GEOCHEMICAL CHARACTERISTICS AND SOURCE OF MIDDLE JURASSIC OIL FROM GUANDU STRUCTURE IN THE SOUTHEASTERN SICHUAN BASIN
-
摘要: 根据轻烃、饱和烃、芳烃和碳同位素的系统分析资料,全面剖析了川东南地区官渡构造中侏罗统原油的地球化学特征,并通过油源对比确定了其主力烃源层.研究结果表明,该原油的C5—C8轻烃中以正构烷烃占优势,异构和环烷烃相对较少,几乎不含苯和甲苯,正庚烷明显高于甲基环已烷;其Pr/Ph值较低(1.56),C27—C29甾烷呈"V"字型分布,伽马蜡烷较高,表征油源岩为较深湖相沉积,成油母质生源构成中水生生物占有较高比例;正烷烃系列分布轮廓线呈上凸状,且碳同位素随碳数增加呈变轻趋势,具有一般陆相原油的特征;经轻烃、生物标志物参数对比,认为该原油与本区的上三叠统须家河组沥青和天然气没有成因上的联系,其油源来自下侏罗统烃源层.Abstract: Based on the systematic analytical data of light hydrocarbon,saturate,aromatic fractions and carbon isotopes,the geochemical characteristics of Middle Jurassic oil from Guandu structure in the southeastern Sichuan Basin was investigated,and the source rock for the oil was determined by oil/ source rock correlation.The studied results reveal the oil shows a dominance of n-alkanes,low amount of branched/cyclic hydrocarbon and a lack of benzene and toluene with a predominance of heptane over methylcyclohexane in C5-C8 light hydrocarbons.Its relative low Pr/Ph (1.56),"V" shaped distribution of C27-C29 steranes and enhanced gammacerane indicate a profundal lacustrine source rock with relatively high contribution of aquatic organisms to deposited original organic matter The studied oil exhibits common features for a terrestrial oil,as reflected by its waxy n-alkane distribution and the isotope profile showing a trend toward isotopically light values with increasing n-alkane chain length.According to the correlations based on the parameters of light hydrocarbon and biomarkers,the oil is believed to be not in origin associated with the natural gas and asphalts in Xujiahe stratum (Upper Triassic),and is determined to be derived from Lower Jurassic source rock.
-
Key words:
- crude oil /
- light hydrocarbon /
- carbon isotope /
- Middle Jurassic /
- Guandu structure /
- the southeastern Sichuan Basin
-
[1] 黄世伟,张延生,王顺玉等.四川盆地赤水地区上三叠统须家河组烃源岩特征及天然气成因探讨[J].天然气地球科学,2004,15(6):590~592 [2] 林壬子.轻烃技术在油气勘探中的应用[M].武汉:中国地质大学出版社,1992.144~154 [3] 王顺玉,王廷栋.四川盆地凝析油的地球化学特征[J].石油与天然气地质,1990,11(4):454~461 [4] Alexander R,Kagi R I,Noble R,et al.Identification of some bicyclic alkanes in petroleum[A].Schenck P A,de Leeuw J W,Lijmbach G W M.eds.Advances in Organic Geochemistry 1983[C].Oxford:Pergamon Press,1984.63~72 [5] Damste J S S,Kenig F,Koopmans M P,et al.Evidence for gammacerane as an indicator of water column stratification[J].Geochimica et Cosmochimica Acta,1995,59(9):1895~1900 [6] 张义纲.油气地球化学的若干展望[J].石油实验地质,2005,27(5):484~489 [7] Murray A P,Summons R E,Boreham C J,et al.Biomarker and n-alkane isotope profiles for Tertiary oils:relationship to source rock depositional setting[J].Organic Geochemistry,1994,22(3-5):521~542 [8] Zhu Yangming,Weng Huanxin,Su Aiguo,et al.Geochemical characteristics of Tertiary saline lacustrine oils in the western Qaidam Basin,Northwest China[J].Applied Geochemistry,2005,20 (10):1875~1889 [9] Thompson K F M.Classification and thermal history of petroleum based on light hydrocarbons[J].Geochimica et Cosmochimica Acta,1983,47(2):303~316 [10] 范善发,周中毅.塔里木古地温与油气[M].北京:科学出版社,1990.52~55 [11] Radke M,Welte D H.The methylphenanthrene index (MPI):A maturity parameter based on aromatic hydrocarbons[A].Bjorфy M.ed.Advances in Organic Geochemistry 1981[C].New York:Wiley,1983.504~512 [12] Kvalheim O M,Christy A A,Telnaes N,et al.Maturity determination of organic matter in coals using the methylphenanthrene distribution[J].Geochimica et Cosmochimica Acta,1987,51(7):1883~1888 [13] Mango F D.The light hydrocarbons in petroleum:a critical review[J].Organic Geochemistry,1997,26(7/8):417~440 [14] Ten Haven H L.Applications and limitations of Mango's light hydrocarbon parameters in petroleum correlation studies[J].Organic Geochemistry,1996,24(10-11):957~976 [15] 王金琪.四川盆地油气地质特征--纪念黄汲清先生百岁诞辰[J].石油实验地质,2004,26(2):115~120 -
计量
- 文章访问数: 622
- HTML全文浏览量: 54
- PDF下载量: 242
- 被引次数: 0