Volume 46 Issue 5
Sep.  2024
Turn off MathJax
Article Contents
ZHI Dongming, LENG Junying, XIE An, TANG Yong, HE Jinyi, HE Wenjun, LI Zhiming, ZOU Yang, ZHU Tao. Characteristics and occurrence states of shale biomarker compounds in Fengcheng Formation, Mahu Sag, Junggar Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(5): 954-964. doi: 10.11781/sysydz202405954
Citation: ZHI Dongming, LENG Junying, XIE An, TANG Yong, HE Jinyi, HE Wenjun, LI Zhiming, ZOU Yang, ZHU Tao. Characteristics and occurrence states of shale biomarker compounds in Fengcheng Formation, Mahu Sag, Junggar Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(5): 954-964. doi: 10.11781/sysydz202405954

Characteristics and occurrence states of shale biomarker compounds in Fengcheng Formation, Mahu Sag, Junggar Basin

doi: 10.11781/sysydz202405954
  • Received Date: 2024-04-19
  • Rev Recd Date: 2024-08-07
  • Publish Date: 2024-09-28
  • The characteristics of biomarker compounds and their occurrence states in different layers of the Permian Fengcheng Formation shale in Mahu Sag, Junggar Basin are poorly understood. By using experimental techniques such as rock pyrolysis, gas chromatography-mass spectrometry, fluorescence thin sections, and argon ion polishing electron microscopy, the material basis of hydrocarbon source rocks in different intervals, the distribution characteristics and significance of biomarker compounds, and different occurrence states of shale oil are clarified. This is of great significance for the next step in exploration and deployment in the Mahu Sag. The shale of the Fengcheng Formation in the Mahu Sag is mainly medium to good hydrocarbon source rocks, with type Ⅱ organic matter and in a mature evolutionary stage. The composition characteristics of biomarker compounds show high abundance of Pr and Ph, β-carotane, and C29 rearranged steranes. The C27-C28-C29 regular steranes exhibit an inverted "L" distribution, indicating that the organic matter is mainly contributed by lower aquatic organisms such as algae. Lower Pr/Ph ratios and higher gammacerane indices reflect a saline reducing sedimentary environment. Maturity parameters such as C31αβ22S/(22S+22R), C29M/C29H, and C29ββ/(ββ+αα) for hopanes and steranes indicate that the hydrocarbon source rocks are in the mature stage. In addition, the shale of the second member of the Fengcheng Formation has greater hydrocarbon generation potential and better source rock material basis than that in the first and third members. Meanwhile, biomarker compound parameters such as C20/C23TT, C21/C23TT, and Ga/C30H indicate that the second member has more contributions from algae and other organisms, and a more reducing and saline environment. The hydrocarbons in the second member are mainly in a free occurrence state, residing in intergranular and intragranular pores. The study shows that the second member of the Fengcheng Formation is more favorable for shale oil enrichment and preservation, showing a better prospect for shale oil exploration and development.

     

  • Author Ll Zhiming is an Editorial Board Member and an employee of the sponsor of this journal. LENG Junying and HE Jinyi are employees of the sponsor of this journal. They did not take part in peer review or decision making of this article.
    ZHI Dongming was responsible for the overall planning, structural design, and implementation of the paper. LENG Yunying was responsible for writing the paper. XIE An was responsible for the literature review. TANG Yong was responsible for the experimental design and comprehensive analysis of experimental results. HE Jinyi was responsible for data collection and analysis. HE Wenjun was responsible for technical support and selection of experimental methods. LI Zhiming was responsible for conducting experiments and analyzing the resulting data. ZOU Yang assisted with figure preparation. ZHU Tao was responsible for revising the paper. All authors have read the last version of the paper and consented to its submission.
  • loading
  • [1]
    陈建平, 王绪龙, 邓春萍, 等. 准噶尔盆地南缘油气生成与分布规律: 烃源岩地球化学特征与生烃史[J]. 石油学报, 2015, 36(7): 767-780.

    CHEN Jianping, WANG Xulong, DENG Chunping, et al. Geoche-mical features of source rocks in the southern margin, Junggar Basin, northwestern China[J]. Acta Petrolei Sinica, 2015, 36(7): 767-780.
    [2]
    唐勇, 曹剑, 何文军, 等. 从玛湖大油区发现看全油气系统地质理论发展趋势[J]. 新疆石油地质, 2021, 42(1): 1-9.

    TANG Yong, CAO Jian, HE Wenjun, et al. Development tendency of geological theory of total petroleum system: insights from the discovery of Mahu large oil province[J]. Xinjiang Petroleum Geology, 2021, 42(1): 1-9.
    [3]
    宋永, 杨智峰, 何文军, 等. 准噶尔盆地玛湖凹陷二叠系风城组碱湖型页岩油勘探进展[J]. 中国石油勘探, 2022, 27(1): 60-72.

    SONG Yong, YANG Zhifeng, HE Wenjun, et al. Exploration progress of alkaline lake type shale oil of the Permian Fengcheng Formation in Mahu Sag, Junggar Basin[J]. China Petroleum Exploration, 2022, 27(1): 60-72.
    [4]
    许琳, 常秋生, 冯玲丽, 等. 准噶尔盆地玛湖凹陷二叠系风城组页岩油储层特征及控制因素[J]. 中国石油勘探, 2019, 24(5): 649-660.

    XU Lin, CHANG Qiusheng, FENG Lingli, et al. The reservoir characteristics and control factors of shale oil in Permian Fengcheng Formation of Mahu sag, Junggar Basin[J]. China Petroleum Exploration, 2019, 24(5): 649-660.
    [5]
    杨帆, 孟鑫, 王先虎, 等. 玛页1井风城组页岩微观孔隙特征及其影响因素[J]. 新疆石油地质, 2022, 43(1): 1-10.

    YANG Fan, MENG Xin, WANG Xianhu, et al. Micro-pore characteristics and influencing factors of Fengcheng Formation shale in well Maye-1[J]. Xinjiang Petroleum Geology, 2022, 43(1): 1-10.
    [6]
    支东明, 唐勇, 郑孟林, 等. 准噶尔盆地玛湖凹陷风城组页岩油藏地质特征与成藏控制因素[J]. 中国石油勘探, 2019, 24(5): 615-623.

    ZHI Dongming, TANG Yong, ZHENG Menglin, et al. Geological characteristics and accumulation controlling factors of shale reservoirs in Fengcheng Formation, Mahu Sag, Junggar Basin[J]. China Petroleum Exploration, 2019, 24(5): 615-623.
    [7]
    姜福杰, 黄任达, 胡涛, 等. 准噶尔盆地玛湖凹陷风城组页岩油地质特征与分级评价[J]. 石油学报, 2022, 43(7): 899-911.

    JIANG Fujie, HUANG Renda, HU Tao, et al. Geological characteristics and classification evaluation of shale oil in Fengcheng Formation in Mahu Sag, Junggar Basin[J]. Acta Petrolei Sinica, 2022, 43(7): 899-911.
    [8]
    钱门辉, 王绪龙, 黎茂稳, 等. 玛页1井风城组页岩含油性与烃类赋存状态[J]. 新疆石油地质, 2022, 43(6): 693-703.

    QIAN Menhui, WANG Xulong, LI Maowen, et al. Oil-bearing properties and hydrocarbon occurrence states of Fengcheng Formation shale in well Maye-1, Mahu Sag[J]. Xinjiang Petroleum Geology, 2022, 43(6): 693-703.
    [9]
    金之钧, 梁新平, 王小军, 等. 玛湖凹陷风城组页岩油富集机制与甜点段优选[J]. 新疆石油地质, 2022, 43(6): 631-639.

    JIN Zhijun, LIANG Xinping, WANG Xiaojun, et al. Shale oil enrichment mechanism and sweet spot selection of Fengcheng Formation in Mahu Sag, Junggar Basin[J]. Xinjiang Petroleum Geology, 2022, 43(6): 631-639.
    [10]
    支东明, 唐勇, 何文军, 等. 准噶尔盆地玛湖凹陷风城组常规—非常规油气有序共生与全油气系统成藏模式[J]. 石油勘探与开发, 2021, 48(1): 38-51.

    ZHI Dongming, TANG Yong, HE Wenjun, et al. Orderly coexistence and accumulation models of conventional and unconventional hydrocarbons in Lower Permian Fengcheng Formation, Mahu Sag, Junggar Basin[J]. Petroleum Exploration and Deve-lopment, 2021, 48(1): 38-51.
    [11]
    张志杰, 袁选俊, 汪梦诗, 等. 准噶尔盆地玛湖凹陷二叠系风城组碱湖沉积特征与古环境演化[J]. 石油勘探与开发, 2018, 45(6): 972-984.

    ZHANG Zhijie, YUAN Xuanjun, WANG Mengshi, et al. Alkaline- lacustrine deposition and paleoenvironmental evolution in Permian Fengcheng Formation at the Mahu Sag, Junggar Basin, NW China[J]. Petroleum Exploration and Development, 2018, 45(6): 972-984.
    [12]
    钱永新, 邹阳, 赵辛楣, 等. 准噶尔盆地玛湖凹陷玛页1井二叠系风城组全井段岩心剖析与油气地质意义[J]. 油气藏评价与开发, 2022, 12(1): 204-214.

    QIAN Yongxin, ZOU Yang, ZHAO Xinmei, et al. Full core analysis and petroleum geological significance of Permian Fengcheng Formation in well-MY1, Mahu Sag[J]. Reservoir Evaluation and Development, 2022, 12(1): 204-214.
    [13]
    邹阳, 韦盼云, 曹元婷, 等. 碱湖型页岩油"甜点"分类与主控因素: 以准噶尔盆地风城组为例[J]. 石油学报, 2023, 44(3): 458-470.

    ZOU Yang, WEI Panyun, CAO Yuanting, et al. Classification and main controlling factors of sweet spots of alkaline lake type shale oil: a case study of Fengcheng Formation in Junggar Basin[J]. Acta Petrolei Sinica, 2023, 44(3): 458-470.
    [14]
    PETERS K E. Guidelines for evaluating petroleum source rock using programmed pyrolysis[J]. AAPG Bulletin, 1986, 70(3): 318-329.
    [15]
    CRANWELL P A, EGLINTON G, ROBINSON N. Lipids of aquatic organisms as potential contributors to lacustrine sediments—Ⅱ[J]. Organic Geochemistry, 1987, 11(6): 513-527.
    [16]
    DIDYK B M, SIMONEIT B R T, BRASSELL S C, et al. Organic geochemical indicators of palaeoenvironmental conditions of sedimentation[J]. Nature, 1978, 272(5650): 216-222.
    [17]
    DURAND B, ESPITALIÉ J. Geochemical studies on the organic matter from the Douala Basin (Cameroon)—Ⅱ. Evolution of kerogen[J]. Geochimica et Cosmochimica Acta, 1976, 40(7): 801-808.
    [18]
    KOOPMANS M P, DE LEEUW J W, SINNINGHE DAMSTÉ J S. Novel cyclised and aromatised diagenetic products of β-carotene in the Green River shale[J]. Organic Geochemistry, 1997, 26(7/8): 451-466.
    [19]
    LUO Qingyong, ZHONG Ningning, LIU Yan, et al. Organic geoche-mical characteristics and accumulation of the organic matter in the Jurassic to Cretaceous sediments of the Saihantala Sag, Erlian Basin, China[J]. Marine and Petroleum Geology, 2018, 92: 855-867.
    [20]
    HANSON A D, RITTS B D, ZINNIKER D, et al. Upper Oligocene lacustrine source rocks and petroleum systems of the northern Qaidam Basin, northwest China[J]. AAPG Bulletin, 2001, 85(4): 601-619.
    [21]
    XU Huiyuan, GEORGE S C, HOU Dujie. The occurrence of isorenieratane and 24-n-propylcholestanes in Paleogene lacustrine source rocks from the Dongying Depression, Bohai Bay Basin: implications for bacterial sulfate reduction, photic zone euxinia and seawater incursions[J]. Organic Geochemistry, 2019, 127: 59-80.
    [22]
    ATOYEBI A O, ADEKOLA S A, AKINLUA A. Tricyclic terpane geochemistry of source rocks from northwestern and central Niger Delta[J]. Petroleum Science and Technology, 2017, 35(22): 2094-2101.
    [23]
    SIMONEIT B R T, LEIF R N, RADLER DE AQUINO NETO F, et al. On the presence of tricyclic terpane hydrocarbons in Permian tasmanite algae[J]. Naturwissenschaften, 1990, 77(8): 380-383.
    [24]
    AQUINO NETO F R, RESTLE A, CONNAN J, et al. Novel tricyclic terpanes (C19, C20) in sediments and petroleums[J]. Tetrahedron Letters, 1982, 23(19): 2027-2030.
    [25]
    PHILP R P, GILBERT T D. Biomarker distributions in Australian oils predominantly derived from terrigenous source material[J]. Organic Geochemistry, 1986, 10(1/3): 73-84.
    [26]
    CLARK J P, PHILP R P. Geochemical characterization of evaporite and carbonate depositional environments and correlation of asso-ciated crude oils in the Black Creek Basin, Alberta[J]. Bulletin of Canadian Petroleum Geology, 1989, 37(4): 401-416.
    [27]
    SUMMONS R E, JAHNKE L L, ROKSANDIC Z. Carbon isotopic fractionation in lipids from methanotrophic bacteria: relevance for interpretation of the geochemical record of biomarkers[J]. Geochimica et Cosmochimica Acta, 1994, 58(13): 2853-2863.
    [28]
    OURISSON G, ROHMER M, PORALLA K. Prokaryotic hopanoids and other polyterpenoid sterol surrogates[J]. Annual Review of Microbiology, 1987, 41: 301-333.
    [29]
    张立平, 黄第藩, 廖志勤. 伽马蜡烷: 水体分层的地球化学标志[J]. 沉积学报, 1999, 17(1): 136-140.

    ZHANG Liping, HUANG Difan, LIAO Zhiqin. Gammacerane geoche-mical indicator of water column stratification[J]. Acta Sedimentolo-gica Sinica, 1999, 17(1): 136-140.
    [30]
    HOLBA A G, DZOU L I, WOOD G D, et al. Application of tetracyclic polyprenoids as indicators of input from fresh-brackish water environments[J]. Organic Geochemistry, 2003, 34(3): 441-469.
    [31]
    VOLKMAN J K. A review of sterol markers for marine and terrigenous organic matter[J]. Organic Geochemistry, 1986, 9(2): 83-99.
    [32]
    HAO Fang, ZHOU Xinhuai, ZHU Yangming, et al. Lacustrine source rock deposition in response to co-evolution of environments and organisms controlled by tectonic subsidence and climate, Bohai Bay Basin, China[J]. Organic Geochemistry, 2011, 42(4): 323-339.
    [33]
    MICHAEL MOLDOWAN J, SUNDARARAMAN P, SCHOELL M. Sensitivity of biomarker properties to depositional environment and/or source input in the Lower Toarcian of SW-Germany[J]. Organic Geochemistry, 1986, 10(4/6): 915-926.
    [34]
    STROBL S A I, SACHSENHOFER R F, BECHTEL A, et al. Depositional environment of oil shale within the Eocene Jijuntun Formation in the Fushun Basin (NE China)[J]. Marine and Petroleum Geology, 2014, 56: 166-183.
    [35]
    王小军, 王婷婷, 曹剑. 玛湖凹陷风城组碱湖烃源岩基本特征及其高效生烃[J]. 新疆石油地质, 2018, 39(1): 9-15.

    WANG Xiaojun, WANG Tingting, CAO Jian. Basic characteristics and highly efficient hydrocarbon generation of alkaline-lacustrine source rocks in Fengcheng Formation of Mahu Sag[J]. Xinjiang Petroleum Geology, 2018, 39(1): 9-15.
    [36]
    朱扬明, 张春明, 张敏, 等. 沉积环境的氧化还原性对重排甾烷形成的作用[J]. 沉积学报, 1997, 15(4): 103-108.

    ZHU Yangming, ZHANG Chunming, ZHANG Min, et al. The effect of oxidation-reduction nature of depositional environments on the formation of diasteranes[J]. Acta Sedimentologica Sinica, 1997, 15(4): 103-108.
    [37]
    包建平, 王志峰, 朱翠山, 等. 柴达木盆地东坪地区一类新的原油及其地球化学特征[J]. 沉积学报, 2018, 36(4): 829-841.

    BAO Jianping, WANG Zhifeng, ZHU Cuishan, et al. A new kind of crude oils and the geochemical characteristics in the Dongping area, Qaidam Basin[J]. Acta Sedimentologica Sinica, 2018, 36(4): 829-841.
    [38]
    KUMA R, HASEGAWA H, YAMAMOTO K, et al. Biogenically induced bedded chert formation in the alkaline palaeo-lake of the Green River Formation[J]. Scientific Reports, 2019, 9(1): 16448.
    [39]
    YU Kuanhong, ZHANG Zhijie, CAO Yingchang, et al. Origin of biogenic-induced cherts from Permian alkaline saline lake deposits in the NW Junggar Basin, NW China: implications for hydrocarbon exploration[J]. Journal of Asian Earth Sciences, 2021, 211: 104712.
    [40]
    XIA Liuwen, CAO Jian, LEE C, et al. A new constraint on the antiquity of ancient haloalkaliphilic green algae that flourished in a ca. 300 Ma Paleozoic lake[J]. Geobiology, 2021, 19(2): 147-161.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(9)  / Tables(1)

    Article Metrics

    Article views (144) PDF downloads(37) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return