Volume 44 Issue 5
Sep.  2022
Turn off MathJax
Article Contents
WU Xiaoqi, ZHOU Xiaojin, CHEN Yingbin, WANG Ping, WANG Yanqing, YANG Jun, ZENG Huasheng. Molecular characteristics of source rocks in Upper Triassic Xujiahe Formation, Western Sichuan Depression, Sichuan Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2022, 44(5): 854-865. doi: 10.11781/sysydz202205854
Citation: WU Xiaoqi, ZHOU Xiaojin, CHEN Yingbin, WANG Ping, WANG Yanqing, YANG Jun, ZENG Huasheng. Molecular characteristics of source rocks in Upper Triassic Xujiahe Formation, Western Sichuan Depression, Sichuan Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2022, 44(5): 854-865. doi: 10.11781/sysydz202205854

Molecular characteristics of source rocks in Upper Triassic Xujiahe Formation, Western Sichuan Depression, Sichuan Basin

doi: 10.11781/sysydz202205854
  • Received Date: 2022-01-14
  • Rev Recd Date: 2022-08-09
  • Publish Date: 2022-09-28
  • The Upper Triassic Xujiahe Formation (T3x) is the most important terrigenous stratum in the Western Sichuan Depression; however, it is still insufficient for the understanding of molecular compositional characteristics of its source rocks. Based on the analysis of both saturated and aromatic fractions of extracts of source rocks from different members of the Xujiahe Formation, the indication is then discussed for sedimentary environment and thermal evolution of source rocks. The distribution of tricyclic terpanes (TTs) and dibenzothiophene/phenanthrene (DBT/P) ratio of the argillaceous source rocks in 2nd to 4th members of the Xujiahe Formation mainly display the signatures of typical lacustrine source rocks, and the relatively high gammacerane/C30 hopane (0.16-0.23), as well as 9-/1-methylphenanthrene (1.16-1.41) ratios suggest relatively high salinity of water body. The parameters such as methylphenanthrene index (MPI1), methylphenanthrene distribution fraction (F1), and methyldibenzothiophene distribution index (MDBI) are effective for the evaluation of thermal maturity, and they show positively and negatively linear correlation with maturity degree before and after Ro=1.35%. The distribution pattern of C27-C29 regular steranes, relative composition of three fluorine series, and methyldibenzothiophene/methyldibenzofuran ratios for high to over-maturity T3x source rocks are distorted due to the effect of thermal maturation.

     

  • loading
  • [1]
    DAI Jinxing, NI Yunyan, ZOU Caineng. Stable carbon and hydrogen isotopes of natural gases sourced from the Xujiahe Formation in the Sichuan Basin, China[J]. Organic Geochemistry, 2012, 43: 103-111. doi: 10.1016/j.orggeochem.2011.10.006
    [2]
    DAI Jinxing, NI Yunyan, ZOU Caineng, et al. Stable carbon isotopes of alkane gases from the Xujiahe coal measures and implication for gas-source correlation in the Sichuan Basin, SW China[J]. Organic Geochemistry, 2009, 40(5): 638-646. doi: 10.1016/j.orggeochem.2009.01.012
    [3]
    邹才能, 陶士振, 朱如凯, 等. "连续型"气藏及其大气区形成机制与分布: 以四川盆地上三叠统须家河组煤系大气区为例[J]. 石油勘探与开发, 2009, 36(3): 307-319. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK200903010.htm

    ZOU Caineng, TAO Shizhen, ZHU Rukai, et al. Formation and distribution of "continuous" gas reservoirs and their giant gas province: a case from the Upper Triassic Xujiahe Formation giant gas province, Sichuan Basin[J]. Petroleum Exploration and Development, 2009, 36(3): 307-319. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK200903010.htm
    [4]
    DAI Jinxing. Giant coal-derived gas fields and their gas sources in China[M]. Beijing: Science Press, 2016: 1-564.
    [5]
    WU Xiaoqi, LIU Quanyou, LIU Guangxiang, et al. Geochemical characteristics and genetic types of natural gas in the Xinchang gas field, Sichuan Basin, SW China[J]. Acta Geologica Sinica (English Edition), 2017, 91(6): 2200-2213. doi: 10.1111/1755-6724.13458
    [6]
    杨克明, 朱宏权. 川西叠覆型致密砂岩气区地质特征[J]. 石油实验地质, 2013, 35(1): 1-8. doi: 10.11781/sysydz201301001

    YANG Keming, ZHU Hongquan. Geological characteristics of superposed tight sandstone gas-bearing areas in western Sichuan[J]. Petroleum Geology & Experiment, 2013, 35(1): 1-8. doi: 10.11781/sysydz201301001
    [7]
    秦胜飞, 陶士振, 涂涛, 等. 川西坳陷天然气地球化学及成藏特征[J]. 石油勘探与开发, 2007, 34(1): 34-38. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK200701007.htm

    QIN Shengfei, TAO Shizhen, TU Tao, et al. Characteristics of natural gas geochemistry and accumulation in Western Sichuan Depression[J]. Petroleum Exploration and Development, 2007, 34(1): 34-38. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK200701007.htm
    [8]
    王玮, 沈忠民, 裴森奇, 等. 致密砂岩气藏油气轻烃特征及其地质意义: 以四川盆地西北部须家河组气藏为例[J]. 石油实验地质, 2018, 40(6): 818-827. doi: 10.11781/sysydz201806818

    WANG Wei, SHEN Zhongmin, PEI Senqi, et al. Light hydrocarbon characteristics of petroleum in a tight sandstone gas reservoir and its geological significance: a case study of the Upper Triassic Xujiahe Formation gas reservoir in the northwestern Sichuan Basin[J]. Petroleum Geology & Experiment, 2018, 40(6): 818-827. doi: 10.11781/sysydz201806818
    [9]
    吴小奇, 罗开平, 王萍, 等. 川西坳陷新场气田须家河组五段流体赋存状态[J]. 石油与天然气地质, 2017, 38(6): 1068-1078. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201706009.htm

    WU Xiaoqi, LUO Kaiping, WANG Ping, et al. Fluid state in the 5th member of the Upper Triassic Xujiahe Formation in the Xinchang gas field, Western Sichuan Depression in Sichuan Basin[J]. Oil & Gas Geology, 2017, 38(6): 1068-1078. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201706009.htm
    [10]
    吴小奇, 王萍, 潘文蕾, 等. 川西坳陷新场构造须五段地层水地球化学特征及其成因[J]. 天然气工业, 2016, 36(3): 22-29. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG201603006.htm

    WU Xiaoqi, WANG Ping, PAN Wenlei, et al. Geochemical cha-racteristics and origin of formation water in the 5th member of the Upper Triassic Xujiahe Fm in Xinchang structure, West Sichuan Depression[J]. Natural Gas Industry, 2016, 36(3): 22-29. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG201603006.htm
    [11]
    林小兵, 田景春, 刘莉萍, 等. 四川盆地川西坳陷须家河组硅质碎屑颗粒溶蚀作用及机理[J]. 石油实验地质, 2019, 41(3): 404-410. doi: 10.11781/sysydz201903404

    LIN Xiaobing, TIAN Jingchun, LIU Liping, et al. Dissolution mechanism of siliciclastic particles in Xujiahe Formation, West Sichuan Depression, Sichuan Basin[J]. Petroleum Geology & Experiment, 2019, 41(3): 404-410. doi: 10.11781/sysydz201903404
    [12]
    王东燕, 曾华盛, 王津义. 四川盆地川西坳陷中段上三叠统烃源岩评价[J]. 石油实验地质, 2010, 32(2): 192-195. doi: 10.11781/sysydz201002192

    WANG Dongyan, ZENG Huasheng, WANG Jinyi. Evaluation on Upper Triassic hydrocarbon source rocks of Western Sichuan Depression, Sichuan Basin[J]. Petroleum Geology & Experiment, 2010, 32(2): 192-195. doi: 10.11781/sysydz201002192
    [13]
    江兴歌, 曾华盛, 朱建辉, 等. 川西坳陷中部上三叠统烃源岩动态演化模拟[J]. 石油与天然气地质, 2012, 33(4): 545-551. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201204010.htm

    JIANG Xingge, ZENG Huasheng, ZHU Jianhui, et al. Dynamic evolution simulation of the Upper Triassic source rocks in central part of Western Sichuan Depression[J]. Oil & Gas Geology, 2012, 33(4): 545-551. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201204010.htm
    [14]
    吴小奇, 陈迎宾, 赵国伟, 等. 四川盆地川西坳陷新场气田上三叠统须家河组五段烃源岩评价[J]. 天然气地球科学, 2017, 28(11): 1714-1722. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201711011.htm

    WU Xiaoqi, CHEN Yingbin, ZHAO Guowei, et al. Evaluation of source rocks in the 5th member of the Upper Triassic Xujiahe Formation in the Xinchang Gasfield, the Western Sichuan Depression, Sichuan Basin[J]. Natural Gas Geoscience, 2017, 28(11): 1714-1722. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201711011.htm
    [15]
    马晓潇, 黎茂稳, 刘鹏, 等. 江汉盆地盐间页岩中芳基类异戊间二烯烷烃特征及对页岩油勘探的意义[J]. 石油实验地质, 2020, 42(4): 575-585. doi: 10.11781/sysydz202004575

    MA Xiaoxiao, LI Maowen, LIU Peng, et al. Aryl isoprenoids and their significance for inter-salt shale oil exploration in the Jianghan Basin[J]. Petroleum Geology & Experiment, 2020, 42(4): 575-585. doi: 10.11781/sysydz202004575
    [16]
    ZHANG Min, HUANG Guanghui, LI Hongbo, et al. Molecular geochemical characteristics of gas source rocks from the Upper Triassic Xujiahe Formation indicate transgression events in the Sichuan Basin[J]. Science China Earth Sciences, 2012, 55(8): 1260-1268.
    [17]
    蔡杰, 张敏. 四川盆地上三叠统须家河组煤系气源岩芳烃地球化学特征[J]. 石油实验地质, 2013, 35(3): 325-330. doi: 10.11781/sysydz201303325

    CAI Jie, ZHANG Min. Geochemical characteristics of aromatic hydrocarbons of coal-bearing gas source rocks from Upper Triassic Xujiahe Formation in Sichuan Basin[J]. Petroleum Geology & Experiment, 2013, 35(3): 325-330. doi: 10.11781/sysydz201303325
    [18]
    LI Ying, ZHU Yangming, HAO Fang, et al. Thermal evolution and applications of aromatic hydrocarbons in highly mature coal-bearing source rocks of the Upper Triassic Xujiahe Formation in the northern Sichuan Basin[J]. Science China Earth Sciences, 2015, 58(11): 1960-1969.
    [19]
    沈忠民, 魏金花, 朱宏权, 等. 川西坳陷煤系烃源岩成熟度特征及成熟度指标对比研究[J]. 矿物岩石, 2009, 29(4): 83-88. https://www.cnki.com.cn/Article/CJFDTOTAL-KWYS200904012.htm

    SHEN Zhongmin, WEI Jinhua, ZHU Hongquan, et al. Comparative research on maturity feature and maturity indicator of coal source rock from West Sichuan Basin Depression[J]. Journal of Mineralogy and Petrology, 2009, 29(4): 83-88. https://www.cnki.com.cn/Article/CJFDTOTAL-KWYS200904012.htm
    [20]
    吴小奇, 陈迎宾, 刘全有, 等. 川西坳陷新场气田须家河组五段烃源岩分子地球化学特征[J]. 地球科学, 2019, 44(3): 859-871. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201903014.htm

    WU Xiaoqi, CHEN Yingbin, LIU Quanyou, et al. Molecular geoche-mical characteristics of source rocks in the 5th member of Upper Triassic Xujiahe Formation, Xinchang gas field, West Sichuan Depression[J]. Earth Science, 2019, 44(3): 859-871. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201903014.htm
    [21]
    PETERS K E, MOLDOWAN J M. The biomarker guide: interpreting molecular fossils in petroleum and ancient sediments[M]. New Jersey: Prentice Hall Inc, 1993.
    [22]
    孙丽娜, 张中宁, 吴远东, 等. 生物标志化合物热成熟度参数演化规律及意义: 以Ⅲ型烃源岩HTHP生排烃热模拟液态烃产物为例[J]. 石油与天然气地质, 2015, 36(4): 573-580. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201504007.htm

    SUN Li'na, ZHANG Zhongning, WU Yuandong, et al. Evolution patterns and their significances of biomarker maturity parameters: a case study on liquid hydrocarbons from type Ⅲ source rock under HTHP hydrous pyrolysis[J]. Oil & Gas Geology, 2015, 36(4): 573-580. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201504007.htm
    [23]
    王铁冠, 钟宁宁, 侯读杰, 等. 低熟油气形成机理与分布[M]. 北京: 石油工业出版社, 1995.

    WANG Tieguan, ZHONG Ningning, HOU Dujie, et al. Genetic mechanism and occurrence of immature hydrocarbon[M]. Beijing: Petroleum Industry Press, 1995.
    [24]
    HUANG W Y, MEINSCHEIN W G. Sterols as ecological indicators[J]. Geochimica et Cosmochimica Acta, 1979, 43(5): 739-745.
    [25]
    包建平, 何丹, 朱翠山, 等. 北部湾盆地迈陈凹陷徐闻X3井原油地球化学特征及其成因[J]. 天然气地球科学, 2017, 28(5): 665-676. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201705001.htm

    BAO Jianping, HE Dan, ZHU Cuishan, et al. Geochemical characteristics and origin of a crude oil from well Xuwen X3 in the Maichen Sag, Beibuwan Basin, China[J]. Natural Gas Geoscience, 2017, 28(5): 665-676. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201705001.htm
    [26]
    SINNINGHE DAMSTÉ J S, KENIG F, KOOPMANS M P, et al. Evidence for gammacerane as an indicator of water column stratification[J]. Geochimica et Cosmochimica Acta, 1995, 59(9): 1895-1900.
    [27]
    李伟. 四川盆地晚三叠世咸化环境的形成与沉积体系的演化特征[J]. 天然气工业, 2011, 31(9): 31-38. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG201109008.htm

    LI Wei. Formation of a saline environment and evolution of a sedimentary system in the Late Triassic reservoirs of the Sichuan Basin[J]. Natural Gas Industry, 2011, 31(9): 31-38. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG201109008.htm
    [28]
    宋长玉, 金洪蕊, 刘璇, 等. 烃源岩中甲基菲的分布及对成熟度参数的影响[J]. 石油实验地质, 2007, 29(2): 183-187. doi: 10.11781/sysydz200702183

    SONG Changyu, JIN Hongrui, LIU Xuan, et al. Distribution of methyl phenanthrene in sediments and its impacting on maturity parameters[J]. Petroleum Geology & Experiment, 2007, 29(2): 183-187. doi: 10.11781/sysydz200702183
    [29]
    RADKE M, WELTE D H, WILLSCH H. Geochemical study on a well in the Western Canada Basin: relation of the aromatic distribution pattern to maturity of organic matter[J]. Geochimica et Cosmochimica Acta, 1982, 46(1): 1-10.
    [30]
    KVALHEIM O M, CHRISTY A A, TELNÆS N, et al. Maturity determination of organic matter in coals using the methylphenanthrene distribution[J]. Geochimica et Cosmochimica Acta, 1987, 51(7): 1883-1888.
    [31]
    LIN Renzi, WANG Peirong. PAH in fossil fuels and their geochemical significance[J]. Journal of Southeast Asian Earth Sciences, 1991, 5(1/4): 257-262.
    [32]
    程克明, 王铁冠, 钟宁宁. 烃源岩地球化学[M]. 北京: 科学出版社, 1995.

    CHENG Keming, WANG Tieguan, ZHONG Ningning. Geoche-mistry of source rocks[M]. Beijing: Science Press, 1995.
    [33]
    RADKE M, VRIEND S P, RAMANAMPISOA L R. Alkyldibenzofurans in terrestrial rocks: influence of organic facies and maturation[J]. Geochimica et Cosmochimica Acta, 2000, 64(2): 275-286.
    [34]
    朱扬明, 顾圣啸, 李颖, 等. 四川盆地龙潭组高热演化烃源岩有机质生源及沉积环境探讨[J]. 地球化学, 2012, 41(1): 35-44. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX201201005.htm

    ZHU Yangming, GU Shengxiao, LI Ying, et al. Biological organic source and depositional environment of over-mature source rocks of Longtan Formation in Sichuan Basin[J]. Geochimica, 2012, 41(1): 35-44. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX201201005.htm
    [35]
    HUGHES W B, HOLBA A G, DZOU L I P. The ratios of dibenzothiophene to phenanthrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks[J]. Geochimica et Cosmochimica Acta, 1995, 59(17): 3581-3598.
    [36]
    RADKE M, WELTE D H, WILLSCH H. Maturity parameters based on aromatic hydrocarbons: influence of the organic matter type[J]. Organic Geochemistry, 1986, 10(1/3): 51-63.
    [37]
    魏志彬, 张大江, 张传禄, 等. 甲基二苯并噻吩分布指数(MDBI)作为烃源岩成熟度标尺的探讨[J]. 地球化学, 2001, 30(3): 242-247. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX200103006.htm

    WEI Zhibin, ZHANG Dajiang, ZHANG Chuanlu, et al. Methyldibenzothiophenes distribution index as a tool for maturity assessments of source rocks[J]. Geochimica, 2001, 30(3): 242-247. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX200103006.htm
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(14)  / Tables(3)

    Article Metrics

    Article views (427) PDF downloads(53) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return