INVESTIGATION OF THE SOLID BITUMEN BY CHEMICAL DEGRADATION METHOD——A CASE STUDY OF THE SOLID BITUMEN FROM THE NORTHEASTERN SICHUAN BASIN
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摘要: 采用选择性化学降解方法并结合多种有机地球化学测定手段对川东北固体沥青的母质来源及成因进行了研究。与固体沥青中可溶有机质的对比结果表明,化学降解释放出的生物标志化合物具有相对低的热演化程度,可以反映早期的母质特征。生物标志化合物参数和沥青反射率数据表明此类固体沥青经历了相对较高的热演化作用,并可能遭受了一定的生物降解。由生物标志化合物推测该样品固体沥青的母源以菌藻类低等水生生物为主,且沉积在一个具有一定咸度或水体较深的环境。Abstract: An investigation on the parent material and the genesis of the solid bitumen from the northeas-tern Sichuan Basin has been carried out by using the selective chemical degradation method combined with various organic geochemical analysis and measurement techniques.Compared with the soluble organic matter extracted from the solid bitumen sample,the biomarker obtained by the chemical degradation method has relatively lower thermal maturity,and can reflect the characteristics of the parent materials of the early evolution stage.The data of the biomarker parameters and the bitumen reflectivity indicate that the solid bitumen has experienced a relatively high thermal evolution,and possibly has under-gone a certain degree of biodegradation.Based on the biomarker distribution of the solid bitumen in the sample,it can be inferred that the precursor of the solid bitumen dominantly derives from the low-level aquatic biota such as the bacteria and the algae,which were deposited under a brackish or relatively deep water environment.
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Key words:
- selective chemical degradation /
- biomarker solid bitumen /
- the Sichuan Basin /
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[1] 马永生,傅强,郭彤楼等.川东北地区普光气田长兴-飞仙关气藏成藏模式与成藏过程[J].石油实验地质,2005,27(5):455~461 [2] 蔡立国,饶丹,潘文蕾等.川东北地区普光气田成藏模式研究[J].石油实验地质,2005,27(5):462~467 [3] 谢增业,田世澄,魏国齐等.川东北飞仙关组储层沥青与古油藏研究[J].天然气地球科学,2005,16(3):283~287 [4] 谢增业,魏国齐,李剑等.川东北飞仙关组鲕滩储层沥青与天然气成藏过程[J].天然气工业,2004,24(12):17~19 [5] 刘德汉,肖贤明,熊永强等.四川东部飞仙关组鲕滩气藏储层含自然硫不混溶包裹体及硫化氢成因研究[J].中国科学(D辑),2006,36(6):520~532 [6] 林峰,王廷栋,代鸿鸣等.四川盆地碳酸盐岩储层中固体运移沥青的性质和成因[J].矿物岩石地球化学通报,1998,17(3):174~178 [7] Peng P A,Morales-Izquierdo A,Hogg A,et al.Molecular structure of athabasca asphaltene:Sulfide,ether,and ester linkages[J].Energy&Fuels,1997,11:1171~1187 [8] 朱军,李术元,郭绍辉.生物降解原油研究的新方法[J].燃料化学学报,2003,31(1):1~5 [9] Jacob H.Classification,structure,genesis and practical importance of natural solid oil bitumen("migrabitumen")[J].International Journal of Coal Geology,1989,11(1):65~79 [10] 范璞.指示沉积古环境的生物标志化合物[A].见:中国科学院兰州地质研究所.生物、气体地球化学开放研究实验室研究年报[R].兰州:甘肃科学技术出版社,1987.47~87 [11] Sinninghe Damste J S,Kenig F,Koopmans M P,et al.Evidence for cammacerane as an indicator of water.Column Stratification[J].Geochim et Cosmechim Acta,1995,59 (9):1895~1900 [12] 胡伯良.塔里木盆地北部沙雅隆起雅克拉构造油气化学特征及其生成、运移及聚集[J].石油实验地质,1990,12 (3):232~247 [13] 李丕龙,于建国,付瑾平等.陆相断陷盆地油气地质与勘探(三)[M].北京:石油工业出版社,2003.84~108
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