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Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2008  >  30(2): 196-199
Yang Huamin, Tao Cheng, Ba Liqiang, Li Guangyou, Zhang Meizhen. A NEW METHOD FOR CALIBRATING HYDROGEN ISOTOPE OF WORKING STANDARD GAS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2008, 30(2): 196-199. doi: 10.11781/sysydz200802196
Citation: Yang Huamin, Tao Cheng, Ba Liqiang, Li Guangyou, Zhang Meizhen. A NEW METHOD FOR CALIBRATING HYDROGEN ISOTOPE OF WORKING STANDARD GAS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2008, 30(2): 196-199. doi: 10.11781/sysydz200802196
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A NEW METHOD FOR CALIBRATING HYDROGEN ISOTOPE OF WORKING STANDARD GAS

doi: 10.11781/sysydz200802196

  • Wuxi Research Institute of Petroleum Geology, Research Institute of Petroleum Exploration and Production, SINOPEC, Wuxi, Jiangsu 214151, China

  • Received Date: 2007-08-28
  • Rev Recd Date: 2008-03-07
  • Publish Date: 2008-03-28
    Abstract
  • The accuracy of hydrogen isotope analysis results needs a kind of working standard gas as a prerequisite.The steel-bottled hydrogen gas can be used as the working standard gas to measure the stability and the error of the instrument during the analyses of hydrogen isotopes.The hydrogen isotope fractionates greatly during the experiment,making the calibration of the standard working gas more important.Based on the theoretical results calculated from the hydrogen isotopic fractionation equilibrium equation of the H2-H2O(ι)system,the calibration of the working standard gas has been carried out in the experimental analysis of the hydrogen isotope of the natural water.The results are consistent with those analyzed by the Cr reduction method under high temperature conversion conditions.Two kinds of national standard water,Gbw04401 and Gbw04403,are used to testify the effectiveness of the calibration method.The results show that both the accuracy and the precision of this calibration method accord with the demands,and thus it can be used for hydrogen isotope analysis.

     

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    • References(12)
  • [1]
    王大锐.有机物中氢同位素分析及在石油勘探中的应用[J].石油勘探与开发,1991,18(1):31～36
    [2]
    沈平.轻烃中碳氢同位素组成特征[J].中国科学(B辑),1993,23(11):1216～1226
    [3]
    王万春.天然气、原油、干酪根的氢同位素地球化学特征[J].沉积学报,1996,14(增刊):131～135
    [4]
    戴金星.我国有机烷烃气的氢同位素的若干特征[J].石油勘探与开发,1990,17(5):27～32
    [5]
    郑淑惠,郑斯成,莫志超.稳定同位素地球化学分析[M].北京:北京大学出版社,1986.147～148
    [6]
    钟正坤,张莉,孙颖.氢-水同位素交换分离因子理论计算[J].原子能科学技术,2004,38(2):147～151
    [7]
    Horita J,Wesolowski D J.Liquid-vapor fractionation of oxygen and hydrogen isotopes of water from the freezing to the critical temperature[J].Geochim Cosmochim Acta,1994,58:3425～3437
    [8]
    Horibe Y,Craig H.D/H fractionation in the system methane-hydrogen-water[J].Geochim Cosmochim Acta,1995,59:5209～5217
    [9]
    Wong W W,Klein P D.A review of the techniques for the preparation of biological samples for mass spectrometric mea-surements of H2/H1and O18/O16 isotope ratios[J].Mass Spe-ctrometry Reviews,1986,5:313～342
    [10]
    Stephen T.A simple,practical methodology for routine VSMOW/SLAP normalization of water samples analyzed by continuous flow methods[J].Rapid Communa Mass Spectrum,2000,14:1044～1046
    [11]
    Ohsumi T,Fujino H.Isotope exchange technique for preparation of hydrogen gas in mass spectrometric D/H analysis of natural waters[J].Anal Sci,1986,80:1064～1067
    [12]
    毛世奇,缪增星,李洪等.用于氢/水同位素交换的Pt-SDB疏水性催化剂的研究[J].核化学与放射化学,1997,9(1):34～37
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