hydrogen isotope in white massive natural gas hydrate by gas chromatography-isotope ratio mass spectrometry[J].Chemical Analysis and Meterage,2015,24(1):23-27.
    [15]
    刘全有,金之钧,刘文汇,等.四川盆地东部天然气地球化学特征与TSR强度对异常碳、氢同位素影响[J].矿物岩石地球化学通报,2015,34(3):471-480.

    LIU Quanyou,JIN Zhijun,LIU Wenhui,et al.TSR impact on abnormal carbon and hydrogen stable isotopes in sour natural gas from marine carbonate gas fields in the eastern Sichuan Basin[J].Bulletin of Mineralogy,Petrology and Geochemistry,2015,34(3):471-480.
    [16]
    倪春华,刘光祥,朱建辉,等.鄂尔多斯盆地杭锦旗地区上古生界天然气成因及来源[J].石油实验地质,2018,40(2):193-199.

    NI Chunhua,LIU Guangxiang,ZHU Jianhui,et al.Origin and source of natural gas in the Upper Paleozoic in Hangjinqi area,Ordos Basin[J].Petroleum Geology & Experiment,2018,40(2):193-199.
    [17]
    王希彬,李中平,张铭杰,等.固相微萃取-气相色谱-同位素质谱法测定天然气中微量烃类单分子氢同位素组成[J].天然气地球科学,2016,27(6):1084-1091.

    WANG Xibin,LI Zhongping,ZHANG Mingjie,et al.Compound-specific hydrogen isotope analysis for trace hydrocarbons in natural gas by using solid phase micro-extraction coupled to gas chromatography-isotope ratio mass spectrometry[J].Natural Gas Geoscience,2016,27(6):1084-1091.
    [18]
    HILKERT A W,DOUTHITT C B,SCHLÜTER H,et al.Isotope ratio monitoring gas chromatography/mass spectrometry of D/H by high temperature conversion isotope ratio mass spectrometry[J].Rapid Communications in Mass Spectrometry,1999,13(13):1226-1230.
    [19]
    CAO Yunning,LIU Weiguo,SAUER P E,et al.An evaluation of alumina reaction tube conditioning for high-precision 2H/1H isotope measurements via gas chromatography/thermal conversion/isotope ratio mass spectrometry[J].Rapid Communications in Mass Spectrometry,2012,26(22):2577-2583.
    [20]
    BILKE S,MOSANDL A.Measurements by gas chromatography/pyrolysis/mass spectrometry:fundamental conditions in 2H/1H isotope ratio analysis[J].Rapid Communications in Mass Spectrometry,2002,16(5):468-472.
    [21]
    GEHRE M,RENPENNING J,GILEVSKA T,et al.On-line hydrogen-isotope measurements of organic samples using elemental chro-mium:an extension for high temperature elemental-analyzer techniques[J].Analytical Chemistry,2015,87(10):5198-5205.
    [22]
    RENPENNING J,KÜMMEL S,HITZFELD K L,et al.Compound-specific hydrogen isotope analysis of heteroatom-bearing compounds via gas chromatography-chromium-based high-temperature conversion (Cr/HTC)-isotope ratio mass spectrometry[J].Analytical Chemistry,2015,87(18):9443-9450.
    [23]
    GRUEN D S,WANG D T,KÖNNEKE M,et al.Experimental investigation on the controls of clumped isotopologue and hydrogen isotope ratios in microbial methane[J].Geochimica et Cosmochimica Acta,2018,237:339-356.
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