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Volume 46 Issue 2
Mar.  2024
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Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2024  >  46(2): 402-411
ZHAO Shouyu, XU Yaohui, YAN Gang, HAN Xin, LIU Baolei, ZHONG Ming, LI Shanshan. Displacement simulation experiments of migration effect on carbazole parameters of crude oil[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(2): 402-411. doi: 10.11781/sysydz202402402
Citation: ZHAO Shouyu, XU Yaohui, YAN Gang, HAN Xin, LIU Baolei, ZHONG Ming, LI Shanshan. Displacement simulation experiments of migration effect on carbazole parameters of crude oil[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(2): 402-411. doi: 10.11781/sysydz202402402
shu

Displacement simulation experiments of migration effect on carbazole parameters of crude oil

doi: 10.11781/sysydz202402402
  • 1.

    Hubei Key Laboratory of Oil and Gas Geochemistry and Environment, College of Resources and Environment, Yangtze University, Wuhan, Hubei 430100, China

  • 2.

    Changqing Industrial Group Co., Ltd., PetroChina Changqing Oilfield Company, Xi'an, Shaanxi 710018, China

  • 3.

    Hubei Key Laboratory of Oil and Gas Drilling and Production Engineering, Yangtze University, Wuhan, Hubei 430100, China

  • 4.

    College of Energy and Resources, China University of Geosciences(Beijing), Beijing 100089, China

  • Received Date: 2023-06-09
  • Rev Recd Date: 2024-02-01
  • Publish Date: 2024-03-28
    Abstract
  • The investigation of oil and gas migration plays a vital role in the field of oil and gas exploration and development. Determining the direction and path of crude oil migration is challenging due to factors such as crude oil viscosity, complex chemical composition, and geological influences. Molecular geochemical parameters are a valuable tool for studying petroleum migration, although they can be affected by factors like compound formation, distribution, and maturation. One approach involves simulating these parameters under controlled laboratory conditions to isolate their individual effects. This study establishes a sandy-packed system to simulate oil-driven experiments and uses a C18 solid-phase extraction column to analyze carbazole compound fractions at different migration distances. The findings indicate that certain carbazole parameters, such as 1-/4-MCA, 1, 8-/1, 7-DMCA, 1, 8-/2, 4-DMCA, 1, 8-/2, 5-DMCA, and 1, 8-/2, 7-DMCA, increase significantly with transport distances. Notably, fully shielded and fully exposed isomers like 1, 8-/2, 4-DMCA and 1, 8-/2, 5-DMCA show enrichment levels of up to 63.97% and 35.50%, making them potential indicators of oil migration. However, parameters related to benzo [a]/[c] carbazole show inconsistencies with previous findings, likely due to intrinsic configurations and varying geological conditions that must be taken into account. The experimental results presented in this study offer insights for assessing specific reservoirs, with a recommendation to also consider molecular kinetics when selecting molecular parameters.

     

    • All authors disclose no relevant conflict of interests.
    The study was designed and the manuscript was drafted by ZHAO Shouyu, XU Yaohui and YAN Gang. The experiment was designed by LIU Baolei and ZHONG Ming. The experimental operation was made by YAN Gang. The proofreading of the manuscript was completed by HAN Xin and LI Shanshan. All the authors have read the last version of paper and consented for submission.
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