Advanced Search
Volume 29 Issue 2
. 
Turn off MathJax
Article Contents
Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2007  >  29(2): 199-202
Liu JinPing, Geng Ansong, Lu Jialan, Wang Tongshan, Yang Chupeng, Jin Zhaoxun. THE INFLUENCES OF MATURATION AND WATER IN THE ISOTOPIC COMPOSITIONS OF PYROLYSIS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2007, 29(2): 199-202. doi: 10.11781/sysydz200702199
Citation: Liu JinPing, Geng Ansong, Lu Jialan, Wang Tongshan, Yang Chupeng, Jin Zhaoxun. THE INFLUENCES OF MATURATION AND WATER IN THE ISOTOPIC COMPOSITIONS OF PYROLYSIS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2007, 29(2): 199-202. doi: 10.11781/sysydz200702199
shu

THE INFLUENCES OF MATURATION AND WATER IN THE ISOTOPIC COMPOSITIONS OF PYROLYSIS

doi: 10.11781/sysydz200702199
  • 1.

    The State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640, China

  • 2. Guangzhou Marine Geology Survey, Guangzhou, Guangdong 510760, China

  • 3. Liaohe Oil Field, PetroChina, Panjin, Liaoning 124114, China

  • Received Date: 2006-06-12
  • Rev Recd Date: 2007-02-09
  • Publish Date: 2007-03-28
    Abstract
  • In order to characterize the influences of maturation and water in the hydrogen isotopic compositions of individual n-alkanes from the pyrolysis,the simulation test of typeⅡsource rock was made by high-pressure autoclave.The analytical results indicate that in the condition of non-hydrous pyrolysis,with the rise of temperature(290～400℃),the individual n-alkanes have the shift toward enriched hydrogen,the difference is over 20‰.But in hydrous pyrolysis,the hydrogen isotopic fractionation is smaller because the lower maturation at the same temperature.Moreover,water has no obvious effect on the hydrogen isotopic compositions of individual n-alkanes in the simulation test.So,the hydrogenisotopic compositions of lipid biomarkers were not obviously influenced by maturation and the hydrogen isotopic exchange during diagenesis.The hydrogen isotopes of lipid biomarkers from source rock can be used to discuss the differences of source rocks and depositional environments and to correlate oil/oil and oil/source.

     

    • FullText(HTML)
  • loading
    • References(22)
  • [1]
    王大锐.氢同位素分析在油气勘探中的新进展[J].石油知识,1992,(1):11～12
    [2]
    Andsersen N,Paul H A,Bernasconi S M,et al.Large and rapid climate variability dunng the Messinian salinity crisis:evidence from deuterium concentrations of individual biomarkers[J].Geology,2001,29:799～802
    [3]
    Huang Y,Shuman B,Wang Y,et al.Hydrogen isotope ratios of palmitic acid in lacustrine sediments record late quaternary climate variations[J].Geology,2002,30:1103～1106
    [4]
    IA M,Huang Y,Obermajer M,et al.Hydrogen isotopic cornpositions of individual alkanes as a new approach to petroleum correlation:case studies from the Western Canada Sedimentary Basin[J].Organic Geochemistry,2001,32:1387～1399
    [5]
    Liu W,Huang Y.Compound specific D/H ratios and molecular distributions of higher plant leaf waxes as novel paleoenvironmental indicators in the Chinese Loess Plateau[J].Organic Geochemistry,2005,36:851～860
    [6]
    Saehse D,Radke J,Gaupp R,et al.Reconstruction of palaeohydrological conditions in a lagoon during the 2nd Zechstein cycle through simultaneous use of δD values of individual n-alkanes and δ18 O and δ13C values of carbons[J].International Journal of Earth Scienccs,2004,93:554～564
    [7]
    Sachse D,Radke J,Gleixner G.Hydrogen isotope ratios of recent lacustrine sedimentary n-alkanes record modern climate variability[J].Geochimiea et Cosmochimica Acta,2004,68:4877～4889
    [8]
    Sauer P T,Eglinton T I,Hayes J M,et al.Compound-specific D/H ratios of lipid biomarkers from sediments as a proxy for environmental and climatic conditions[J].Geochimica et Cosmoehimica Acta,2001,65:213～222
    [9]
    Xiong Y,Gang A,Pan C,et al.Characterization of hydrogen isotopic composition of individual n-alkanes in terrestrial source rocks[J].Applied Geochemistry,2005,20:455～463
    [10]
    Yang H,Huang Y S.Preservation of lipid hydrogen isotope ratios in Miocene lacustrine sediments and plant fossils at Clarkia,north Idaho,USA[J].Organic Geochemistry,2003,34:413～423
    [11]
    Xie S,Nott C J,Avsejs L A,et al.Palaeoclimate records in compound-specific δD values of a lipid biomarker in ombrotrophic peat[J].Organic Geochemistry,2000,31:1053～1057
    [12]
    Dawson D,Grice K,Alexander R.Effect of maturation on the indigenous δD signatures of individual hydrocarbons in sediments and crude oils from the Perth Basin(Western Australia)[J].Organic Geochemistry,2005,36(1):95～104
    [13]
    Sessions A L,Burgoyne T W,Sehimmelmann A,et al.Fractionation of hydrogen isotopes in lipid biosynthesis[J].Organic Geochemistry,1999,30:1193～1200
    [14]
    Sehimmelmann A,Sessions A L,Boreham C J,et aI.D/Hratios in terrestrially sourced petroleum systems[J].Organic Geochemistry,2004,35:1169～1195
    [15]
    Jineai Tuo,Mingfeng Zhang,Xianbin Wang,et al.Hydrogen isotope ratios of aliphatic and diterpenoid hydrocarbons in coals and carbonaceous mudstones from the Liaohe Basin,China[J].Organic Geochemistry,2006,37:165～176
    [16]
    Lewan M D,Winters J C,Mcdonald J H.Generation of oillike pyrolysates from organic-rich shales[J].Science,1979,203:896～899
    [17]
    Lewan M D.Evaluation of petroleum generation by hydrous pyrolysis experiments[J].Phil Trans Royal Sci,1985,A315:123～134
    [18]
    Winters J C,Williams J A,Lewan M D.A laboratory study of petroleum generation by hydrous pyrolysis[A].In:Bjorφy M,ed.Advances in Organic Geochemistry[C],New York:Wiley,1981.524～533
    [19]
    Lewan M D.Experiments on the role of water in petroleum formation[J].Geochimica et Cosmochimica Acta,1997,61:3691～3723
    [20]
    Schimmelmann A,Lewan M D,Wintsch R P.D/H isotope ratios of kerogen,bitumen,oil,and water in hydrous pyr4yds of source rocks containing kerogen typesⅠ,Ⅱ,ⅡS and Ⅲ[J].Geochimica et Cosmochimica Acta,1999,63:3751～3766
    [21]
    Rigby D,Batts B D,Smith J W.The effect of maturation on the isotopic composition of fossil fuels[J].Organic Geochemistry,1981,3:29～36
    [22]
    Schou L,Eggen S,Schoell M.Oil-oil and oil-source rock correlation in Norwegian North Sea[A].In:Thomas B M,ed.Petroleum Geochemistry in Exploration of the Norwegian Shelf[M].London:Graham and Trotman,1985.101～117
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Citation
    XML
    PDF-CN

    Article Metrics

    Article views (681) PDF downloads(299) Cited by()
    Proportional views
    Related

    Website Copyright © Wuxi Research Institute of Petroleum Geology, SINOPEC 苏ICP备15009037号 苏公网安备32021102000780号

    Address：No. 2060, Lihu Avenue, Wuxi, Jiangsu   (214126) Tel：0510-68787204，68787203 Fax：0510-68787113 Email：sysydz.syky@sinopec.com

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return