JIN Yunyun, LI Chuxiong, WANG Yong, YAN Yongxin, LUO Xi, HUANG Shuaibo, LI Zhiming, ZHOU Yuanyuan, SUN Zhongliang, LIU Yahui, JIA Mengyao, LENG Junying. Oil-bearing potential and hydrocarbon occurrence characteristics of shale in Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(2): 354-365. doi: 10.11781/sysydz202402354
Citation: JIN Yunyun, LI Chuxiong, WANG Yong, YAN Yongxin, LUO Xi, HUANG Shuaibo, LI Zhiming, ZHOU Yuanyuan, SUN Zhongliang, LIU Yahui, JIA Mengyao, LENG Junying. Oil-bearing potential and hydrocarbon occurrence characteristics of shale in Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(2): 354-365. doi: 10.11781/sysydz202402354

Oil-bearing potential and hydrocarbon occurrence characteristics of shale in Paleogene Hetaoyuan Formation in Biyang Sag, Nanxiang Basin

doi: 10.11781/sysydz202402354
  • Received Date: 2023-03-16
  • Rev Recd Date: 2024-01-05
  • Publish Date: 2024-03-28
  • High-quality lacustrine shale beds within the Paleogene Hetaoyuan Formation in the Biyang Sag, Nanxiang Basin, exhibit significant potential for shale oil resources. Previous studies on the oil-bearing potential and hydrocarbon occurrence of shales in the Biyang Sag were relatively limited, potentially hindering advancements for shale oil exploration. This study focuses on the shales found in the third sub-member of the third member within the Hetaoyuan Formation in well Y1, which locates in the southern area of the Biyang Sag. Through various geochemical analyses such as Rock-Eval pyrolysis, multi-temperature pyrolysis and X-ray diffraction, this research systematically investigates the shale oil contents, hydrocarbon occurrence characteristics, and influencing factors. These results indicate that the lithofacies assemblages of the shale primarily consist of felsic shale facies, dolomitic shale facies and mixed shale facies, with a well-developed laminar structure. The source rock quality is classified as good to excellent, and the thermal maturity stage of oil window. The predominant organic maceral is sapropelic, with organic matter types ranging from Ⅰ to Ⅱ1. Oil content increases with burial depth, ranged from adsorbed hydrocarbons in the upper section to free hydrocarbons in the lower section. Detrital mineral content and total organic carbon (TOC) content are identified as the main factors influencing free and adsorbed hydrocarbon content, respectively. Overall, the oil saturation index (OSI) of the shale in the lower section of the Hetaoyuan Formation exceeds 100 mg/g, with an average free hydrocarbon content over 3 mg/g, indicating promising prospects for shale oil exploration and development.

     

  • All authors disclose no relevant conflict of interests.
    The study was designed by LI Chuxiong and LI Zhiming. The experimental operation was completed by ZHOU Yuanyuan, LIU Yahui, JIA Mengyao, LENG Junying and SUN Zhongliang. The manuscript was drafted and revised by JIN Yunyun, LI Chuxiong, LI Zhiming, WANG Yong, YAN Yongxin, LUO Xi and HUANG Shuaibo. All the authors have read the last version of paper and consented for submission.
  • [1]
    贾承造, 郑民, 张永峰. 中国非常规油气资源与勘探开发前景[J]. 石油勘探与开发, 2012, 39(2): 129-136. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK201202002.htm

    JIA Chengzao, ZHENG Min, ZHANG Yongfeng. Unconventional hydrocarbon resources in China and the prospect of exploration and development[J]. Petroleum Exploration and Development, 2012, 39(2): 129-136. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK201202002.htm
    [2]
    李吉君, 史颖琳, 章新文, 等. 页岩油富集可采主控因素分析: 以泌阳凹陷为例[J]. 地球科学(中国地质大学学报), 2014, 39(7): 848-857. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201407007.htm

    LI Jijun, SHI Yinglin, ZHANG Xinwen, et al. Control factors of enrichment and producibility of shale oil: a case study of Biyang Depression[J]. Earth Science(Journal of China University of Geosciences), 2014, 39(7): 848-857. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201407007.htm
    [3]
    刘惠民. 济阳坳陷页岩油勘探实践与前景展望[J]. 中国石油勘探, 2022, 27(1): 73-87. https://www.cnki.com.cn/Article/CJFDTOTAL-KTSY202201007.htm

    LIU Huimin. Exploration practice and prospect of shale oil in Jiyang Depression[J]. China Petroleum Exploration, 2022, 27(1): 73-87. https://www.cnki.com.cn/Article/CJFDTOTAL-KTSY202201007.htm
    [4]
    邹才能, 杨智, 崔景伟, 等. 页岩油形成机制、地质特征及发展对策[J]. 石油勘探与开发, 2013, 40(1): 14-26. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK201301003.htm

    ZOU Caineng, YANG Zhi, CUI Jingwei, et al. Formation mechanism, geological characteristics and development strategy of nonmarine shale oil in China[J]. Petroleum Exploration and Development, 2013, 40(1): 14-26. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK201301003.htm
    [5]
    BRUNAUER S, EMMETT P H, TELLER E. Adsorption of gases in multimolecular layers[J]. Journal of the American Chemical Society, 1938, 60(2): 309-319. doi: 10.1021/ja01269a023
    [6]
    包友书, 张林晔, 张金功, 等. 渤海湾盆地东营凹陷古近系页岩油可动性影响因素[J]. 石油与天然气地质, 2016, 37(3): 408-414. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201603015.htm

    BAO Youshu, ZHANG Linye, ZHANG Jingong, et al. Factors influencing mobility of Paleogene shale oil in Dongying Sag, Bohai Bay Basin[J]. Oil & Gas Geology, 2016, 37(3): 408-414. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201603015.htm
    [7]
    蒋启贵, 黎茂稳, 钱门辉, 等. 不同赋存状态页岩油定量表征技术与应用研究[J]. 石油实验地质, 2016, 38(6): 842-849. doi: 10.11781/sysydz201606842

    JIANG Qigui, LI Maowen, QIAN Menhui, et al. Quantitative characterization of shale oil in different occurrence states and its application[J]. Petroleum Geology & Experiment, 2016, 38(6): 842-849. doi: 10.11781/sysydz201606842
    [8]
    ZINK K G, SCHEEDER G, STUECK H L, et al. Total shale oil inventory from an extended Rock-Eval approach on non-extracted and extracted source rocks from Germany[J]. International Journal of Coal Geology, 2016, 163: 186-194. doi: 10.1016/j.coal.2016.06.023
    [9]
    薛海涛, 田善思, 王伟明, 等. 页岩油资源评价关键参数——含油率的校正[J]. 石油与天然气地质, 2016, 37(1): 15-22. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201601004.htm

    XUE Haitao, TIAN Shansi, WANG Weiming, et al. Correction of oil content: one key parameter in shale oil resource assessment[J]. Oil & Gas Geology, 2016, 37(1): 15-22. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201601004.htm
    [10]
    BORDENAVE M L. Geochemical methods and tools in petroleum exploration[M]//BORDENAVE M L. Applied petroleum geochemistry. Paris: Editons Technip, 1993: 240-243.
    [11]
    JARVIE D M. Shale resource systems for oil and gas: part 2: shale-oil resource systems[M]//BREYER J A. Shale reservoirs: giant resources for the 21st century. Tulsa: American Association of Petroleum Geologists, 2012: 89-119.
    [12]
    JARVIE D M. Components and processes affecting producibility and commerciality of shale resource systems[J]. Geologica Acta, 2014, 12(4): 307-325.
    [13]
    LI Jijun, WANG Weiming, CAO Qun, et al. Impact of hydrocarbon expulsion efficiency of continental shale upon shale oil accumulations in Eastern China[J]. Marine and Petroleum Geology, 2015, 59: 467-479. doi: 10.1016/j.marpetgeo.2014.10.002
    [14]
    钱门辉, 王绪龙, 黎茂稳, 等. 玛页1井风城组页岩含油性与烃类赋存状态[J]. 新疆石油地质, 2022, 43(6): 693-703. https://www.cnki.com.cn/Article/CJFDTOTAL-XJSD202206007.htm

    QIAN Menhui, WANG Xulong, LI Maowen, et al. Oil-bearing properties and hydrocarbon occurrence states of Fengcheng Formation shale in well Maye-1, Mahu Sag[J]. Xinjiang Petroleum Geology, 2022, 43(6): 693-703. https://www.cnki.com.cn/Article/CJFDTOTAL-XJSD202206007.htm
    [15]
    袁玉哲, 罗家群, 朱颜, 等. 南襄盆地泌阳凹陷和南阳凹陷油气勘探历程与启示[J]. 新疆石油地质, 2021, 42(3): 364-373. https://www.cnki.com.cn/Article/CJFDTOTAL-XJSD202103014.htm

    YUAN Yuzhe, LUO Jiaqun, ZHU Yan, et al. Petroleum exploration history and enlightenment of Biyang Sag and Nanyang Sag in Nanxiang Basin[J]. Xinjiang Petroleum Geology, 2021, 42(3): 364-373. https://www.cnki.com.cn/Article/CJFDTOTAL-XJSD202103014.htm
    [16]
    李志明, 金芸芸, 李楚雄, 等. 南襄盆地泌阳凹陷渐新统核桃园组三Ⅲ亚段页岩油富集模式: 以中部深凹带YYY1井取心段为例[J]. 石油实验地质, 2023, 45(5): 952-962. doi: 10.11781/sysydz202305952

    LI Zhiming, JIN Yunyun, LI Chuxiong, et al. Discussion on shale oil enrichment pattern in the Ⅲ submember of the third member of Oligocene Hetaoyuan Formation, Biyang Sag, Nanxiang Basin: a case study of cored interval of well YYY1 in the central deep sag zone[J]. Petroleum Geology & Experiment, 2023, 45(5): 952-962. doi: 10.11781/sysydz202305952
    [17]
    LI Jinbu, WANG Min, CHEN Zhuoheng, et al. Evaluating the total oil yield using a single routine Rock-Eval experiment on asreceived shales[J]. Journal of Analytical and Applied Pyrolysis, 2019, 144: 104707. doi: 10.1016/j.jaap.2019.104707
    [18]
    何涛华, 李文浩, 谭昭昭, 等. 南襄盆地泌阳凹陷核桃园组页岩油富集机制[J]. 石油与天然气地质, 2019, 40(6): 1259-1269. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201906010.htm

    HE Taohua, LI Wenhao, TAN Zhaozhao, et al. Mechanism of shale oil accumulation in the Hetaoyuan Formation from the Biyang Depression, Nanxiang Basin[J]. Oil & Gas Geology, 2019, 40(6): 1259-1269. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201906010.htm
    [19]
    蒋启贵, 黎茂稳, 钱门辉, 等. 页岩油探井现场地质评价实验流程与技术进展[J]. 石油与天然气地质, 2019, 40(3): 571-582. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201903013.htm

    JIANG Qigui, LI Maowen, QIAN Menhui, et al. Experimental procedures of well-site geological evaluation for shale oil and related technological progress[J]. Oil & Gas Geology, 2019, 40(3): 571-582. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201903013.htm
    [20]
    孙焕泉. 济阳坳陷页岩油勘探实践与认识[J]. 中国石油勘探, 2017, 22(4): 1-14. doi: 10.3969/j.issn.1672-7703.2017.04.001

    SUN Huanquan. Exploration practice and cognitions of shale oil in Jiyang Depression[J]. China Petroleum Exploration, 2017, 22(4): 1-14. doi: 10.3969/j.issn.1672-7703.2017.04.001
    [21]
    PETERS K E, CASSA M R. Applied source rock geochemistry[M]//MAGOON L B, DOW W G. The petroleum system: from source to trap. Tulsa: American Association of Petroleum Geologists, 1994: 93-120.
    [22]
    PHILP R P. Petroleum formation and occurrence[J]. Eos, Trans-actions American Geophysical Union, 1985, 66(37): 643-644. doi: 10.1029/EO066i037p00643
    [23]
    李志明, 徐二社, 秦建中, 等. 烃源岩评价中的若干问题[J]. 西安石油大学学报(自然科学版), 2010, 25(6): 8-12. doi: 10.3969/j.issn.1673-064X.2010.06.002

    LI Zhiming, XU Ershe, QIN Jianzhong, et al. Some problems on the evaluation of source rock[J]. Journal of Xi'an Shiyou University (Natural Science Edition), 2010, 25(6): 8-12. doi: 10.3969/j.issn.1673-064X.2010.06.002
    [24]
    李志明, 孙中良, 鲍云杰, 等. 冀北坳陷中元古界洪水庄组页岩油勘探前景探讨[J]. 石油实验地质, 2023, 45(1): 29-40. doi: 10.11781/sysydz202301029

    LI Zhiming, SUN Zhongliang, BAO Yunjie, et al. Discussion on prospecting shale oil potential of Mesoproterozoic Hongshuizhuang Formation in the Jibei Depression[J]. Petroleum Geology & Experiment, 2023, 45(1): 29-40. doi: 10.11781/sysydz202301029
    [25]
    ESPITALIÉ J. Use of Tmax as a maturation index for different types of organic matter: comparison with vitrinite reflectance[M]//BURRUS J. Thermal modeling in sedimentary basins. Paris: Editions Technip, 1986: 475-496.
    [26]
    WANG Enze, LI Changrong, FENG Yue, et al. Novel method for determining the oil moveable threshold and an innovative model for evaluating the oil content in shales[J]. Energy, 2022, 239: 121848. doi: 10.1016/j.energy.2021.121848
    [27]
    郭飞飞, 柳广弟. 南襄盆地南阳凹陷古近系核桃园组核三段优质烃源岩分布与油气成藏特征[J]. 天然气地球科学, 2021, 32(3): 405-415. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX202103010.htm

    GUO Feifei, LIU Guangdi. The distribution of high-quality source rocks in He3 member and hydrocarbon accumulation characteristics in Nanyang Depression, Nanxiang Basin[J]. Natural Gas Geoscience, 2021, 32(3): 405-415. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX202103010.htm
    [28]
    李志明, 陶国亮, 黎茂稳, 等. 鄂尔多斯盆地西南部彬长区块三叠系延长组7段3亚段页岩油勘探前景探讨[J]. 石油与天然气地质, 2019, 40(3): 558-570. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201903012.htm

    LI Zhiming, TAO Guoliang, LI Maowen, et al. Discussion on prospecting potential of shale oil in the 3rd sub-member of the Triassic Chang 7 member in Binchang block, southwestern Ordos Basin[J]. Oil & Gas Geology, 2019, 40(3): 558-570. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201903012.htm
    [29]
    蒋启贵, 王延斌, 秦建中, 等. 中国南方海相烃源岩生烃动力学研究[J]. 石油实验地质, 2008, 30(6): 606-610. doi: 10.3969/j.issn.1001-6112.2008.06.014

    JIANG Qigui, WANG Yanbin, QIN Jianzhong, et al. Kinetics of hydrocarbon generation of marine source rocks in South China[J]. Petroleum Geology & Experiment, 2008, 30(6): 606-610. doi: 10.3969/j.issn.1001-6112.2008.06.014
    [30]
    张大庚, 依艳丽, 郑西来, 等. 土壤对石油烃吸附及其释放规律的研究[J]. 沈阳农业大学学报, 2005, 36(1): 53-56. https://www.cnki.com.cn/Article/CJFDTOTAL-SYNY200501013.htm

    ZHANG Dageng, YI Yanli, ZHENG Xilai, et al. Soil adsorption to petroleum and release in meadow soils[J]. Journal of Shenyang Agricultural University, 2005, 36(1): 53-56. https://www.cnki.com.cn/Article/CJFDTOTAL-SYNY200501013.htm
    [31]
    PANG Xiongqi, LI Maowen, LI Sumei, et al. Geochemistry of petroleum systems in the Niuzhuang South Slope of Bohai Bay Basin: part 3. Estimating hydrocarbon expulsion from the Shahejie Formation[J]. Organic Geochemistry, 2005, 36(4): 497-510. doi: 10.1016/j.orggeochem.2004.12.001
    [32]
    WANG Enze, LIU Guoyong, PANG Xiongqi, et al. An improved hydrocarbon generation potential method for quantifying hydrocarbon generation and expulsion characteristics with application example of Paleogene Shahejie Formation, Nanpu Sag, Bohai Bay Basin[J]. Marine and Petroleum Geology, 2020, 112: 104-106.
    [33]
    李嘉蕊, 杨智, 王兆云, 等. 准噶尔盆地玛湖凹陷二叠系风城组页岩油赋存定量表征及其主控因素[J]. 石油实验地质, 2023, 45(4): 681-692. doi: 10.11781/sysydz202304681

    LI Jiarui, YANG Zhi, WANG Zhaoyun, et al. Quantitative characte-rization and main controlling factors of shale oil occurrence in Permian Fengcheng Formation, Mahu Sag, Junggar Basin[J]. Petroleum Geology & Experiment, 2023, 45(4): 681-692. doi: 10.11781/sysydz202304681
    [34]
    李洪波, 吴智超, 张敏, 等. 吉木萨尔凹陷芦草沟组页岩油地球化学特征与运聚意义[J]. 断块油气田, 2023, 30(4): 579-585. https://www.cnki.com.cn/Article/CJFDTOTAL-DKYT202304008.htm

    LI Hongbo, WU Zhichao, ZHANG Min, et al. The geochemical characteristics and migration-accumulation significances of shale oil in Lucaogou Formation of Jimsar Sag[J]. Fault-Block Oil and Gas Field, 2023, 30(4): 579-585. https://www.cnki.com.cn/Article/CJFDTOTAL-DKYT202304008.htm
    [35]
    罗超, 张焕旭, 张纪智, 等. 岩石密闭热释方法评价页岩含油性特征: 以四川盆地侏罗系大安寨段为例[J]. 石油实验地质, 2022, 44(4): 712-719. doi: 10.11781/sysydz202204712

    LUO Chao, ZHANG Huanxu, ZHANG Jizhi, et al. Evaluation of oil content in shale by sealed thermal desorption: a case study of Jurassic Da'anzhai Member, Sichuan Basin[J]. Petroleum Geology & Experiment, 2022, 44(4): 712-719. doi: 10.11781/sysydz202204712
    [36]
    钱门辉, 黎茂稳, 蒋启贵, 等. 页岩岩心样品烃类散失特征与地质意义[J]. 石油实验地质, 2022, 44(3): 497-504. doi: 10.11781/sysydz202203497

    QIAN Menhui, LI Maowen, JIANG Qigui, et al. Evaluation of evaporative loss of hydrocarbon in shale samples and its geological implications[J]. Petroleum Geology & Experiment, 2022, 44(3): 497-504. doi: 10.11781/sysydz202203497
    [37]
    杨智, 邹才能. "进源找油": 源岩油气内涵与前景[J]. 石油勘探与开发, 2019, 46(1): 173-184. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK201901018.htm

    YANG Zhi, ZOU Caineng. "Exploring petroleum inside source kitchen": connotation and prospects of source rock oil and gas[J]. Petroleum Exploration and Development, 2019, 46(1): 173-184. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK201901018.htm
    [38]
    杨丽, 彭志春, 刘薇, 等. 文昌X油田珠海组低渗储层成岩作用与孔隙演化[J]. 断块油气田, 2022, 29(5): 641-646, 658. https://www.cnki.com.cn/Article/CJFDTOTAL-DKYT202205011.htm

    YANG Li, PENG Zhichun, LIU Wei, et al. Diagenesis and pore evolution of low permeability reservoir in Zhuhai Formation of Wenchang X oil field[J]. Fault-Block Oil and Gas Field, 2022, 29(5): 641-646, 658. https://www.cnki.com.cn/Article/CJFDTOTAL-DKYT202205011.htm
    [39]
    支东明, 唐勇, 何文军, 等. 准噶尔盆地玛湖凹陷风城组常规-非常规油气有序共生与全油气系统成藏模式[J]. 石油勘探与开发, 2021, 48(1): 38-51. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK202101006.htm

    ZHI Dongming, TANG Yong, HE Wenjun, et al. Orderly coexistence and accumulation models of conventional and unconventional hydrocarbons in Lower Permian Fengcheng Formation, Mahu Sag, Junggar Basin[J]. Petroleum Exploration and Deve-lopment, 2021, 48(1): 38-51. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK202101006.htm
  • Cited by

    Periodical cited type(1)

    1. 刘惠民,文华国,张奎华,郭佩,张关龙,于洪洲,熊伟,周健,徐文礼,宋梅远,李长志. 准噶尔盆地西北缘哈山地区风城组碱湖页岩油地质特征与勘探展望. 古地理学报. 2024(05): 1017-1036 .

    Other cited types(0)

  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(12)

    Article Metrics

    Article views (503) PDF downloads(50) Cited by(1)
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return