Volume 42 Issue 3
May  2020
Turn off MathJax
Article Contents
ZHANG Guangrong, NIE Haikuan, TANG Xuan, DU Wei, SUN Chuanxiang, CHEN Song. Pyrite type and its effect on shale gas accumulation: a case study of Wufeng-Longmaxi shale in Sichuan Basin and its periphery[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2020, 42(3): 459-466. doi: 10.11781/sysydz202003459
Citation: ZHANG Guangrong, NIE Haikuan, TANG Xuan, DU Wei, SUN Chuanxiang, CHEN Song. Pyrite type and its effect on shale gas accumulation: a case study of Wufeng-Longmaxi shale in Sichuan Basin and its periphery[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2020, 42(3): 459-466. doi: 10.11781/sysydz202003459

Pyrite type and its effect on shale gas accumulation: a case study of Wufeng-Longmaxi shale in Sichuan Basin and its periphery

doi: 10.11781/sysydz202003459
  • Received Date: 2019-11-06
  • Rev Recd Date: 2020-03-26
  • Publish Date: 2020-05-28
  • Pyrite is one of the most common minerals in shale, but its type, genesis and effect on shale gas accumulation are still in the initial study stage. The shale in the Upper Ordovician Wufeng Formation and the Lower Silurian Longmaxi Formation in the Sichuan Basin and its periphery was studied. Strawberry-like, stratified, tuberculosis, euhedral and anhedral pyrites were identified through thin section observation, scanning electronic microscopy analyses. The pyrites in the Wufeng-Longmaxi formations are mainly developed during the syngenetic and early diagenetic stages. The strawberry-like pyrites are formed in the syngenetic stage, indicating a reducing environment, which is conducive for organic matter enrichment and preservation. The pyrite content has a positive correlation with the organic carbon content. The layers with a high content of pyrites are usually rich in organic matter. Strawberry-like pyrites, together with biogenic quartz and terrestrial detrital quartz, formed a rigid particle grid supporting the original intergranular pores, which was beneficial to hydrocarbon charging, preservation and organic matter-hosted pore development. The bottom of the Wufeng -Longmaxi shale with well developed strawberry-like pyrite in the Sichuan Basin and its periphery, indicate it not only has a good condition for organic matter enrichment, but also is conducive to the formation of high-quality shale gas reservoirs. The strawberry-like pyrite content can be used as a clue for identifying shale gas "sweet spots".

     

  • loading
  • [1]
    蒲泊伶, 董大忠, 耳闯, 等. 川南地区龙马溪组页岩有利储层发育特征及其影响因素[J]. 天然气工业, 2013, 33(12): 41-47. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG201312006.htm

    PU Boling, DONG Dazhong, ER Chuang, et al. Favorable reservoir characteristics of the Longmaxi shale in the southern Sichuan Basin and their influencing factors[J]. Natural Gas Industry, 2013, 33(12): 41-47. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG201312006.htm
    [2]
    刘国恒, 翟刚毅, 邹才能, 等. 鄂尔多斯盆地延长组泥页岩硅质来源与油气富集[J]. 石油实验地质, 2019, 41(1): 45-55. doi: 10.11781/sysydz201901045

    LIU Guodong, ZHAI Gangyi, ZOU Caineng, et al. Silicon sources and hydrocarbon accumulation in shale, Triassic Yanchang Formation, Ordos Basin[J]. Petroleum Geology & Experiment, 2019, 41(1): 45-55. doi: 10.11781/sysydz201901045
    [3]
    何顺, 秦启荣, 周吉羚, 等. 川东南DS地区龙马溪组页岩气形成及富集控制因素[J]. 特种油气藏, 2018, 25(6): 70-76. doi: 10.3969/j.issn.1006-6535.2018.06.013

    HE Shun, QIN Qirong, ZHOU Jiling, et al. Shale gas generation and enrichment in the Longmaxi Formation of DS, southeast Sichuan[J]. Special Oil & Gas Reservoirs, 2018, 25(6): 70-76. doi: 10.3969/j.issn.1006-6535.2018.06.013
    [4]
    郭彤楼. 页岩气勘探开发中的几个地质问题[J]. 油气藏评价与开发, 2019, 9(5): 14-19. https://www.cnki.com.cn/Article/CJFDTOTAL-KTDQ201905002.htm

    GUO Tonglou. A few geological issues in shale gas exploration and development[J]. Reservoir Evaluation and Development, 2019, 9(5): 14-19. https://www.cnki.com.cn/Article/CJFDTOTAL-KTDQ201905002.htm
    [5]
    易积正, 王超. 四川盆地焦石坝地区龙马溪组海相页岩储层非均质性特征[J]. 石油实验地质, 2018, 40(1): 13-19. doi: 10.11781/sysydz201801013

    YI Jizheng, WANG Chao. Differential pore development characteristics in various shale lithofacies of Longmaxi Formation in Jiaoshiba area, Sichuan Basin[J]. Petroleum Geology & Experiment, 2018, 40(1): 13-19. doi: 10.11781/sysydz201801013
    [6]
    LOUCKS R G, REED R M, RUPPEL S C, et al. Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrock pores[J]. AAPG Bulletin, 2012, 96(6): 1071-1098. doi: 10.1306/08171111061
    [7]
    WILKIN R T, BARNES H L, BRANTLEY S L. The size distribution of framboidal pyrite in modern sediments: an indicator of redox conditions[J]. Geochimica et Cosmochimica Acta, 1996, 60(20): 209-216.
    [8]
    ZHU Dongya, LIU Quanyou, ZHOU Bing, et al. Sulfur isotope of pyrite response to redox chemistry in organic matter-enriched shales and implications for components of shale gas[J]. Interpretation, 2018, 6(4): 1-43.
    [9]
    徐祖新, 韩淑敏, 王启超. 中扬子地区陡山沱组页岩储层中黄铁矿特征及其油气意义[J]. 岩性油气藏, 2015, 27(2): 31-37. https://www.cnki.com.cn/Article/CJFDTOTAL-YANX201502007.htm

    XU Zuxin, HAN Shumin, WANG Qichao. Characteristics of pyrite and its hydrocarbon significance of shale reservoir of Doushantuo Formation in middle Yangtze area[J]. Lithologic Reservoirs, 2015, 27(2): 31-37. https://www.cnki.com.cn/Article/CJFDTOTAL-YANX201502007.htm
    [10]
    SHILEY R H, CLUFF R M, DICKERSON D R, et al. Correlation of natural gas content to iron species in the New Albany shale group[J]. Fuel, 1981, 60(8): 732-738. doi: 10.1016/0016-2361(81)90228-3
    [11]
    聂海宽, 金之钧, 马鑫, 等. 四川盆地及邻区上奥陶统五峰组-下志留统龙马溪组底部笔石带及沉积特征[J]. 石油学报, 2017, 38(2): 160-174. https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB201702004.htm

    NIE Haikuan, JIN Zhijun, MA Xin, et al. Graptolites zone and sedimentary characteristics of Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation in Sichuan Basin and its adjacent areas[J]. Acta Petrolei Sinica, 2017, 38(2): 160-174. https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB201702004.htm
    [12]
    张崇瑞, 倪冬, 庄登登, 等. 柿庄南3~#煤储层渗透率特征及其控制因素[J]. 内蒙古石油化工, 2019, 45(2): 37-38. https://www.cnki.com.cn/Article/CJFDTOTAL-NMSH201902014.htm

    ZHANG Chongrui, NI Dong, ZHUANG Dengdeng, et al. Characteristics of permeability for 3~# coal reservoir in south Shizhuang and its control factors[J]. Inner Mongolia Petrochemical Industry, 2019, 45(2): 37-38. https://www.cnki.com.cn/Article/CJFDTOTAL-NMSH201902014.htm
    [13]
    李建忠, 董大忠, 陈更生, 等. 中国页岩气资源前景与战略地位[J]. 天然气工业, 2009, 29(5): 11-16, 134. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG200905003.htm

    LI Jianzhong, DONG Dazhong, CHEN Gengsheng, et al. Prospects and strategic position of shale gas resources in China[J]. Natural Gas Industry, 2009, 29(5): 11-16, 134. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG200905003.htm
    [14]
    邓鑫, 康志宏, 彭媛媛, 等. 四川盆地南部五峰组页岩元素特征对古构造及古环境的指示意义[J]. 煤炭技术, 2018, 37(5): 131-133. https://www.cnki.com.cn/Article/CJFDTOTAL-MTJS201805051.htm

    DENG Xin, KANG Zhihong, PENG Yuanyuan, et al. Element characteristics of shale in Wufeng Formation in southern Sichuan Basin indicating significance of paleo-tectonic and Paleoenvironment[J]. Coal Technology, 2018, 37(5): 131-133. https://www.cnki.com.cn/Article/CJFDTOTAL-MTJS201805051.htm
    [15]
    李丹, 欧成华, 马中高, 等. 黄铁矿与页岩的相互作用及其对页岩气富集与开发的意义[J]. 石油物探, 2018, 57(3): 332-343. https://www.cnki.com.cn/Article/CJFDTOTAL-SYWT201803003.htm

    LI Dan, OU Chenghua, MA Zhonggao, et al. Pyrite-shale interaction in shale gas enrichment and development[J]. Geophysical Prospecting for Petroleum, 2018, 57(3): 332-343. https://www.cnki.com.cn/Article/CJFDTOTAL-SYWT201803003.htm
    [16]
    刘子驿. 湘鄂西五峰-龙马溪组黄铁矿成因及其页岩气意义[D]. 北京: 中国地质大学(北京), 2017.

    LIU Ziyi. Shale gas significance of pyrite in Wufeng-Longmaxi formations, case study in western Hunan and Hubei[D]. Beijing: China University of Geosciences (Beijing), 2017.
    [17]
    赵迪斐, 郭英海, 朱炎铭, 等. 龙马溪组页岩黄铁矿微观赋孔特征及地质意义[J]. 沉积学报, 2018, 36(5): 864-876. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB201805002.htm

    ZHAO Difei, GUO Yinghai, ZHU Yanming, et al. Micropore characteristics and geological significance of pyrite in shale rocks of Longmaxi Formation[J]. Acta Sedimentologica Sinica, 2018, 36(5): 864-876. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB201805002.htm
    [18]
    RAISWELL R, BERNER R A. Pyrite formation in euxinic and semi-euxinic sediments[J]. American Journal of Science, 1985, 285(8): 710-724.
    [19]
    BOND D P G, WIGNALL P B. Pyrite framboid study of marine Permian-Triassic boundary sections: a complex anoxic event and its relationship to contemporaneous mass extinction[J]. Geological Society of America Bulletin, 2010, 122(7-8): 1265-1279.
    [20]
    王晓洁, 张世奇, 魏孟吉, 等. 东濮凹陷文东地区沙三段黄铁矿特征及形成模式[J]. 断块油气田, 2015, 22(2): 178-183. https://www.cnki.com.cn/Article/CJFDTOTAL-DKYT201502009.htm

    WANG Xiaojie, ZHANG Shiqi, WEI Mengji, et al. Characte-ristics and formation mode of Es3 Member pyrite in Wendong area of Dongpu Depression[J]. Fault-Block Oil & Gas Field, 2015, 22(2): 178-183. https://www.cnki.com.cn/Article/CJFDTOTAL-DKYT201502009.htm
    [21]
    张鑫. 硫酸盐还原菌还原分解硫酸盐矿物的机制及环境意义[D]. 合肥: 合肥工业大学, 2015.

    ZHANG Xin. Mechanism and environmental significance of the decomposition of sulfate-reduction bacterium[D]. Hefei: Hefei Polytechnic University, 2015.
    [22]
    聂海宽, 张金川. 页岩气储层类型和特征研究: 以四川盆地及其周缘下古生界为例[J]. 石油实验地质, 2011, 33(3): 219-225, 232. https://www.cnki.com.cn/Article/CJFDTOTAL-SYSD201103003.htm

    NIE Haikuan, ZHANG Jinchuan. Types and characteristics of shale gas reservoir: a case study of Lower Paleozoic in and around Sichuan Basin[J]. Petroleum Geology & Experiment, 2011, 33(3): 219-225, 232. https://www.cnki.com.cn/Article/CJFDTOTAL-SYSD201103003.htm
    [23]
    RAISWELL R. Pyrite texture, isotopic composition and the availability of iron[J]. American Journal of Science, 1982, 282(8): 1244-1263.
    [24]
    帅德权, 胡晓强. 陕西二台子-半仓沟金矿的黄铁矿海绵结构[J]. 黄金地质, 1996, (2): 71-73. https://www.cnki.com.cn/Article/CJFDTOTAL-HJDZ602.013.htm

    SHUAI Dequan, HU Xiaoqiang. Sponge structure of pyrite in Ertaizi-Bancanggou Gold Deposit, Shaanxi province[J]. Gold Geology. 1996, (2): 71-73. https://www.cnki.com.cn/Article/CJFDTOTAL-HJDZ602.013.htm
    [25]
    张林晔, 李钜源, 李政, 等. 湖相页岩有机储集空间发育特点与成因机制[J]. 地球科学(中国地质大学学报), 2015, 40(11): 1824-1833. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201511005.htm

    ZHANG Linye, LI Juyuan, LI Zheng, et al. Development characte-ristics and formation mechanism of intra-organic reservoir space in lacustrine shales[J]. Earth Science(Journal of China University of Geosciences), 2015, 40(11): 1824-1833. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201511005.htm
    [26]
    程超, 林海宇, 蒋裕强, 等. 川南龙马溪组含气页岩热导率实验研究[J]. 石油实验地质, 2019, 41(2): 289-294. doi: 10.11781/sysydz201103219

    CHENG Chao, LIN Haiyu, JIANG Yuqiang, et al. Thermal conductivity of gas-bearing shale of the Longmaxi Formation in the southern Sichuan[J]. Petroleum Geology & Experiment, 2019, 41(2): 289-294. doi: 10.11781/sysydz201103219
    [27]
    舒丽娟. 奈曼凹陷九佛堂组非烃流体地质意义及控制因素[J]. 岩性油气藏, 2015, 27(3): 75-81. https://www.cnki.com.cn/Article/CJFDTOTAL-YANX201503012.htm

    SHU Lijuan. Geological significance and controlling factors of nonhydrocarbon fluid of Jiufotang Formation in Naiman Sag[J]. Lithologic Reservoirs, 2015, 27(3): 75-81. https://www.cnki.com.cn/Article/CJFDTOTAL-YANX201503012.htm
    [28]
    孙川翔, 聂海宽, 刘光祥, 等. 石英矿物类型及其对页岩气富集开采的控制: 以四川盆地及其周缘五峰组-龙马溪组为例[J]. 地球科学, 2019, 44(11): 1-16. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201911009.htm

    SUN Chuanxiang, NIE Haikuan, LIU Guangxiang, et al. Quartz type and its control on shale gas enrichment and production: a case study of the Wufeng-Longmaxi formations in the Sichuan Basin and its surrounding areas, China[J]. Earth Science, 2019, 44(11): 1-16. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201911009.htm
    [29]
    刘霜, 钱华, 张梦吟, 等. 四川盆地涪陵页岩气田五峰-龙马溪组岩矿纵向差异性研究: 以JYA井为例[J]. 石油实验地质, 2018, 40(1): 64-70. doi: 10.11781/sysydz201801064

    LIU Shuang, QIAN Hua, ZHANG Mengyin, et al. Vertical variation of rocks and minerals in Wufeng-Longmaxi formations in Fuling shale gas field, Sichuan Basin: a case study of well JYA[J]. Petroleum Geology & Experiment, 2018, 40(1): 64-70. doi: 10.11781/sysydz201801064
    [30]
    赖富强, 冷寒冰, 龚大建, 等. 综合矿物组分和弹性力学参数的页岩脆性评价方法[J]. 断块油气田, 2019, 26(2): 168-171, 186. https://www.cnki.com.cn/Article/CJFDTOTAL-DKYT201902008.htm

    LAI Fuqiang, LENG Hanbing, GONG Dajian, et al. Evaluation of shale brittleness based on mineral compositions and elastic mechanics parameters[J]. Fault-Block Oil & Gas Field, 2019, 26(2): 168-171, 186. https://www.cnki.com.cn/Article/CJFDTOTAL-DKYT201902008.htm
    [31]
    刘尧文, 王进, 张梦吟, 等. 四川盆地涪陵地区五峰-龙马溪组页岩气层孔隙特征及对开发的启示[J]. 石油实验地质, 2018, 40(1): 44-50. doi: 10.11781/sysydz201801044

    LIU Yaowen, WANG Jin, ZHANG Mengyin, et al. Pore features of shale gas layer in Wufeng-Longmaxi formations in Fuling area of Sichuan Basin and the application to development[J]. Petroleum Geology & Experiment, 2018, 40(1): 44-50. doi: 10.11781/sysydz201801044
    [32]
    朱联强, 袁海峰, 林雪梅, 等. 四川盆地安岳构造寒武系龙王庙组成岩矿物充填期次及油气成藏[J]. 石油实验地质, 2019, (6): 812-820. doi: 10.11781/sysydz201906812

    ZHU Lianqiang, YUAN Haifeng, LIN Xuemei, et al. Diagenesis and hydrocarbon accumulation of the Cambrian Longwangmiao Formation in Anyue, Sichuan Basin[J]. Petroleum Geology & Experiment, 2019, (6): 812-820. doi: 10.11781/sysydz201906812
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(9)  / Tables(1)

    Article Metrics

    Article views (957) PDF downloads(180) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return