XIONG Yong-qiang, ZHANG Hai-zu, GENG An-song. VARIATION OF CARBON ISOTOPIC COMPOSITION OF KEROGEN DURING THERMAL EVOLUTION[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2004, 26(5): 484-487. doi: 10.11781/sysydz200405484
Citation: XIONG Yong-qiang, ZHANG Hai-zu, GENG An-song. VARIATION OF CARBON ISOTOPIC COMPOSITION OF KEROGEN DURING THERMAL EVOLUTION[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2004, 26(5): 484-487. doi: 10.11781/sysydz200405484

VARIATION OF CARBON ISOTOPIC COMPOSITION OF KEROGEN DURING THERMAL EVOLUTION

doi: 10.11781/sysydz200405484
  • Received Date: 2004-01-18
  • Rev Recd Date: 2004-07-26
  • Publish Date: 2004-09-25
  • Purpose of this study is to reveal the variation characteristics of kerogen during thermal evolution by determining the residual rate of kerogen and the carbon isotopic composition of residual kerogen at (different thermal) (evolution) stages, thus providing evidence of carbon isotope for quantitative identification and assessment of effective gas source rock. The result indicates that, at the early stage of methane (generation) (Ro1.5%), kerogen (obviously) enriches in 13C with the increasing of thermal evolution, up to 3.8‰. However, when Ro reaches 1.5%-2%, δ13C values of residual kerogen display a trend of slight depletion in 13C, varying within about 2‰. When the thermal maturity is higher (Ro2%), the variation of carbon isotopic composition is less than 0.8‰ for residual kerogen.

     

  • loading
  • [1]
    熊永强,耿安松,王云鹏等. 干酪根二次生烃动力学模拟实验研究[J]. 中国科学(D辑),2001,31(4):315~320
    [2]
    熊永强,耿安松,刘金钟等. 生烃动力学模拟实验结合GC-IRMS测定在有效气源岩判识中的应用[J]. 地球化学,2002,31(1):21~25
    [3]
    Lorant F, Behar F,Vandenbroucke M. Methane generation from methylated aromatics:kinetic study and carbon isotope modeling[J]. Energy and Fuels, 2000, 14(6):1 143~1 155
    [4]
    Rooney M A, Claypool G E, Chung H M. Modeling thermogenic gas generation using carbon isotope ratios of natural gas hydrocarbons[J]. Chem Geol,1995,126(3~4):219~232
    [5]
    Cramer B, Krooss B M, Littke R. Modelling isotope fractionation during primary cracking of natural gas: a reaction kinetic approach[J]. Chem Geol,1998,149(3~4):235~250
    [6]
    Lorant F, Prinzhofer A, Behar F, et al. Carbon isotopic and mole-cular constrains on the formation and the expulsion of thermogenic hydrocarbon gases[J]. Chem Geol,1998,147(3~4):249~264
    [7]
    陈红汉,孙永传,张启明. 应用δ13C瑞利分馏模型判断气藏运聚过程[J]. 石油勘探与开发,1995,22(2):29~33
    [8]
    傅家谟,秦匡宗. 干酪根地球化学[M]. 广州:广东科技出版社,1995. 251~295
    [9]
    Qin K Z, Chen D Y,Li Z G. A new method to estimate the oil and gas potentials of coals and kerogens by solid state 13C NMR spectroscopy[J]. Org Geochem,1991,17(6):865~872
    [10]
    Clayton C J. Effect of maturity on carbon isotope ratios of oils and condensates[J]. Org Geochem,1991,17(6):887~899
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (1037) PDF downloads(533) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return