Volume 44 Issue 2
Mar.  2022
Turn off MathJax
Article Contents
YANG Xi, BAO Jianping, NI Chunhua, ZHU Cuishan. Effect of evaporative fractionation on the distribution and composition of diamondoids in crude oils: a case study of crude oils from Yangtake structure, Kuqa Depression, Tarim Basim[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2022, 44(2): 295-305. doi: 10.11781/sysydz202202295
Citation: YANG Xi, BAO Jianping, NI Chunhua, ZHU Cuishan. Effect of evaporative fractionation on the distribution and composition of diamondoids in crude oils: a case study of crude oils from Yangtake structure, Kuqa Depression, Tarim Basim[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2022, 44(2): 295-305. doi: 10.11781/sysydz202202295

Effect of evaporative fractionation on the distribution and composition of diamondoids in crude oils: a case study of crude oils from Yangtake structure, Kuqa Depression, Tarim Basim

doi: 10.11781/sysydz202202295
  • Received Date: 2021-08-09
  • Rev Recd Date: 2022-01-05
  • Publish Date: 2022-03-28
  • Two sets of crude oil samples from the Yangtake structure in the Kuqa Depression of Tarim Basin were analyzed with the aid of GC and GC-MS to evaluate the effect of evaporative fractionation on the distribution and composition of diamondoid hydrocarbon in crude oils. The light hydrocarbon signatures of oils from wells YT 5 and YT 101 indicate secondary products of evaporative fractionation for the condensates from the upper reservoirs, and the oils from the lower reservoirs are residuals. Moreover, the distribution and composition of steranes and terpanes in two sets of crude oils appeared to be comparable, suggesting that these oils shared a same source. Evaporative fractionation has imperceptible effect on the distribution and relative abundance of alkyl admantanes and diamantanes, but their concentrations in secondary condensates and residual oils appeared to be significantly varied. For example, the concentration of diamondoids in secondary condensates is much higher than that in residual oils, and the increasing extent of concentration for alkyl admantanes in secondary condensates is much higher than that in residual oils. Therefore, it should be very cautious to use the concentration of diamondoids to determine the degree of maturity of crude oils if evaporative fractionation occurred. However, the effect caused by evaporative fractionation to the maturity parameters such as MAI and MDI is relatively minor and they can still be used as indicators to evaluate maturity of crude oils even with the alteration of evaporative fractionation.

     

  • loading
  • [1]
    梁狄刚, 陈建平, 张宝民, 等. 塔里木盆地库车坳陷陆相油气的生成[M]. 北京: 石油工业出版社, 2004: 142-202.

    LIANG Digang, CHEN Jianping, ZHANG Baomin, et al. Generation of nonmarine oil and gas in the Kuqa Depression of the Tarim Basin[M]. Beijing: Petroleum Industry Press, 2004: 142-202.
    [2]
    LIANG Digang, ZHANG Shuichang, CHEN Jianping, et al. Organic geochemistry of oil and gas in the Kuqa Depression, Tarim Basin, NW China[J]. Organic Geochemistry, 2003, 34(7): 873-888. doi: 10.1016/S0146-6380(03)00029-9
    [3]
    THOMPSON K F M. Fractionated aromatic petroleums and the generation of gas-condensates[J]. Organic Geochemistry, 1987, 11(6): 573-590. doi: 10.1016/0146-6380(87)90011-8
    [4]
    THOMPSON K F M. Gas-condensate migration and oil fractionation in deltaic systems[J]. Marine and Petroleum Geology, 1988, 5(3): 237-246. doi: 10.1016/0264-8172(88)90004-9
    [5]
    THOMPSON K F M. Aspects of petroleum basin evolution due to gas advection and evaporative fractionation[J]. Organic Geochemistry, 2010, 41(4): 370-385. doi: 10.1016/j.orggeochem.2009.12.005
    [6]
    VAN GRAAS G W, GILJE A E, ISOM T P, et al. The effects of phase fractionation on the composition of oils, condensates and gases[J]. Organic Geochemistry, 2000, 31(12): 1419-1439. doi: 10.1016/S0146-6380(00)00128-5
    [7]
    王秀红, 陈涛, 李政, 等. 济阳坳陷滩海地区埕北斜394井凝析油气特征及形成机制[J]. 油气地质与采收率, 2021, 28(3): 35-41. https://www.cnki.com.cn/Article/CJFDTOTAL-YQCS202103005.htm

    WANG Xiuhong, CHEN Tao, LI Zheng, et al. Characteristics and formation mechanism of condensate oil and gas from well CBX394 in Jiyang Depression[J]. Petroleum Geology and Recovery Efficiency, 2021, 28(3): 35-41. https://www.cnki.com.cn/Article/CJFDTOTAL-YQCS202103005.htm
    [8]
    房忱琛, 翟佳, 胡国艺, 等. 凝析油中金刚烷类和硫代金刚烷类化合物同步检测方法及地质意义: 以塔里木盆地塔中地区凝析油为例[J]. 石油实验地质, 2021, 43(5): 906-914. doi: 10.11781/sysydz202105906

    FANG Chenchen, ZHAI Jia, HU Guoyi, et al. A simultaneous determination method for diamondoids and thiadiamondoids in condensate oil and its geological significance: taking condensate oil from central Tarim Basin as an example[J]. Petroleum Geology & Experiment, 2021, 43(5): 906-914. doi: 10.11781/sysydz202105906
    [9]
    黄凌, 翁娜, 魏彩云, 等. 利用不同质谱技术分析鉴定金刚烷类化合物[J]. 石油实验地质, 2020, 42(6): 1024-1030. doi: 10.11781/sysydz2020061024

    HUANG Ling, WENG Na, WEI Caiyun, et al. Analysis and identification of diamondoids by different mass spectrometry techniques[J]. Petroleum Geology & Experiment, 2020, 42(6): 1024-1030. doi: 10.11781/sysydz2020061024
    [10]
    翟佳, 房忱琛, 胡国艺, 等. 烃源岩前处理过程对金刚烷类化合物定量分析的影响[J]. 天然气地球科学, 2019, 30(2): 295-304. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201902017.htm

    ZHAI Jia, FANG Chenchen, HU Guoyi, et al. Effect of source rock pretreatment on diamondoid quantitative analysis[J]. Natural Gas Geoscience, 2019, 30(2): 295-304. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201902017.htm
    [11]
    马安来, 朱翠山, 顾忆, 等. 塔中地区中深1C井寒武系原油低聚硫代金刚烷含量分析[J]. 天然气地球科学, 2018, 29(7): 1009-1019. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201807011.htm

    MA Anlai, ZHU Cuishan, GU Yi, et al. Concentrations analysis of lower thiadiamondoids of Cambrian oil from well Zhongshen 1C of Tazhong Uplift, Tarim Basin, NW China[J]. Natural Gas Geoscience, 2018, 29(7): 1009-1019. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201807011.htm
    [12]
    张坤, 唐友军, 胡森清, 等. 平湖斜坡带原油中金刚烷的检出及其地球化学意义[J]. 石油天然气学报, 2014, 36(10): 30-34. https://www.cnki.com.cn/Article/CJFDTOTAL-JHSX201410007.htm

    ZHANG Kun, TANG Youjun, HU Senqing, et al. Detection of adamantane in crude oil in Pinghu slope zone and its geochemical significance[J]. Journal of Oil and Gas Technology, 2014, 36(10): 30-34. https://www.cnki.com.cn/Article/CJFDTOTAL-JHSX201410007.htm
    [13]
    CHEN Junhong, FU Jiamo, SHENG Guoying, et al. Diamondoid hydrocarbon ratios: novel maturity indices for highly mature crude oils[J]. Organic Geochemistry, 1996, 25(3/4): 179-190.
    [14]
    WEI Zhibin, MOLDOWAN J M, ZHANG Shuichang, et al. Diamondoid hydrocarbons as a molecular proxy for thermal maturity and oil cracking: geochemical models from hydrous pyrolysis[J]. Organic Geochemistry, 2007, 38(2): 227-249.
    [15]
    郭小文, 何生, 陈红汉. 甲基双金刚烷成熟度指标讨论与应用[J]. 地质科技情报, 2007, 26(1): 71-76. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ200701012.htm

    GUO Xiaowen, HE Sheng, CHEN Honghan. Discussion and application of the maturity indicators of methyl double diamantane hydrocarbons[J]. Geological Science and Technology Information, 2007, 26(1): 71-76. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ200701012.htm
    [16]
    李景贵, 崔明中, 张谦. 双金刚烷指标作为下古生界高、过成熟阶段碳酸盐岩成熟度衡量标尺的讨论[J]. 石油勘探与开发, 1998, 25(2): 83-85. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK802.024.htm

    LI Jinggui, CUI Mingzhong, ZHANG Qian. A discussion about diamantane ratios as maturity indicators of Lower Paleozoic carbonate source rocks at high and over mature stages[J]. Petroleum Exploration and Development, 1998, 25(2): 83-85. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK802.024.htm
    [17]
    包建平, 倪春华, 朱翠山, 等. 黔北坳陷高演化海相烃源岩中金刚烷类化合物及其意义[J]. 地球化学, 2021, 50(2): 133-151. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX202102001.htm

    BAO Jianping, NI Chunhua, ZHU Cuishan, et al. Diamondoid hydrocarbons in highly mature marine source rocks from the North Guizhou Depression[J]. Geochimica, 2021, 50(2): 133-151. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX202102001.htm
    [18]
    马万云, 李二庭, 蒋文敏, 等. 准噶尔盆地南缘原油金刚烷分布特征[J]. 地质论评, 2017, 63(S1): 385-386. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP2017S1185.htm

    MA Wanyun, LI Erting, JIANG Wenmin, et al. Distribution characte-ristics of adamantane in crude oil on the southern margin of theJunggar Basin[J]. Geological Review, 2017, 63(S1): 385-386. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP2017S1185.htm
    [19]
    包建平, 朱翠山, 申旭. 金刚烷类化合物与库车坳陷克拉2构造凝析油的形成机理研究[J]. 天然气地球科学, 2018, 29(9): 1217-1230. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201809001.htm

    BAO Jianping, ZHU Cuishan, SHEN Xu. Study on diamondoids and genetic mechanism of condensates from the Kela 2 structure in the Kuche Depression[J]. Natural Gas Geoscience, 2018, 29(9): 1217-1230. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201809001.htm
    [20]
    包建平, 梁星宇, 朱翠山, 等. 苏北盆地盐城凹陷朱家墩气藏凝析油中的金刚烷类及其意义[J]. 天然气地球科学, 2015, 26(3): 505-512. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201503013.htm

    BAO Jianping, LIANG Xingyu, ZHU Cuishan, et al. Diamondoid hydrocarbons and their geochemical significances in condensate from the Zhujiadun gas reservoir in the Yancheng Sag[J]. Natural Gas Geoscience, 2015, 26(3): 505-512. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201503013.htm
    [21]
    包建平, 汪立群, 朱翠山, 等. 柴达木盆地开特米里克油田凝析油成因研究: 基于金刚烷烃类化合物[J]. 天然气地球科学, 2016, 27(2): 330-340. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201602016.htm

    BAO Jianping, WANG Liqun, ZHU Cuishan, et al. Origin of the condensates from Kaitemilike Oilfield in the western Qaidam Basin: diamondoid hydrocarbons[J]. Natural Gas Geoscience, 2016, 27(2): 330-340. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201602016.htm
    [22]
    DAHL J E, MOLDOWAN J M, PETERS K E, et al. Diamondoid hydrocarbons as indicators of natural oil cracking[J]. Nature, 1999, 399(6731): 54-57.
    [23]
    FANG Chenchen, XIONG Yongqiang, LIANG Qianyong, et al. Variation in abundance and distribution of diamondoids during oil cracking[J]. Organic Geochemistry, 2012, 47: 1-8.
    [24]
    李素梅, 庞雄奇, 杨海军, 等. 塔中Ⅰ号坡折带高熟油气地球化学特征及其意义[J]. 石油与天然气地质, 2008, 29(2): 210-216. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT200802008.htm

    LI Sumei, PANG Xiongqi, YANG Haijun, et al. Geochemical characteristics and implication of high thermal maturity oils in Tazhong- I faulted slope break zone[J]. Oil & Gas Geology, 2008, 29(2): 210-216. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT200802008.htm
    [25]
    包建平, 斯春松, 蒋兴超, 等. 黔北坳陷小草坝古油藏储层沥青来源与成因研究[J]. 地球化学, 2016, 45(3): 315-328. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX201603007.htm

    BAO Jianping, SI Chunsong, JIANG Xingchao, et al. Study on origin and source of solid bitumen from the Xiaocaoba paleo-reservoir in the northern Guizhou Depression[J]. Geochimica, 2016, 45(3): 315-328. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX201603007.htm
    [26]
    张水昌, 赵文智, 王飞宇, 等. 塔里木盆地东部地区古生界原油裂解气成藏历史分析: 以英南2气藏为例[J]. 天然气地球科学, 2004, 15(5): 441-451. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX200405001.htm

    ZHANG Shuichang, ZHAO Wenzhi, WANG Feiyu, et al. Paleozoic oil cracking gas accumulation history from eastern part of the Tarim Basin: a case study of the YN2 gas reservoir[J]. Natural Gas Geoscience, 2004, 15(5): 441-451. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX200405001.htm
    [27]
    LI Yun, XIONG Yongqiang, CHEN Yuan, et al. The effect of evaporation on the concentration and distribution of diamondoids in oils[J]. Organic Geochemistry, 2014, 69(4): 88-97.
    [28]
    CHAKHMAKHCHEV A, SANDERSON J, PEARSON C, et al. Compositional changes of diamondoid distributions caused by simulated evaporative fractionation[J]. Organic Geochemistry, 2017, 113: 224-228.
    [29]
    ZHU Xinjian, CHEN Jianfa, ZHANG Chao, et al. Effects of evaporative fractionation on diamondoid hydrocarbons in condensates from the Xihu Sag, East China Sea Shelf Basin[J]. Marine and Petroleum Geology, 2021, 126: 104929.
    [30]
    包建平, 朱翠山, 张秋茶, 等. 库车坳陷前缘隆起带上原油地球化学特征[J]. 石油天然气学报, 2007, 29(4): 40-44. https://www.cnki.com.cn/Article/CJFDTOTAL-JHSX200704006.htm

    BAO Jianping, ZHU Cuishan, ZHANG Qiucha, et al. Geochemical characteristics of crude oil from Frontal Uplift in Kuqa Depression[J]. Journal of Oil and Gas Technology, 2007, 29(4): 40-44. https://www.cnki.com.cn/Article/CJFDTOTAL-JHSX200704006.htm
    [31]
    包建平, 朱翠山, 张秋茶, 等. 塔里木盆地库车坳陷不同构造单元天然气地球化学特征[J]. 石油与天然气地质, 2007, 28(5): 664-668, 674. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT200705020.htm

    BAO Jianping, ZHU Cuishan, ZHANG Qiucha, et al. Geochemical characteristics of natural gas from different structural units of the Kuqa Depression, the Tarim Basin[J]. Oil & Gas Geology, 2007, 28(5): 664-668, 674. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT200705020.htm
    [32]
    苏洲, 张慧芳, 韩剑发, 等. 塔里木盆地库车坳陷中、新生界高蜡凝析油和轻质油形成及其控制因素[J]. 石油与天然气地质, 2018, 39(6): 1255-1269. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201806016.htm

    SU Zhou, ZHANG Huifang, HAN Jianfa, et al. Origin and controlling factors of Mesozoic-Cenozoic gas condensates with high wax content and high-gravity oil in Kuqa Depression[J]. Oil & Gas Geology, 2018, 39(6): 1255-1269. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201806016.htm
    [33]
    梁狄刚, 顾乔元, 皮学军. 塔里木盆地塔北隆起凝析气藏的分布规律[J]. 天然气工业, 1998, 18(3): 5-9. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG803.001.htm

    LIANG Digang, GU Qiaoyuan, PI Xuejun. Distribution law of the condensate gas reservoirs in Tabei Uplift[J]. Natural Gas Industry, 1998, 18(3): 5-9. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG803.001.htm
    [34]
    刘建良, 姜振学, 刘可禹, 等. 库车前陆盆地羊塔克地区流体包裹体特征及油气成藏过程[J]. 地球科学, 2016, 41(7): 1188-1197. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201607008.htm

    LIU Jianliang, JIANG Zhenxue, LIU Keyu, et al. Fluid inclusion characteristics and hydrocarbon accumulation process of Yangtake area, Kuqa Foreland Basin[J]. Earth Science, 2016, 41(7): 1188-1197. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201607008.htm
    [35]
    刘全有, KROOSS B M, 刘文汇, 等. 应用CH4/N2指标估算塔里木盆地天然气热成熟度[J]. 地学前缘, 2008, 15(1): 209-216. https://www.cnki.com.cn/Article/CJFDTOTAL-DXQY200801028.htm

    LIU Quanyou, KROOSS B M, LIU Wenhui, et al. CH4/N2 ratio as a potential alternative geochemical tool to predict the thermal maturity of natural gas in Tarim Basin[J]. Earth Science Frontiers, 2008, 15(1): 209-216. https://www.cnki.com.cn/Article/CJFDTOTAL-DXQY200801028.htm
    [36]
    JIANG Wenmin, LI Yun, XIONG Yongqiang. The effect of organic matter type on formation and evolution of diamondoids[J]. Marine and Petroleum Geology, 2018, 89: 714-720.
    [37]
    SCHULZ L K, WILHELMS A, REIN E, et al. Application of diamondoids to distinguish source rock facies[J]. Organic Geochemistry, 2001, 32(3): 365-375.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(9)  / Tables(3)

    Article Metrics

    Article views (425) PDF downloads(46) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return