Advanced Search
Volume 25 Issue 1
. 
Turn off MathJax
Article Contents
Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2003  >  25(1): 45-52
LIAO Ze-wen, GENG An-song. CHARACTERISTICS OF N-HEPTANE-SOLUBLE COMPONENTS IN THE MILD CHEMICAL OXIDATION DEGRADED PRODUCTS OF ASPHALTENE[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2003, 25(1): 45-52. doi: 10.11781/sysydz200301045
Citation: LIAO Ze-wen, GENG An-song. CHARACTERISTICS OF N-HEPTANE-SOLUBLE COMPONENTS IN THE MILD CHEMICAL OXIDATION DEGRADED PRODUCTS OF ASPHALTENE[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2003, 25(1): 45-52. doi: 10.11781/sysydz200301045
shu

CHARACTERISTICS OF N-HEPTANE-SOLUBLE COMPONENTS IN THE MILD CHEMICAL OXIDATION DEGRADED PRODUCTS OF ASPHALTENE

doi: 10.11781/sysydz200301045

  • State Key Laboratory of Organic Geochemisty, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640, China

  • Received Date: 2001-09-17
  • Rev Recd Date: 2002-10-17
  • Publish Date: 2003-01-25
    Abstract
  • Some hydrocarbon components adsorbed and included in the molecular skeleton of asphaltene.were subjected less reconstruction from the paulopost evolution of oil pools,and were thought to be primary and containing important organic geochemical information.The experimental results showed that these primary components in the molecular skeleton of asphaltene can be released rationally by mild chemical oxidation degradation treatment,and can obtained well application in oiloil correlation,oilsource correlation,the sedimentary environments of organic matter in oil pools,the secondary reconstruction of oil pools and other researches.To some oil pools subjected serious paulopost degradation,these components especially possessed important significance in the study of restoring original organic geochemical information.

     

    • FullText(HTML)
  • loading
    • References(25)
  • [1]
    Speight J G.Asphaltenes in crude oil and bitumen:structure and dispersion[J].Adv Chem Ser,1996,251(Suspensions:Fundamentals and Applications in the Petroleum Industry):377-401.
    [2]
    Mansoori G A.Modeling of asphaltene and other heavy organic depositions[J].Journal of Petroleum Science and Engineering,1997,17:101-111.
    [3]
    Strausz O P,Mojelsky T W,Faraji F,et al.Additional structural details on Athabasca asphaltene and their ramifications[J].Energy &Fuels.1999,13(a):207-227.
    [4]
    Strausz O P,Mojelsky T W,Lown E M,et al.Structural features of Boscan and Duri asphaltene[J].Energy &Fuels,1999,13(b):228-247.
    [5]
    Bergmann U,Mullins O,Cramer S P.X-ray Raman spectroscopy of carbon in asphaltene:light element characterization with bulk sensitivity[J].Anal Chem,2000,72(11):2609-2612.
    [6]
    Calemma V,Rausa R,D'Antona P.et al.Characterization of asphaltenes molecular structure[J].Energy &Fuels,1998,12:422-428.
    [7]
    Acevedo S,Escobar G,Ranaudo M N,et al.Observations about the structure and dispersion of petroleum asphaltenes aggregates obtained from dialysis fractionation and characterization[J].Energy &Fuels,1997,11:774-778.
    [8]
    Mujica V,Nieto P,Puerta L,et al.Caging of molecules by asphaltenes:a model for free radical preservation in crude oils[J].Energy &Fuel,2000,14(3),632-639.
    [9]
    Murgich J,Abanero J A,Strausz O P.Molecular recognition in aggregates formed by asphaltene and resin molecules from the Athabasca oil sand[J].Energy &Fuel,1999,13(2):278-286.
    [10]
    Schabron J F,Speight J G.The solubility and three-dimensional structure of asphaltenes[J].Petroleum Science and Technology,1998,16(3-4):361-375.
    [11]
    Behar F,Pelet R,Roucache J.Geochemistry of asphaltenes[J].Org Geochem,1984,16:587-595.
    [12]
    Ekweozor C M.Tricyclic terpenoid derivatives from chemical degradation reactions of asphaltenes[J].Org Geochem,1984,6:51-61.
    [13]
    Ekweozor C M.Characterisation of the non-asphaltene pro-ducts of mild chemical degradation of asphaltenes[J].Org Geochem,1986,10:1053-1058.
    [14]
    Rubinstein I'Strausz O P.Thermal treatment of the Athabasca oil sand bitumen and its component parts[J].Geochimica et Cosmochimica Acta,1979,43:1887-1893.
    [15]
    Wilhelms A,Larter S R.Characterization of asphaltenes by pyrolysis-field ionization mass spectrometry-some observations[J].Org Geochem,1993,20(7):1049-1062.
    [16]
    Rubinstein I,Spyckerelle C,Strausz O P.Pyrolysis of asphaltenes:a source of geochemical information[J].Geochi-mica et Cosmochimica Acta,1979,43:1-6.
    [17]
    Magnier C,Huc A Y.Pyrolysis of asphaltenes as a tool for reservoir geochemistry[J].Org Geochem,1995,23:963-967.
    [18]
    Jones D M,Douglas A G,Connan J.Hydrous pyrolysis of asphaltenes and polar fractions of biodegraded oils[J].Org Geochem,1988,13:981-993.
    [19]
    Liao Zewen,Geng Ansong.Study of pyrolysis kinetics of asphaltenes in Silurian oilsands in the Tarim basin [J].Acta Geological Sinica,2000,74(3):680-684.
    [20]
    熊永强,耿安松.辽河油田生物降解原油沥青质热解产物中单体化合物碳同位素组成[J].地球化学,1998,27(6):532-536.
    [21]
    Geng Ansong,Liao Zewen.Kinetic studies on the pyrolysis of asphaltenes from different types of kerogens [J].Chinese Science Bulletin,2000,45(Supplement):53-59.
    [22]
    Anonymous.Stabilization oils to minimize asphaltene deposition[J].Research Disclosure,2000,43272:686-689.
    [23]
    Laux H,Rahimian I,Butz T.Theoretical and practical approach to the selection of asphaltene dispersing agents[J].Fuel Processing Technology,2000,67:79-89.
    [24]
    Pan H,Firoozabadi A.Thermodynamic micellization model for asphaltene precipitation inhibition[J].AIChE,2000,46(2):416-426.
    [25]
    Peters K E,Moldowan J M.The Biomarker Guide:Interpreting Molecular Fossils in Petroleum and Ancient Sediments[M].Pretice Hall Inc,1993.79-188.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Citation
    XML
    PDF-CN

    Article Metrics

    Article views (776) PDF downloads(443) Cited by()
    Proportional views
    Related

    Website Copyright © Wuxi Research Institute of Petroleum Geology, SINOPEC 苏ICP备15009037号 苏公网安备32021102000780号

    Address：No. 2060, Lihu Avenue, Wuxi, Jiangsu   (214126) Tel：0510-68787204，68787203 Fax：0510-68787113 Email：sysydz.syky@sinopec.com

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return