Volume 46 Issue 2
Mar.  2024
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ZHU Nan, WANG Aiguo, GUO Kai, WU Chunyan, LI Chunyu, YANG Zeguang, HE Sensen. Effectiveness of nitrogen compound indices of oil-bearing sandstone extracts[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(2): 393-401. doi: 10.11781/sysydz202402393
Citation: ZHU Nan, WANG Aiguo, GUO Kai, WU Chunyan, LI Chunyu, YANG Zeguang, HE Sensen. Effectiveness of nitrogen compound indices of oil-bearing sandstone extracts[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(2): 393-401. doi: 10.11781/sysydz202402393

Effectiveness of nitrogen compound indices of oil-bearing sandstone extracts

doi: 10.11781/sysydz202402393
  • Received Date: 2023-05-15
  • Rev Recd Date: 2024-02-18
  • Publish Date: 2024-03-28
  • Reports on the utilization of nitrogen compounds to trace oil and gas migration in oil-scarce regions are limited. This scarcity can be attributed to the lack of clarity regarding the effectiveness of nitrogen compound indices in oil-bearing sandstone extracts. To address this knowledge gap, two sets of experiments were designed, encompassing five extraction methods, to evaluate the validity of nitrogen compound indices. The results showed that as the extraction intensity increased, the ratios of 1-/4-methylcarbazole and 1, 8-/2, 7-dimethylcarbazole in the extracts gradually decreased but remained consistently elevated compared to the control oils. The benzocarbazole [a]/[c] ratio remained relatively stable and closely aligned with the control oils. Upon analysis, it was concluded that the observed variations could be attributed to the differing adsorption capacities of carbazole isomers. These differences lead to the fractionation of carbazole isomers between free and adsorbed hydrocarbons under surface conditions, as well as between the extracts and rocks during the extraction process. In comparison to 1-/4-methylcarbazole and 1, 8-/2, 7-dimethylcarbazole, the benzocarbazole [a]/[c] ratio is less susceptible to these two fractionations, with its variations primarily governed by migration fractionation. Additionally, the indicated direction of oil and gas migration aligns with geological realities. Therefore, the benzocarbazole [a]/[c] ratio can be considered an effective nitrogen compound index in oil-bearing sandstone extracts, suitable for oil migration tracing studies in oil-scarce regions.

     

  • All authors disclose no relevant conflict of interests.
    The study was designed by ZHU Nan, WANG Aiguo and WU Chunyan. The sample collection and experimental operation were completed by GUO Kai, LI Chunyu, YANG Zeguang and HE Sensen. The manuscript was drafted and revised by ZHU Nan and WANG Aiguo. All the authors have read the last version of paper and consented for submission.
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  • [1]
    郭佳, 牛博. 有机地球化学方法示踪石油运移的研究进展[J]. 吉林化工学院学报, 2016, 33(5): 1-4. https://www.cnki.com.cn/Article/CJFDTOTAL-JHXY201605001.htm

    GUO Jia, NIU Bo. Progresses in organic geochemical studies on tracing oil migration[J]. Journal of Jilin Institute of Chemical Technology, 2016, 33(5): 1-4. https://www.cnki.com.cn/Article/CJFDTOTAL-JHXY201605001.htm
    [2]
    刘洛夫, 徐新德, 毛东风, 等. 咔唑类化合物在油气运移研究中的应用初探[J]. 科学通报, 1997, 42(4): 420-423. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB199704025.htm

    LIU Luofu, XU Xinde, MAO Dongfeng, et al. Application of carbazole compounds in study of hydrocarbon migration[J]. Chinese Science Bulletin, 1997, 42(23): 1970-1974. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB199704025.htm
    [3]
    杨宪彰, 徐志明, 赵丹阳. 含氮化合物在油气地球化学中的应用[J]. 天然气地球科学, 2005, 16(6): 809-813. doi: 10.3969/j.issn.1672-1926.2005.06.026

    YANG Xianzhang, XU Zhiming, ZHAO Danyang. The using of nitrogen compounds in geochemistry[J]. Natural Gas Geoscience, 2005, 16(6): 809-813. doi: 10.3969/j.issn.1672-1926.2005.06.026
    [4]
    王铁冠, 李素梅, 张爱云, 等. 应用含氮化合物探讨新疆轮南油田油气运移[J]. 地质学报, 2000, 74(1): 85-93. doi: 10.3321/j.issn:0001-5717.2000.01.009

    WANG Tieguan, LI Sumei, ZHANG Aiyun, et al. A discussion on petroleum migration in the Lunnan Oilfield of Xinjiang based on nitrogen compounds[J]. Acta Geologica Sinica, 2000, 74(1): 85-93. doi: 10.3321/j.issn:0001-5717.2000.01.009
    [5]
    卢青, 包建平. 咔唑类化合物的地球化学意义及应用[J]. 广东石油化工学院学报, 2013, 23(6): 20-23. doi: 10.3969/j.issn.2095-2562.2013.06.006

    LU Qing, BAO Jianping. The overview of research progress on carbazole compounds[J]. Journal of Guangdong University of Petrochemical Technology, 2013, 23(6): 20-23. doi: 10.3969/j.issn.2095-2562.2013.06.006
    [6]
    刘洛夫, 康永尚. 运用原油吡咯类含氮化合物研究塔里木盆地塔中地区石油的二次运移[J]. 地球化学, 1998, 27(5): 475-482. doi: 10.3321/j.issn:0379-1726.1998.05.009

    LIU Luofu, KANG Yongshang. Investigation on secondary migration of oils in central Tarim, Tarim Basin using pyrrolic nitrogen compounds[J]. Geochimica, 1998, 27(5): 475-482 doi: 10.3321/j.issn:0379-1726.1998.05.009
    [7]
    李贤庆, 侯读杰, 肖贤明, 等. 应用含氮化合物探讨油气运移和注入方向[J]. 石油实验地质, 2004, 26(2): 200-205. doi: 10.3969/j.issn.1001-6112.2004.02.013

    LI Xianqing, HOU Dujie, XIAO Xianming, et al. Study of oil migration and injection directions by nitrogen compounds[J]. Petroleum Geology & Experiment, 2004, 26(2): 200-205. doi: 10.3969/j.issn.1001-6112.2004.02.013
    [8]
    章倩倩, 田东恩, 马艳荣, 等. 应用含氮化合物判别油气运移的方向[J]. 长江大学学报(自然科学版), 2012, 9(5): 90-92. https://www.cnki.com.cn/Article/CJFDTOTAL-CJDL201205031.htm

    ZHANG Qianqian, TIAN Dongen, MA Yanrong, et al. Methods of distinguishing nitrogen compound migration orientation by using carbazole compound[J]. Journal of Yangtze University(Natural Science Edition), 2012, 9(5): 90-92. https://www.cnki.com.cn/Article/CJFDTOTAL-CJDL201205031.htm
    [9]
    张寒池. 新沟地区原油的含氮化合物分布及油气运移方向[J]. 化工管理, 2017(18): 47-48. doi: 10.3969/j.issn.1008-4800.2017.18.034

    ZHANG Hanchi. Distribution of nitrogen-containing compounds and oil and gas migration in Xingou area[J]. Chemical Enterprise Management, 2017(18): 47-48. doi: 10.3969/j.issn.1008-4800.2017.18.034
    [10]
    付金华, 段明辰, 段毅, 等. 华庆地区长8原油含氮化合物及运移研究[J]. 中国矿业大学学报, 2017, 46(4): 838-845. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGKD201704018.htm

    FU Jinhua, DUAN Mingchen, DUAN Yi, et al. Characteristics of nitrogen compounds and migration of crude oil in Chang 8 subsection of Huaqing region in Ordos Basin, China[J]. Journal of China University of Mining & Technology, 2017, 46(4): 838-845. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGKD201704018.htm
    [11]
    DIAS L C, BAHIA P V B, DO AMARAL D N, et al. Nitrogen compounds as molecular markers: an overview of analytical methodologies for its determination in crude oils and source rock extracts[J]. Microchemical Journal, 2020, 157: 105039. doi: 10.1016/j.microc.2020.105039
    [12]
    LI Maowen, LARTER S R, STODDART D, et al. Fractionation of pyrrolic nitrogen compounds in petroleum during migration: derivation of migration-related geochemical parameters[J]. Geological Society, London, Special Publications, 1995, 86(1): 103-123. doi: 10.1144/GSL.SP.1995.086.01.09
    [13]
    ZIEGS V, NOAH M, POETZ S, et al. Unravelling maturity- and migration-related carbazole and phenol distributions in Central Graben crude oils[J]. Marine and Petroleum Geology, 2018, 94: 114-130. doi: 10.1016/j.marpetgeo.2018.03.039
    [14]
    FABOYA O L, SONIBARE O O, LIAO Zewen, et al. Occurrence and distribution of carbazoles and benzocarbazoles in Tertiary Niger delta source rocks[J]. Petroleum Science and Technology, 2014, 32(24): 2938-2952. doi: 10.1080/10916466.2014.926922
    [15]
    LI Maowen, LARTER S R, FROLOV Y B, et al. Adsorptive interaction between nitrogen compounds and organic and/or mineral phases in subsurface rocks. Models for compositional fractionation of pyrrolic nitrogen compounds in petroleum during petroleum migration[J]. Journal of High Resolution Chromatography, 1994, 17(4): 230-236. doi: 10.1002/jhrc.1240170408
    [16]
    LI Chao, CHEN Guojun, LI Xiaotian, et al. The occurrence of tight oil in the Chang 8 lacustrine sandstone of the Huaqing area, Ordos Basin: insights into the content of adsorbed oil and its controlling factors[J]. Journal of Natural Gas Geoscience, 2022, 7(1): 27-37. doi: 10.1016/j.jnggs.2021.11.001
    [17]
    刘俊海, 陈小宏, 杨香华. 吡咯类含氮化合物油气运移参数适用性研究[C]//第四届油气成藏机理与资源评价国际学术研讨会论文集. 北京: 石油工业出版社, 2006.

    LIU Junhai, CHEN Xiaohong, YANG Xianghua. Study on the applicability of hydrocarbon migration parameters of pyrrole nitrogen-containing compounds[C]//The 4th International Symposium on Reservoir Mechanism and Resource Evaluation. Beijing: Petroleum Industry Press, 2006.
    [18]
    易传俊, 陈小慧. 含油页岩连续抽提物芳烃与含氮化合物组成特征[J]. 科学技术与工程, 2017, 17(29): 233-240. doi: 10.3969/j.issn.1671-1815.2017.29.034

    YI Chuanjun, CHEN Xiaohui. Aromatic hydrocarbon and non-hydrocarbon composition characteristics of sequential extracts of oil-bearing shales with different polarity reagents[J]. Science Technology and Engineering, 2017, 17(29): 233-240. doi: 10.3969/j.issn.1671-1815.2017.29.034
    [19]
    陈小慧, 张敏. 含油页岩不同极性试剂连续抽提物饱和烃组成特征[J]. 大庆石油地质与开发, 2017, 36(3): 168-174. https://www.cnki.com.cn/Article/CJFDTOTAL-DQSK201703031.htm

    CHEN Xiaohui, ZHANG Min. Composition characteristics of the saturated hydrocarbon of the sequential extracts from the oil-bearing shales with different polarity reagents[J]. Petroleum Geology and Oilfield Development in Daqing, 2017, 36(3): 168-174. https://www.cnki.com.cn/Article/CJFDTOTAL-DQSK201703031.htm
    [20]
    张宝, 包建平. 有机含氮化合物研究新进展[J]. 天然气地球科学, 2004, 15(2): 182-186. doi: 10.3969/j.issn.1672-1926.2004.02.018

    ZHANG Bao, BAO Jianping. New progress on organonitrogen compound studies[J]. Natural Gas Geoscience, 2004, 15(2): 182-186. doi: 10.3969/j.issn.1672-1926.2004.02.018
    [21]
    丛奇, 陈君青, 卢贵武, 等. 利用分子动力学模拟研究页岩吸附能力的影响因素及微观机理的综述[J]. 中南大学学报(自然科学版), 2022, 53(9): 3474-3489. https://www.cnki.com.cn/Article/CJFDTOTAL-ZNGD202209015.htm

    CONG Qi, CHEN Junqing, LU Guiwu, et al. Review on influencing factors and microscopic mechanism of shale adsorption capacity by molecular dynamics simulation[J]. Journal of Central South University(Science and Technology), 2022, 53(9): 3474-3489. https://www.cnki.com.cn/Article/CJFDTOTAL-ZNGD202209015.htm
    [22]
    王永诗, 李政, 王民, 等. 渤海湾盆地济阳坳陷陆相页岩油吸附控制因素[J]. 石油与天然气地质, 2022, 43(3): 489-498. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT202203001.htm

    WANG Yongshi, LI Zheng, WANG Min, et al. Factors controlling lacustrine shale oil adsorption in the Jiyang Depression, Bohai Bay Basin[J]. Oil & Gas Geology, 2022, 43(3): 489-498. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT202203001.htm
    [23]
    王帅. 鄂尔多斯盆地华庆地区延长组油气储层与输导体系研究[D]. 大庆: 东北石油大学, 2014.

    WANG Shuai. Research on the oil and gas reservoir and pathway systems in Yanchang Group of Huaqing area, Ordos's Basin[D]. Daqing: Northeast Petroleum University, 2014.
    [24]
    QU Hongjun, YANG Bo, GAO Shengli, et al. Controls on hydrocarbon accumulation by facies and fluid potential in large-scale lacustrine petroliferous basins in compressional settings: a case study of the Mesozoic Ordos Basin, China[J]. Marine and Petroleum Geology, 2020, 122: 104668.
    [25]
    杨泽光. 鄂尔多斯盆地三边北地区长6、长7石油成藏过程[D]. 西安: 西北大学, 2022.

    YANG Zeguang. Petroleum accumulation process of Chang 6 and Chang 7 member in Sanbianbei area, Ordos Basin[D]. Xi'an: Northwest University, 2022.
    [26]
    王乃军, 赵靖舟, 赵卫卫, 等. 鄂尔多斯盆地三叠系长6油层组"准连续型"油气藏成藏主控因素[J]. 兰州大学学报(自然科学版), 2012, 48(4): 8-13. https://www.cnki.com.cn/Article/CJFDTOTAL-LDZK201204004.htm

    WANG Naijun, ZHAO Jingzhou, ZHAO Weiwei, et al. Key controlling factors for petroleum accumulation in "quasi-continuous" oil reservoirs of Chang 6 oil-bearing formation of Triassic, Ordos Basin[J]. Journal of Lanzhou University(Natural Sciences), 2012, 48(4): 8-13. https://www.cnki.com.cn/Article/CJFDTOTAL-LDZK201204004.htm
    [27]
    廖青. 鄂尔多斯盆地长7段有效烃源岩及其控油作用[D]. 北京: 中国石油大学(北京), 2019.

    LIAO Qing. Effective source rock and its control to crude oil in the Chang 7 member of the Ordos Basin[D]. Beijing: China University of Petroleum (Beijing), 2019.
    [28]
    付金华, 郭正权, 邓秀芹. 鄂尔多斯盆地西南地区上三叠统延长组沉积相及石油地质意义[J]. 古地理学报, 2005, 7(1): 34-44. https://www.cnki.com.cn/Article/CJFDTOTAL-GDLX200501004.htm

    FU Jinhua, GUO Zhengquan, DENG Xiuqin, et al. Sedimentary facies of the Yanchang Formation of Upper Triassic and petroleum geological implication in southwestern Ordos Basin[J]. Journal of Palaeogeography, 2005, 7(1): 34-44. https://www.cnki.com.cn/Article/CJFDTOTAL-GDLX200501004.htm
    [29]
    王青春, 朱扬明, 贺萍, 等. 中性含氮化合物的演化及地化意义[J]. 地质地球化学, 2002, 30(4): 15-19. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ200204002.htm

    WANG Qingchun, ZHU Yangming, HE Ping, et al. Evolution of neutral nitrogen-containing compounds and geochemical significance[J]. Geology-Geochemistry, 2002, 30(4): 15-19. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ200204002.htm
    [30]
    张枝焕, 王铁冠, 吴水平, 等. 原油中部分吡咯类含氮化合物运移参数的适用性[J]. 成都理工大学学报(自然科学版), 2004, 31(2): 162-167. https://www.cnki.com.cn/Article/CJFDTOTAL-CDLG200402010.htm

    ZHANG Zhihuan, WANG Tieguan, WU Shuiping, et al. Discussion on effects of pyrrolic nitrogen compound parameters on petroleum migration[J]. Journal of Chengdu University of Technology(Science & Technology Edition), 2004, 31(2): 162-167. https://www.cnki.com.cn/Article/CJFDTOTAL-CDLG200402010.htm
    [31]
    张春明, 赵红静, 梅博文, 等. 微生物降解对原油中咔唑类化合物的影响[J]. 石油与天然气地质, 1999, 20(4): 341-343. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT199904015.htm

    ZHANG Chunming, ZHAO Hongjing, MEI Bowen, et al. Effect of biodegradation on carbazole compounds in crude oils[J]. Oil & Gas Geology, 1999, 20(4): 341-343. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT199904015.htm
    [32]
    王传远, 段毅, 杜建国. 母源、沉积环境和成熟度对中性含氮化合物分布的影响[J]. 新疆石油地质, 2008, 29(3): 299-302. https://www.cnki.com.cn/Article/CJFDTOTAL-XJSD200803006.htm

    WANG Chuanyuan, DUAN Yi, DU Jianguo. The effects of source rock, depositional environment and maturity on distribution of neutral nitrogen compounds[J]. Xinjiang Petroleum Geology, 2008, 29(3): 299-302. https://www.cnki.com.cn/Article/CJFDTOTAL-XJSD200803006.htm
    [33]
    LI Maowen, FOWLER M G, OBERMAJER M, et al. Geochemical characterization of Middle Devonian oils in NW Alberta, Canada: possible source and maturity effect on pyrrolic nitrogen compounds[J]. Organic Geochemistry, 1999, 30(9): 1039-1057.
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