KINETICS OF HYDROCARBON GENERATION OF MARINE SOURCE ROCKS IN SOUTH CHINA

Jiang Qigui; Wang Yanbin; Qin Jianzhong; Wang Qin; Zhang Caiming

doi:10.11781/sysydz200806606

Volume 30 Issue 6

Turn off MathJax

Article Contents

Abstract

References

Article Navigation > PETROLEUM GEOLOGY & EXPERIMENT > 2008 > 30(6): 606-610

Jiang Qigui, Wang Yanbin, Qin Jianzhong, Wang Qin, Zhang Caiming. KINETICS OF HYDROCARBON GENERATION OF MARINE SOURCE ROCKS IN SOUTH CHINA[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2008, 30(6): 606-610. doi: 10.11781/sysydz200806606

Citation:

Jiang Qigui, Wang Yanbin, Qin Jianzhong, Wang Qin, Zhang Caiming. KINETICS OF HYDROCARBON GENERATION OF MARINE SOURCE ROCKS IN SOUTH CHINA[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2008, 30(6): 606-610. doi: 10.11781/sysydz200806606

Citation:

PDF( 404 KB)

KINETICS OF HYDROCARBON GENERATION OF MARINE SOURCE ROCKS IN SOUTH CHINA

doi: 10.11781/sysydz200806606

1.
China University of Mining Technology, Beijing 100083, China
2. Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi, Jiangsu 214151, China

Received Date: 2008-05-14
Rev Recd Date: 2008-10-06
Publish Date: 2008-12-28

Abstract

Abstract

With Rock-Eval 6 and Optkin kinetics software,the kinetics analysis on four types of kerogens of marine hydrocarbon source rocks in South China were carried out.The results showed that,in the similar maturity period,the hydrocarbon generation activation energy of kerogen was Ⅲ>Ⅱ₂>Ⅱ₁>Ⅰ;the ability of hydrocarbon generation was Ⅰ>Ⅱ₁>Ⅱ₂>Ⅲ;the span of generating effective hydrocarbon activation energy was ΔE_Ⅰ<15kJ/mol,15 kJ/mol<ΔE_Ⅱ₁<20kJ/mol,20kJ/mol<ΔE_Ⅱ₂<30 kJ/mol,ΔE_Ⅲ>30kJ/mol;the span of generating effective hydrocarbon temperature was ΔT_Ⅰ≤65℃,65℃≤ΔT_Ⅱ1≤75℃,75℃≤ΔT_Ⅱ₂≤85℃,ΔT_Ⅲ≥110℃.The time of hydrocarbon generation conversion rate to reach 10% was Ⅲ<Ⅱ₂<Ⅱ₁<Ⅰ;and the type Ⅰ kerogen first reached to 90% conversion rate,and then the typeⅡ₁,type Ⅱ₂ and type Ⅲ of kerogen.The character of hydrocarbon generation activation energy distribution of kerogen was determined by their element composition and organic high molecular structure.The hydrocarbon generation speed of good marine source rocks was very fast.
- element composition,
- molecular structure,
- hydrocarbon generation kinetics,
- marine source rocks,
- South China

FullText(HTML)

References(15)

References

[1]	Tissot B P,Pelet R,Ungerer P.Thermal history of sedimentary basins,maturation indices,and kinetics of oil and gas generation[J].AAPG Bulletin.,1987,71(12):1445～1466
[2]	黄第藩,李晋超,周翥红等.陆相有机质的演化与成烃机理[M].北京:石油工业出版社,1984.171～179
[3]	傅家谟,史继扬.石油演化理论与实践(Ⅰ):石油演化的机理与石油演化的阶段[J].地球化学,1975,(2):87～110
[4]	裴存民,周中毅.干酪根性质对油气形成影响的研究[J].地球化学,1989,(4):322～333
[5]	杨国华,吴肇亮,刘庆豪等.不同类型干酪根热解生烃动力学研究(一)[J].石油大学学报,1990,14(1):72～79
[6]	沈忠民陈义才.源岩平均活化能影响因素浅析[J].成都理工学院学报,2002,29(6):600～604
[7]	蒋启贵,王勤,承秋泉等.不同组分烃源岩生烃动力学特征浅析[J].石油实验地质,2005,27(5):512～518
[8]	秦匡宗,郭绍辉,李术元.有机地质大分子结构与未熟油生成[J].石油勘探与开发,1997,24(5):1～6
[9]	Hunt J M,Lewan M D,Hennet R J.Modelling oil generation with time-temperature index graphs based on the Arrhenius equation[J].AAPG Bulletin,1991,75(4):795～807
[10]	沈忠民,周光甲,洪志华.陆相低成熟烃源岩有机硫与热解成烃动力学关系初探[J].沉积学报,1998,16(4):133～139
[11]	卢双舫,刘晓艳,付晓泰等.未熟-低熟油生成机理的化学动力学研究及其初步应用[J].沉积学报,2001,19(1):130～135
[12]	张黯.立体化学和有机反应历程概要[M].北京:人民教育出版社,1985.252
[13]	黄福堂,阎卫东,李振广等.石油化学[M].北京:石油工业出版社,2000.233～235
[14]	秦建中,李志明,刘宝泉等.海相烃源岩形成重质油和固体沥青潜力分析[J].石油实验地质,2007,29(3):280～291
[15]	林世静,葛明兰,李术元等.松辽盆地干酪根在矿物基质作用下的热解生烃特征和动力学的研究[J].北京石油化工学院学报,2001,9(1):19～22

Relative Articles

[1]	LI Furong, LIU Wenhui, WANG Xiaofeng, ZHANG Dongdong, LUO Houyong, CHEN Xiaoyan, LI Fuqi, ZHANG Wen. Geochemical characteristics and genesis of Paleozoic natural gas in the Ordos Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2023, 45(4): 809-820. doi: 10.11781/sysydz202304809
[2]	LU Zhongdeng, LIU Yan, CHEN Zulin, FAN Yunpeng, WEN Zhigang, XU Yaohui, NIU Jin, TIAN Yongjing, LIU Bo, XIE Xiaomin, XIE Wei. An improved method and indications for the compound specific isotopic analysis of hopanes in source rock extracts[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2022, 44(2): 288-294. doi: 10.11781/sysydz202202288
[3]	Wang Jun, Wang Qingbin, Wang Feilong, Liu Xiaojian, Pan Wenjing. Gold tube pyrolysis study of source rock hydrocarbon generation in Bozhong area, offshore Bohai Bay Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2017, 39(3): 423-430. doi: 10.11781/sysydz201703423
[4]	Qin Jianzhong, Tenger Borjin, Shen Baojian, Tao Guoliang, Lu Longfei, Yang Yunfeng. Ultramicroscopic organic petrology characteristics and component classification of excellent marine source rocks[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2015, 37(6): 671-680. doi: 10.11781/sysydz201506671
[5]	Xu Zhengyu, Yao Genshun, Huang Ling, Dong Yong, Wang Pengwan, Yu Guang. Risk analysis and play evaluation of marine residual basins in South China[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2013, 35(1): 9-16. doi: 10.11781/sysydz201301009
[6]	Wo Yujin, Wang Xinwei, Yuan Yusong, Li Shuangjian, Zhou Yan, Gao Bo, Zhang Rongqiang, Zhang Dianwei. New explorations of petroleum preservation conditions in marine sequences, South China—concept and research methods of ‘preservation system’[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(1): 66-73. doi: 10.11781/sysydz201101066
[7]	Li Shuangjian, Gao Bo, Wo Yujin, Zhou Yan, Yuan Yusong. Destruction types and temporal—spatial distribution of marine hydrocarbon reservoirs in South China[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(1): 43-49. doi: 10.11781/sysydz201101043
[8]	Qin Jianzhong, Tao Guoliang, Tenger, Bian Lizeng, Xie Xiaomin, Fu Xiaodong. HYDROCARBON-FORMING ORGANISMS IN EXCELLENT MARINE SOURCE ROCKS IN SOUTH CHINA[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2010, 32(3): 262-269. doi: 10.11781/sysydz201003262
[9]	He Mingxi, Du Jianbo, Wang Rongxin, Guo Shangting, Yan Yongxin, Wu Minghui, Xie Qifeng, Li Fengxun. THE STUDY OF EXPLORATION PROSPECT OF MARINE NATURAL GAS IN THE NEOPROTEROZOIC-LOWER PALEOZOIC ON THE SOUTH MARGIN OF THE NORTH CHINA PLATFORM[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2009, 31(2): 154-159. doi: 10.11781/sysydz200902154
[10]	Zhang Shouchun, Zhang Linye, Zha Ming, Bao Youshu, Zhang Lei. AN EXPERIMENTAL SIMULATION ON THE HYDROCARBON QUANTITY GENERATED UNDER PRESSURE SUPPRESSION-A CASE STUDY FROM THE JIYANG DEPRESSION OF THE BOHAI BAY BASIN[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2008, 30(5): 522-526. doi: 10.11781/sysydz200805522
[11]	Qin Jianzhong, Fu Xiaodong, Tenger. EVALUATION OF THE EXCELLENT TRIASSIC TO SILURIAN MARINE HYDROCARBON SOURCE ROCKS IN XUANHAN-DAXIAN AREA OF NORTHEAST SICHUAN BASIN[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2008, 30(4): 367-374. doi: 10.11781/sysydz200804367
[12]	Tenger, Qin Jianzhong, Fu Xiaodong, Li Wu, Rao Dan, Zhang Meizhen. BASIC CONDITIONS OF MARINE HYDROCARBON ACCUMULATION IN NORTHWEST SICHUAN BASIN-HIGH GUALITY SOURCE ROCKS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2008, 30(5): 478-483. doi: 10.11781/sysydz200805478
[13]	Zhang Qu, Jiang Qigui, Tao Cheng, Zhang Caiming, Ba Liqiang. DEGASIFICATION METHODS AND APPLICATION OF HIGH QUALITY MARINE SOURCE ROCKS IN SOUTH CHINA[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2008, 30(5): 527-531. doi: 10.11781/sysydz200805527
[14]	Xu Sihuang, Ma Yongsheng, Mei Lianfu, Yuan Caiping, Guo Tonglou. NATURAL GAS MODELS CONTROLLED BY GRADED MULTI-FACTORS IN MARINE SEQUENCES OF SOUTH CHINA[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2007, 29(1): 19-24. doi: 10.11781/sysydz200701019
[15]	Fan Xiaolin, Zhai Changbo, Deng Mo. SIGNIFICANCE OF MESO-CENOZOIC TECTONIC MOVEMENTS IN MARIN PETROLEUM EXPLORATIONS IN THE SOUTH OF CHINA[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2006, 28(6): 539-543. doi: 10.11781/sysydz200606539
[16]	Liu Guangxiang. CHARACTERISTICS OF MIDDLE PALAEOZOIC MARINE SOURCE ROCK IN THE NORTH MARGIN OF MIDDLE AND UPPER YANGTZE REGION[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2005, 27(5): 490-495. doi: 10.11781/sysydz200505490
[17]	CHEN Yong-hong, LU Hong-you, ZENG Qing-hui, XIAO Xian-ming, TANG Yong-chun. INVESTIGATION ON THE POOL-FORMING TIME OF THE CHENGDAO OILFIELD IN THE BOHAIWAN BASIN USING THE HYDROCARBON GENERATION KINETICS METHOD[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2004, 26(6): 580-584. doi: 10.11781/sysydz200406580
[18]	GUO Tong-lou, LOU Zhang-hua, MA Yong-sheng. SEVERAL PROBLEMS ON OIL AND GAS PRESERVATION AND THEIR COMMERCIAL PROSPECTING IN MARINE SEQUENCES OF SOUTH CHINA[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2003, 25(1): 3-9. doi: 10.11781/sysydz200301003
[19]	ZHAO Zong-ju, ZHU Yan, DENG Hong-ying, XU Yun-jun. CONTROL OF PALEOUPLIFTS TO THE MESO-PALEOZOIC PRIMARY OIL AND GAS POOLS IN THE SOUTH OF CHINA[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2003, 25(1): 10-17. doi: 10.11781/sysydz200301010
[20]	WANG Jian-bao, XIAO Xian-ming, GUO Ru-tai, LU Hong-you, GAO Xi-long. STUDY ON THE HYDROCARBON GENERATION KINETICS OF SOURCE ROCKS FROM THE DONGYING DEPRESSION, THE BOHAIWAN BASIN[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2003, 25(4): 403-409. doi: 10.11781/sysydz200304403

Supplements(0)

Cited By

Proportional views

Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Citation

XML

PDF-CN

Article Metrics

Article views (1685) PDF downloads(822)

KINETICS OF HYDROCARBON GENERATION OF MARINE SOURCE ROCKS IN SOUTH CHINA

doi: 10.11781/sysydz200806606

Abstract

References

Relative Articles

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

KINETICS OF HYDROCARBON GENERATION OF MARINE SOURCE ROCKS IN SOUTH CHINA

doi: 10.11781/sysydz200806606

Abstract

References

Relative Articles

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

Export File

Citation

Format

Content